一种含硅、氮成炭剂的合成及其阻燃聚丙烯的研究

张乃恩1,2, 靳晴1,2, 郭晓荣1,2, 孙强1,2, 晏泓1,2*

化工新型材料 ›› 2020, Vol. 48 ›› Issue (5) : 206 -209.

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化工新型材料 ›› 2020, Vol. 48 ›› Issue (5) : 206-209.
科学研究

一种含硅、氮成炭剂的合成及其阻燃聚丙烯的研究

    张乃恩1,2, 靳晴1,2, 郭晓荣1,2, 孙强1,2, 晏泓1,2*
作者信息 +

Synthesis of a char-forming agent containing silicon and nitrogen and its application to polypropylene

  • Zhang Naien1,2, Jin Qing1,2, Guo Xiaorong1,2, Sun Qiang1,2, Yan Hong1,2
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文章历史 +
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摘要

以超支化聚酯(HBPE)与γ-氨丙基三乙氧基硅烷(KH550)为原料制备了一种含硅、氮的新型阻燃剂(K-HBPE)。傅里叶红外光谱(FT-IR)和扫描电子显微镜(SEM)结果证明其已成功制备,然后将其与聚磷酸铵(APP)复配添加入聚丙烯(PP)中。在30%(K-HBPE∶APP=1∶1)的添加质量下,阻燃PP的极限氧指数(LOI)增加到了33.2%,且成功通过了UL-94的V-0级别。实验表明K-HBPE与APP有优异的协同阻燃效应。

Abstract

A novel flame retardant (K-HBPE) containing silicon and nitrogen was prepared from hyperbranched polyester (HBPE) and γ-aminopropyltriethoxysilane (KH550).FT-IR and SEM confirmed the synthesis of K-HBPE,which was then blended with ammonium polyphosphate (APP) into polypropylene (PP).With 30% (K-HBPE∶APP=1∶1) of the intumescent flame retardant,the limiting oxygen index (LOI) of PP composite was increased to 33.2% and the UL-94 test achieved V-0 rating.The results showed that K-HBPE with APP had an excellent synergistic flame retardant effect.

关键词

聚磷酸铵 / 膨胀型阻燃剂 / 协同效应 / 聚丙烯

Key words

ammonium polyphosphate / intumescent flame retardant / synergistic effect / polypropylene

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一种含硅、氮成炭剂的合成及其阻燃聚丙烯的研究[J]. 化工新型材料, 2020, 48(5): 206-209 DOI:

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基金资助

国家青年科学基金(51703152);山西省自然科学基金(201701D121044)

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