电泳涂料的合成与应用是涂料行业的一个突破性进展。综述了环氧丙烯酸电泳涂料的研究进展,主要介绍了环氧丙烯酸树脂的合成方法,环氧丙烯酸电泳涂料研究的概况,简要概述了环氧丙烯酸电泳涂料的应用领域及未来展望。
The synthesis and application of electrophoretic coatings were breakthrough in the coating industry.The research progress of epoxy-acrylic electrophoretic coatings was reviewed.The synthesis methods of epoxy-acrylic resin and the research situation of epoxy acrylic electrophoretic coatings were introduced.Then,the application fields and future prospects of epoxy-acrylic electrophoretic coatings were also briefly summarized.
[1] Das G,Karak N,Mesua L.Seed oil based amido-amine modified nanoclay/epoxy nanocomposites[J].J Appl Polym Sci,2012,124(3):2403-2414.
[2] 万涛,吴让君,吴绍林,等.光固化聚氨酯型阴极电泳清漆的研究[J].涂料工业,2009,39(7):1-3.
[3] Lee P C,Kim S,Hwang T,et al.Tunable surface hardness and dielectric constant of SiCxOy thin film converted from solution-processed organosilicon compound[J].J Mater Sci,2012,47(11):4540-4545.
[4] 狄文伟,陈卫东,周伟博,等.电泳漆专用色浆的研制[J].涂料工业,2011,41(12):26-29.
[5] Poh B T,Cheong S K.Adhesion behavior of natural rubber-based adhesives crosslinked by benzoyl peroxide[J].J Appl Polym Sci,2012,124(2):1031-1035.
[6] Rabea A M,Mirabedini S M,Mohseni M.Investigating the surface properties of polyurethane based anti-graffiti coatings against UV exposure[J].J Appl Polym Sci,2012,124(4):3082-3091.
[7] 李金艳,王胜军,李再亮,等.聚氨酯嵌段环氧阳极电泳树脂的制备及烘烤工艺[J].聚氨酯工业,2008,23(3):18-21.
[8] 胡美芳,邹治能,尤毅,等.NAVECO车架电泳漆改型混槽试验与生产应用[J].腐蚀与防护,2000,21(1):23-26.
[9] Armstrong G,Thornton R,Ryan M P,et al.Formulation of epoxy-polyester powder coatings containing silver-modified nanoclays and evaluation of their antimicrobial properties[J].Polym Bull,2012,68(7):1951-1963.
[10] Wang X M,Wang J W,Li Q,et al.Synthesis and characterization of waterborne epoxy-acrylic corrosion resistant coatings[J].Journal of Macromolecular Science,Part B:Physics,2013,52:751-761.
[11] 张玉芳,孔令奇,周春华.水性环氧丙烯酸乳液的合成与表征[J].济南大学学报,2009,23:162-165.
[12] Abbasian A,Ghaffarian S R,Mohammadi N.Investigation of factors affecting stratification phenomenon in epoxy-acrylic coatings[J].Iranian Polymer Journal,2004,13(1):61-68.
[13] Sun S H,Sun P Q,Liu D Z.The study of esterifying reaction between epoxy resins and carboxyl acrylic polymers in the presence of tertiary amine[J].European Polymer Journal,2005,41:913-922.
[14] Ewa L,Helena K,Elbieta K T,et al.Changes of solubility parameters during evaporation of solvents as a factor influencing the self-stratification of epoxy/acrylic systems[J].Progress in Organic Coatings,2009,66:228-234.
[15] Sun S H,Sun P Q,Liu D Z.Esterification in preparation of epoxy/acrylate composite aqueous coatings[J].Modern Chemical Industry,2004,24(10):35-37.
[16] Matthews J F,Sommerfeld E G.Water-borne coating composition made from epoxy resin,polymeric acid and tertiary amine:US 4247439[P].1981.
[17] Chu S C.Aqueous coating comprising dispersible epoxy resin-acid polymer ester and diluent polymer,and method of preparation:US 4446258[P].1984.
[18] Ting V W,Marcinko R M.Aqueous epoxy ester emulsions:US 4480058[P].1984.
[19] Noda,Sumio.Aqueous coating of carboxyl acrylic resin-epoxy resin produce:US 5780532[P].1998.
[20] Azarnia,Farah D,Aqueous epoxy resin dispersions for can coating use:US 4623680[P].1986.
[21] Ratna D,Simon G P.Mechanical characterization and morphology of carboxyl randomized poly(2-ethylhexylacrylate) liquid rubber toughened epoxy resins[J].Polymer,2001(42):7739-7747.
[22] 马洪芳.水性涂料用环氧丙烯酸树脂的研究[J].山东建筑工程学院学报,2002,17(3):74-77.
[23] 杨瑞芹,崔天放,陈尔凡.环氧-丙烯酸酯乳液的研制[J].化学世界,2002(1):23-24.
[24] 杨卫疆,王铺先.环氧树脂-丙烯酸酯IPN材料的合成与表征[J].高分子材料与工程,1998,14(11):24-27.
[25] 何东保,李庆云,范昌烈,等.紫外光固化的环氧丙烯酸酯的合成及其性能的研究[J].武汉大学学报,1999,45(4):415-418.
[26] 潘桂荣,武利民,张朱青,等.缩聚物/加聚物复合胶乳的制备I:环氧树脂/丙烯酸树脂乳液接枝聚合反应[J].高分子材料科学与工程,2002,18(3):39-42.
[27] Pan G R,Wu L M,Zhang Z Q,et al.Synthesis and characterization of epoxy-acrylate composite latex[J].Journal of Applied Polymer Science,2002,(83):1736-1743.
[28] 刘铁虎,韩巨岩,邱俊.新型水性防腐涂料的开发与研究[J].涂料工业,1999,(5):31-33.
[29] Woo J T K.Synthesis and characterization of water-reducible graft epoxy copolymers[J].Coat Tec,1982,(54):41-55.
[30] Woo J T K,Toman A.Water-based epoxy-acrylic graft copolymer[J].Progress in Organic Coatings,1993,21(4):371-385.
[31] Johnson R N.Water-borne phenoxy resins low VOC coatings with excellent toughness[J].Flexibility and Adhesion,1988(2):3-5.
[32] Evans J M,Ting V.Modified epoxy resins,processes for making and using same and substrates coated therewith:US 4212781[P].1980.
[33] Ting,Vincent.Polymerization process and product:US 4285847[P].1981.
[34] 吴静,刘常青,傅海军,等.甲基丙烯酸接枝改性环氧树脂的研究[J].沈阳化工学院报,2002,16(3):209-212.
[35] 陈尔凡,程远杰,赵常礼,等.接枝环氧水溶性涂料[J].涂料工业,1997(5):16-18.
[36] 李翠英,彭志杰.水性环氧丙烯酸浸涂漆的研制[J].涂料工业,2003(4):26-27.
[37] 朱国民,王善琦.环氧酯-丙烯酸接枝共聚物水性化的研究[J].涂料工业,1994,(5):3-6.
[38] 朱国民,王善琦,席海萍.环氧磷酸酯-丙烯酸接枝共聚反应的研究[J].涂料工业,1995(2):5-8.
[39] Schaeur E,Berglund L,Pena G,et al.Morphological variations in PMMA-modified epoxy mixtures by PEO addition[J].Polymer,2002,43:1241-1248.
[40] Shikha D,Kamani P K,Shukla M C.Studies on synthesis of water-borne epoxy ester based on RPO fatty acids[J].Progress in Organic Coatings,2003,47:87-94.
[41] 张燕.丙烯酸酯改性环氧阴极电泳涂料的研究[D].北京:北京化工大学,2006.
[42] 郭秀兰.丙烯酸-环氧阳离子树脂及阴极电泳漆的研究[D].广州:华南理工大学,2000.
[43] 刘玉.丙烯酸环氧树脂高耐候环保型阴极电泳涂料的研究[J].现代涂料与涂装,2010,13(9):7-9.
[44] 李田霞,陈峰.环氧丙烯酸阴极电泳涂料的研制及涂装工艺对漆膜性能的影响[J].材料保护,2011,44(1):35-37.
[45] 周子鹄,涂伟萍,杨卓如,等.环氧-丙烯酸阴极电泳涂料的实验研究(Ⅰ)—合成工艺和配方[J].化学工业与工程,2000,17(4):235-239.
[46] 张思奇.环氧丙烯酸电泳涂料的制备与性能研究[D].沈阳:东北大学,2012.
[47] 胡军,吴绍林,刘静,等.底面合一阴极电泳漆的研究[J].涂料工业,2007,37(6):49-51.
[48] Kim Y B,Kim H K,Hong J W.Epoxy-acrylic microgels in electrodeposition coating films[J].Surface and Coatings Technology,2002,153:284-289.
[49] 王海侨,张燕,李效玉.丙烯酸酯改性环氧阴极电泳涂料的研究[J].涂料工业,2006,36(6):11-15.
[50] 钟萍,邓继勇,易翔,等.底面合一型阴极电泳涂料的制备方法:中国发明专利,200710035454.2[P].
[51] 李文庄,高睿,何愿文,等.一种底面合一阴极电泳涂料及其制备方法和使用方法:中国发明专利,201310229789.3[P].
[52] 严刚,吴田,湛辅城.新型底面合一阴极电泳漆的合成与研究[J].涂层与防护,2018,39(7):44-47.
基金资助
中国博士后科学基金面上项目(2018M632433)
PDF
(1147KB)
