无机荧光材料主要由基质和激活剂构成,具有吸收能力强、转换率高、物理化学性质稳定等特点。综述了无机荧光材料的发光原理及制备方法。无机荧光材料的制备方法主要包括高温固相法、溶胶-凝胶法、化学共沉淀法、水热合成法、微波辐射法、燃烧合成法等,介绍了不同制备方法的优缺点并对无机荧光材料的研究方向进行了展望。
The inorganic fluorescent material is mainly composed of a matrix and an activator,and has the characteristics of strong absorption capacity,high conversion rate,stable physical and chemical properties.The luminescent principle and preparation methods of inorganic fluorescent materials were reviewed.The preparation methods included the high temperature solid phase reaction method,sol-gel method,chemical cooperation method,hydrothermal synthesis method and the microwave radiation method,and the advantage and disadvantage of each method were discussed.The future research direction of the inorganic fluorescent materials were discussed.
[1] Du Jie,Yang Rong,Fang Changqing,et al.Preparation and characterization of organic pigments and their fluorescence properties depending on bulk structure[J].Journal of Materials Science & Technology,2018,34(11):2218-2224.
[2] Serroukh S,Huber P,Lallam A.Adsorption behavior of optical brightening agent on microfibrillated cellulose studied through inverse liquid chromatography:the need to correct for axial dispersion effect[J].Journal of Chromatography A,2018,1533:17-29.
[3] Li Z,Zhao J,Wu X,et al.A rapid microfluidic platform with real-time fluorescence detection system for molecular diagnosis[J].Biotechnology & Biotechnological Equipment,2019,67:1-8.
[4] Kalaiyarasan G,Hemlata C,Joseph J.Fluorescence turn-on,specific detection of cystine in human blood plasma and urine samples by nitrogen-doped carbon quantum dots[J].ACS Omega,2019,4(1):1007-1014.
[5] Lange Jens,Olsson Oliver,Sweeney Brian,et al.Fluorescent tracers to evaluate pesticide dissipation and transformation in agricultural soils[J].The Science of the Total Environment,2018,23(4):619-620.
[6] Fan J,Wang S,Sun W,et al.Anticancer drug delivery systems based on inorganic nanocarriers with fluorescent tracers[J].AIChE Journal,2017,64(4):34-37.
[7] Martin Debreczeny P,Richard Dorshow B.Transdermal optical renal function monitoring in humans:development,verification,and validation of a prototype device[J].Journal of Biomedical Optics,2018,23(5):1.
[8] 赵红昆,丁波,王修光,等.4-(1,2,4-三唑-1-基)苯酚铜(Ⅱ)/镍(Ⅱ)配合物的晶体结构及荧光性质[J].无机化学学报,2018,34(9):1739-1746.
[9] Hao T,Wei X,Nie Y,et al.An eco-friendly molecularly imprinted fluorescence composite material based on carbon dots for fluorescent detection of 4-nitrophenol[J].Microchimica Acta,2016,183(7):2197-2203.
[10] 孙阳艺,罗思媛,费慧龙,等.铕掺杂无机红色荧光材料的研究进展[J].电子元件与材料,2010,29(5):75-78.
[11] 孙家跃,杜海燕,胡文祥.固体发光材料[M].北京:化学工业出版社,2003.
[12] Eglitis R I,Kotomin E A,Borstel G.Quantum chemical modelling of electron polarons and charge-transfer vibronic excitons in BaTiO3 perovskite crystals[J].Journal of Physics Condensed Matter,2002,14(14):3735-3741.
[13] Yu X B,Xu X L,Zhou C L,et al.Synthesis and luminescent properties of SrZnO2∶Eu3+,M+(M=Li,Na,K)phosphor[J].Mater Res Bull,2006,41(8):1578-1583.
[14] Wang F,Zhou D,Ma S,et al.Preparation and luminescent properties of Eu2+ doped Sr3La(PO4)3 phosphor[J].Journal of Alloys & Compounds,2011,509(14):4824-4827.
[15] Dong G,Ma H,Liu Y,et al.Synthesis and photoluminescence properties of the high-brightness Eu3+-doped Sr3Bi(PO4)3 phosphors[J].Optics Communications,2012,285(20):4097-4101.
[16] 何洪.硅酸盐基稀土发光材料的制备及其光谱特性与光谱调控[D].南京:南京航空航天大学,2010.
[17] 乔东霞,莎仁,边树勋.Eu3+掺杂Gd2TiO5荧光粉的制备及其发光性质研究[J].内蒙古石油化工,2017,43(增刊):12-13.
[18] Zainurul A Z,Asiah M N,Rosmani C H,et al.Preparation of LaPO4 with different morphologies and fluorescence properties by sol-gel spin-coating method[J].Advanced Materials Research,2014,832:562-566.
[19] 贺香红,周健,毕承路,等.新型蓝绿色稀土荧光粉SrZnO2∶Pr3+的发光性能[J].人工晶体学报,2007,36(6):1408-1411.
[20] Eychmüller,Alexander.Structure and photophysics of semiconductor nanocrystals[J].The Journal of Physical Chemistry B,2000,104(28):6514-6528.
[21] 王雅静,李娟娟,史忠祥,等.(La,Gd)PO4∶Pr3+荧光材料的制备及上转换发光性能的研究[J].化工新型材料,2016,44(11):140-142.
[22] Bai Y L,Gao H,Zhang J Y.Hydrothermal synthesis of micro-nanofluorescent materials[J].Journal of Functional Materials,2014,45(12):12019-12026.
[23] Li J,Lu G,Xie B,et al.Nano-preparation promoting effectively luminescent properties of one-dimensional rare earth oxides[J].Journal of Rare Earths,2012,30(11):1096-1101.
[24] Wan Q,He Y P,Dai N,et al.Eu3+-doped LaPO4 and LaAlO3 nanosystems and their luminescence properties[J].Sic China Series B,2009,52(8):1104-1112.
[25] Xu G Q,Xu H T,Zheng Z X,et al.Preparation and characterization of Zn2SiO4∶ Mn phosphors with hydrothermal methods[J].Journal of Luminescence,2010,130(10):1717-1720.
[26] Ju X,Li X,Li W,et al.Luminescence properties of ZnMoO4∶Tb3+ green phosphor prepared via co-precipitation[J].Materials Letters,2011,65(17/18):2642-2644.
[27] Li J K,Liu Z P,Luo J F,et al.Investigation on the preparation and properties of monodispersed spherical Y2O3∶Dy3+ phosphor[J].Key Engineering Materials,2017,726:255-260.
[28] Wan L,Lu Shuchen,Sun L,et al.Bi3+ enhanced red emission in Sr0.5Ca0.4MoO4∶Eu3+ phosphor[J].Optical Materials,2014,36(3):628-632.
[29] 曹仕秀,彭玲玲,魏宁,等.化学共沉淀法制备Ba2Si3O8∶Eu2+荧光粉及其发光特性[J].稀有金属材料与工程,2013,42(S2):561-564.
[30] 刘慧娟.化学沉淀法制备YAlO3∶Eu3+荧光粉及其性能表征[D].郑州:郑州大学,2011.
[31] Iwako Yasuo,Akimoto Yuki,Omiya Masaki,et al.Photoluminescence of cubic and monoclinic Gd2O3∶Eu phosphors prepared by flame spray pyrolysis[J].Journal of Luminescence,2010,130(8):1470-1474.
[32] Wang S,Wang H Q.Spray pyrolysis synthesis and luminescence properties of spherical Eu3+ doped SrMoO4 phosphors[J].Key Engineering Materials,2015,655:4.
[33] Khan Z S,Ingale N B,Omanwar S K.Combustion synthesis and luminescence studies of Eu(Ⅲ) activated LiBaBO3 inorganic phosphor[J].Optik-International Journal for Light and Electron Optics,2016,127(20):9679-9682.
[34] Verma N,Mari B,Singh K C,et al.Luminescence properties of ZnMoO4∶Eu3+∶Y3+ materials synthesized by solution combustion synthesis method[C].National Conference on Thermophysical Properties.AIP Publishing LLC,2016.
[35] Lephoto M A,Tshabalala K G,Motloung S J,et al.Photoluminescence studies of green emitting BaB8O13∶Bi3+,phosphors prepared by solution combustion method[J].Journal of Luminescence,2018,200:94-102.
[36] 朱聪旭.微波法制备Ba2SiO4∶Eu荧光材料及其性能研究[J].广州化工,2017,45(7):30-31.
[37] Zhang Yeai,Liu Xiaotang,Lei Bingfu.Effect of C3N6H6 on luminescent properties of SrSi2N2O2∶Eu2+ yellow phosphors prepared by microwave reaction method[J].Energy Procedia,2012,16:391-396.
[38] 王林香.Na+,Li+,Bi3+掺杂CaWO4∶Eu3+荧光粉的制备及发光特性[J].高等学校化学学报,2018,39(1):25-31.
[39] Venkatachalaiah K N,Nagabhushana H,Darshan G P,et al.Structural,morphological and photometric properties of sonochemically synthesized Eu3+,doped Y2O3,nanophosphor for optoelectronic devices[J].Materials Research Bulletin,2017,94(10):442-455.
[40] 刘文全,史瑞新,段如霞,等.CaxSi合金前驱物常压氮化制备Ca(1-x)AlSiN3∶xEu2+红色荧光粉及发光性能研究[J].发光学报,2017,38(10):1295-1301.
基金资助
国家自然科学基金(21666015)