卟啉由于具有独特的电学、光学和催化性能,在可见光光催化应用中表现出巨大的潜力。简述了近年来基于卟啉超分子组装体的构筑和光催化应用的最新进展,并且介绍了卟啉与二维共轭材料的纳米结构复合材料在光催化降解和分解水产氢中的应用。通过讨论目前卟啉超分子自组装体系光催化剂存在的问题,提出今后的研究重点。
Porphyrins have great potential in visible light photocatalysis applications due to their unique electrical,optical and catalytic properties.Recent advances in the construction of porphyrin supramolecular assemblies and their photocatalytic applications were presented.In addition,the composites with nanostructure based on porphyrins and two-dimensional conjugated materials applied in photocatalytic degradation and hydrogen production were also described.By discussing the problems existing in the research aspects of porphyrin-based supramolecular self-assembly as photocatalyst,the research focus in the future was proposed.
[1] Woehrle D,Schnurpfeil G.Porphyrins and phthalocyanines in macromolecules[J].Cheminform,2004,35(11):177-246.
[2] Kundu S,Patra A.Nanoscale strategies for light harvesting[J].Chemical Reviews,2016,117(2):712-757.
[3] Kim F S,Ren G,Jenekhe S A.One-dimensional nanostructures of π-conjugated molecular systems:assembly,properties,and applications from photovoltaics,sensors,and nanophotonics to nanoelectronics[J].Chemistry of Materials,2011,23(3):622-629.
[4] Hasobe T.Porphyrin-based supramolecular nanoarchitectures for solar energy conversion[J].Journal of Physical Chemistry Letters,2013,4(11):1771-1780.
[5] Elemans J A A W,van Hameren R,Nolte R.M,et al.Molecular materials by self-assembly of porphyrins,phthalocyanines,and perylenes[J].Advanced Materials,2010,18(10):1251-1266.
[6] Abrahamse H,Hamblin M R.New photosensitizers for photodynamic therapy[J].Biochemical Journal,2016,473(4):347-364.
[7] Costacoquelard C,Sorgues S,Ruhlmann L.Photocatalysis with polyoxometalates associated to porphyrins under visible light:an application of charge transfer in electrostatic complexes[J].Journal of Physical Chemistry A,2010,114(22):6394-6400.
[8] Luo Q,Ge R,Kang S Z,et al.Fabrication mechanism and photocatalytic activity for a novel graphene oxide hybrid functionalized with tetrakis-(4-hydroxylphenyl) porphyrin and 1-pyrenesulfonic acid[J].Applied Surface Science,2018,427:15-23.
[9] Mandal S,Bhattacharyya S,Borovkov V,et al.Photophysical properties,self-assembly behavior,and energy transfer of porphyrin-based functional nanoparticles[J].Journal of Physical Chemistry C,2012,116(20):11401-11407.
[10] Arai T,Tanaka M,Kawakami H.Porphyrin-containing electrospun nanofibers:positional control of porphyrin molecules in nanofibers and their catalytic application[J].ACS Applied Materials & Interfaces,2012,4(10):5453-5457.
[11] Jusélius J,Sundholm D.The aromatic pathways of porphins,chlorins and bacteriochlorins[J].Physical Chemistry Chemical Physics,2000,2(10):2145-2151.
[12] Paavo H.Hynninen.Protonation-deprotonation equilibria in tetrapyrroles Part 4:mono- and diprotonations of deutero-,hemato-,meso-,and protoporphyrin IX dimethyl esters in methanolic hydrochloric acid[J].Journal of Porphyrins & Phthalocyanines,2014,18(05):385-395.
[13] Wasielewski M R.ChemInform abstract:self-assembly strategies for integrating light harvesting and charge separation in artificial photosynthetic systems[J].Acc Chem Res,2010,41(20):1910-1921.
[14] Schmidt-Mende L,Campbell W M,Wang Q,et al.Zn-porphyrin-sensitized nanocrystalline TiO2 heterojunction photovoltaic cells[J].Chemphyschem,2005,6(7):1253-1258.
[15] Ji J M,Zhou H,Kim H K.Rational design criteria for D-π-A structured organic and porphyrin sensitizers for highly efficient dye-sensitized solar cells[J].Journal of Materials Chemistry A,2018,6:14518-14545.
[16] Mozer A J,Wagner P,Officer D L,et al.The origin of open circuit voltage of porphyrin-sensitised TiO2 solar cells[J].Chemical Communications,2008,39(39):4741-4743.
[17] Fu Y,Lu T,Xu Y,et al.Theoretical screening and design of SM315-based porphyrin dyes for highly efficient dye-sensitized solar cells with near-IR light harvesting[J].Dyes & Pigments,2018,155:292-299.
[18] Groves J T,Haushalter R C,Nakamura M,et al.High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450[J].Journal of the American Chemical Society,1981,103(10):2884-2886.
[19] Kwong K W,Chen T H,Luo W,et al.A biomimetic oxidation catalyzed by manganese(Ⅲ) porphyrins and iodobenzene diacetate:synthetic and mechanistic investigations[J].Inorganica Chimica Acta,2015,430:176-183.
[20] Li Y,Duan Q,Wang H,et al.Construction of two-dimensional porphyrin-based fully conjugated microporous polymers as highly efficient photocatalysts[J].Journal of Photochemistry & Photobiology A Chemistry,2018,356:370-378.
[21] Hajjaj F,Yoon Z S,Yoon M C,et al.Assemblies of supramolecular porphyrin dimers in pentagonal and hexagonal arrays exhibiting light-harvesting antenna function[J].Journal of the American Chemical Society,2006,128(14):4612-4623.
[22] Devaramani S,Shinger M I,Ma X,et al.Porphyrin aggregates decorated MWCNT film for solar light harvesting:influence of J- and H-aggregation on the charge recombination resistance,photocatalysis,and photoinduced charge transfer kinetics[J].Physical Chemistry Chemical Physics,2017,19(28):18232-18242.
[23] Byrn M P,Curtis C J,Yu H,et al.Porphyrin sponges:conservative of host structure in over 200 porphyrin-based lattice clathrates[J].Journal of the American Chemical Society,1993,115(21):9480-9497.
[24] 张娜.卟啉可控自组装及可见光光解水制氢应用[D].开封:河南大学,2016.
[25] Wang Z,Medforth C J,Shelnutt J A.Self-metallization of photocatalytic porphyrin nanotubes[J].Journal of the American Chemical Society,2004,126(51):16720-16721.
[26] Wang Z,Lybarger L E,Wang W,et al.Monodisperse porphyrin nanospheres synthesized by coordination polymerization[J].Nanotechnology,2008,19(39):395604.
[27] Marciniak H,Li X Q,Würthner F,et al.One-dimensional exciton diffusion in perylene bisimide aggregates[J].Journal of Physical Chemistry A,2011,115(5):648-654.
[28] Tian Y,Martin K E,Shelnutt J Y,et al.Morphological families of self-assembled porphyrin structures and their photosensitization of hydrogen generation[J].Chemical Communications,2011,47(21):6069-6071.
[29] Martin K E,Tian Y,Busani T,et al.Charge effects on the structure and composition of porphyrin binary ionic solids:ZnTPPS/SnTMePyP nanomaterials[J].Chemistry of Materials,2013,25(3):441-447.
[30] Mandal S,Nayak S K,Mallampalli S,et al.Surfactant-assisted porphyrin based hierarchical nano/micro assemblies and their efficient photocatalytic behavior[J].ACS Applied Materials & Interfaces,2014,6(1):130-136.
[31] Guo P,Chen P,Liu M.One-dimensional porphyrin nanoassemblies assisted via graphene oxide:sheetlike functional surfactant and enhanced photocatalytic behaviors[J].Applied Materials & Interfaces,2013,5(11):5336-5345.
[32] Guo P,Chen P,Ma W,et al.Morphology-dependent supramolecular photocatalytic performance of porphyrin nanoassemblies:from molecule to artificial supramolecular nanoantenna[J].Journal of Materials Chemistry,2012,22(38):20243-20249.
[33] Zhong Y,Wang J F,Zhang R F,et al.Morphology-controlled self-assembly and synthesis of photocatalytic nanocrystals[J].Nano Letters,2014,(12):7175-7179.
[34] Lin S,Diercks C S,Zhang Y B,et al.Covalent organic frameworks comprising cobalt porphyrins for catalytic CO2 reduction in water[J].Science,2015,349(6253):1208-1213.
[35] Zhao G,Pang H,Liu G,et al.Co-porphyrin/carbon nitride hybrids for improved photocatalytic CO2,reduction under visible light[J].Applied Catalysis B Environmental,2017,200:141-149.
[36] Shen J,Kortlever R,Kas R,et al.Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin[J].Nature Communications,2015,6(4):809-815.
[37] Lian S,Kodaimati M S,Weiss E A.Photocatalytically active superstructures of quantum dots and iron porphyrins for reduction of CO2 to CO in water[J].ACS Nano,2018,12(1):568-575.
[38] Bonin J,Robert M,Routier M.Selective and efficient photocatalytic CO2 reduction to CO using visible light and an iron-based homogeneous catalyst[J].Journal of the American Chemical Society,2014,136(48):16768-16771.
[39] Chen Y,Huang Z H,Yue M,et al.Integrating porphyrin nanoparticles into a 2D graphene matrix for free-standing nanohybrid films with enhanced visible-light photocatalytic activity[J].Nanoscale,2013,6(2):978-985.
[40] Zhu M,Li Z,Xiao B,et al.Surfactant assistance in improvement of photocatalytic hydrogen production with the porphyrin noncovalently functionalized graphene nanocomposite[J].ACS Applied Materials & Interfaces,2013,5(5):1732-1740.
[41] Luo Q,Ge R,Kang S Z,et al.Fabrication mechanism and photocatalytic activity for a novel graphene oxide hybrid functionalized with tetrakis-(4-hydroxylphenyl)porphyrin and 1-pyrenesulfonic acid[J].Applied Surface Science,2018,427:15-23.[42] Cao S W,Liu X F,Yuan Y P,et al.Solar-to-fuels conversion over In2O3/g-C3N4,hybrid photocatalysts[J].Applied Catalysis B Environmental,2014,147(5):940-946.
[43] Zheng Y,Liu J,Liang J,et al.Graphitic carbon nitride materials:controllable synthesis and applications in fuel cells and photocatalysis[J].Energy & Environmental Science,2012,5(5):6717-6731.
[44] Niu P,Zhang L,Liu G,et al.Graphene-like carbon nitride nanosheets for improved photocatalytic Activities[J].Advanced Functional Materials,2012,22(22):4763-4770.
[45] Wang D H,Pan J N,Li H H,et al.A pure organic heterostructure of μ-oxo dimeric iron(Ⅲ) porphyrin and graphitic-C3N4 for solar H2 roduction from water[J].Journal of Materials Chemistry A,2015,4(1):290-296.
[46] Chen Y,Li A,Huang Z H,et al.Porphyrin-based nanostructures for photocatalytic applications[J].Nanomaterials,2016,6(3):51.
[47] Silva E S D,Moura N M M,Neves M G P M S,et al.Novel hybrids of graphitic carbon nitride sensitized with free-base meso-tetrakis (carboxyphenyl) porphyrins for efficient visible light photocatalytic hydrogen production[J].Applied Catalysis B Environmental,2018,221:56-69.
[48] Chen D,Wang K,Hong W,et al.Visible light photoactivity enhancement via CuTCPP hybridized g-C3N4,nanocomposite[J].Applied Catalysis B Environmental,2015,166-167:366-373.
基金资助
河北省自然科学基金青年科学基金项目(B2016209139)
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