双发光层有机电致发光器件的制备及性能研究

李小康1, 左宏剑2, 马玉芹1, 杨秀云1*

化工新型材料 ›› 2020, Vol. 48 ›› Issue (5) : 71 -75.

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化工新型材料 ›› 2020, Vol. 48 ›› Issue (5) : 71-75.
新材料与新技术

双发光层有机电致发光器件的制备及性能研究

    李小康1, 左宏剑2, 马玉芹1, 杨秀云1*
作者信息 +

Research fabrication and property of high efficiency yellow organic light-emitting diode with double-emitting layer

  • Li Xiaokang1, Zuo Hongjian2, Ma Yuqin1, Yang Xiuyun1
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摘要

为了提高黄光有机电致发光器件的效率,以二(2-苯基喹啉)(2,2,6,6-四甲基庚烷)-二酸合铱[PQ2Ir(dpm)]和三(2-(4-甲苯基)苯基吡啶)合铱[Ir(mppy)3]为发光材料,选择4,4′,4″-三(9-咔唑基)三苯胺(TcTa)和2,6-二(3-(9H-咔唑基-9-基)苯基)吡啶(26DczPPy)分别作为主体材料,设计了阶梯式能级结构的器件,制备出一系列双发光层有机电致发光器件并考察了红光材料掺杂量对电致发光器件性能和电致发光光谱的影响。结果表明:制备的双发光层有机电致发光器件的启亮电压为3.5V、最大亮度为147900cd/m2、最大电流效率为88.91cd/A、最大功率效率为61.05lm/W、最大外量子效率为33.2%;亮度为1000cd/m2时,该器件的电流效率和外量子效率分别为84.9cd/A和32.1%。

Abstract

A series of high efficiency yellow devices with double-emitting layers were fabricated by selecting bis(2-phenylquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(Ⅲ)(PQ2Ir(dpm)) and tris(phenylpyrazole) iridium (Ir(mppy)3) as phosphorescent materials,and 4,4′,4″-tri(9-carbazoyl)triphenylamine (TcTa) and 2,6-bis(3-(9H-carbazol-9-yl)phenyl)pyridine (26DCzPPy) as host materials,respectively.The effects on the efficiency and spectrum of yellow light devices were investigated by optimizing the doping concentration of the red phosphorescent material.Finally,the optimized device with turn-on voltage,the maximum brightness,current efficiency power efficiency and external quantum efficiency up to 3.5V,147900cd/m2,88.91cd/A,61.05lm/W and 33.2%,respectively,was obtained.Even at the practical brightness of 1000cd/m2,current efficiency and external quantum efficiency as high as 84.9cd/A and 32.1%,respectively,can still be retained.

关键词

电致发光 / 黄光 / 双发光层 / 激子俘获

Key words

electroluminescence / yellow light / double-emitting layer / exciton capture

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双发光层有机电致发光器件的制备及性能研究[J]. 化工新型材料, 2020, 48(5): 71-75 DOI:

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基金资助

吉林省发改委项目(2017C050);吉林省科技厅项目(20190302001GX)

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