空穴传输层材料与吸收层的选择性接触对提高钙钛矿太阳能电池的光电转化效率具有重要作用,空穴缓冲层材料直接影响钙钛矿的生长,同时,空穴缓冲层对钙钛矿太阳能电池的稳定性和寿命起到决定性的作用。介绍了氧化镍(NiO)空穴传输层材料的制备方法及其在钙钛矿太阳能电池中的应用,指出通过优化制备方法可以提高NiO的透光性和导电性,进而提高钙钛矿太阳能电池的光电转化效率。
The selective contact between the hole transport material and the absorption layer plays an important role in improving the photoelectric conversion efficiency of perovskite cells.Different hole buffer layer materials have a direct impact on the growth of perovskite.Meanwhile,the hole buffer plays a decisive role in the stability and life of perovskite solar cells.The preparation method and application of NiO as hole transport layer material in perovskite solar cells were introduced.It was pointed out that the light transmittance and conductivity of NiO can be improved by optimizing the preparation method.And then the photoelectric conversion efficiency of perovskite solar cells can be improved.
[1] Lee M M,Teuscher J,Miyasaka T,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].Science,2012,338(6107):643-647.
[2] Kojima A,Teshima K,Shirai Y,et al.Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].Journal of the American Chemical Society,2009,131(17):6050-6051.
[3] Jeon N J,Na H,Jung E H,et al.A fluorene-terminated hole-transporting material for highly efficient and stable perovskite solar cells[J].Nature Energy,2018,3(8):682.
[4] Zhang M D,Zhao D X,Chen L,et al.Structure-performance relationship on the asymmetric methoxy substituents of spiro-OMeTAD for perovskite solar cells[J].Solar Energy Materials and Solar Cells,2018,176:318-323.
[5] Bi D,Yang L,Boschloo G,et al.Effect of different hole transport materials on recombination in CH3NH3PbI3 perovskite-sensitized mesoscopic solar cells[J].The Journal of Physical Chemistry Letters,2013,4(9):1532-1536.
[6] Bruijnaers B J,Schiepers E,Weijtens C H L,et al.The effect of oxygen on the efficiency of planar p-i-n metal halide perovskite solar cells with a PEDOT∶PSS hole transport layer[J].Journal of Materials Chemistry A,2018,6(16):6882-6890.
[7] Lv Y,Guo Y,Zhang H,et al.Enhanced efficiency and stability of fully air-processed TiO2 nanorods array based perovskite solar cell using commercial available CuSCN and carbon[J].Solar Energy,2018,173:7-16.
[8] Byranvand M M,Kim T,Song S,et al.p-type CuI islands on TiO2 electron transport layer for a highly efficient planar-perovskite solar cell with negligible hysteresis[J].Advanced Energy Materials,2018,8(5):1702235.
[9] Lin L,Jiang L,Li P,et al.A modeled perovskite solar cell structure with a Cu2O hole-transporting layer enabling over 20% efficiency by low-cost low-temperature processing[J].Journal of Physics and Chemistry of Solids,2019,124:205-211.
[10] Park J H,Seo J,Park S,et al.Efficient CH3NH3PbI3 perovskite solar cells employing nanostructured p-type NiO electrode formed by a pulsed laser deposition[J].Advanced Materials,2015,27(27):4013-4019.
[11] Qiu Z,Gong H,Zheng G,et al.Enhanced physical properties of pulsed laser deposited NiO films via annealing and lithium doping for improving perovskite solar cell efficiency[J].Journal of Materials Chemistry C,2017,5(28):7084-7094.
[12] Cui J,Meng F,Zhang H,et al.CH3NH3PbI3-based planar solar cells with magnetron-sputtered nickel oxide[J].ACS Applied Materials & Interfaces,2014,6(24):22862-22870.
[13] Wang K C,Shen P S,Li M H,et al.Low-temperature sputtered nickel oxide compact thin film as effective electron blocking layer for mesoscopic NiO/CH3NH3PbI3 perovskite heterojunction solar cells[J].ACS Applied Materials & Interfaces,2014,6(15):11851-11858.
[14] Hu L,Peng J,Wang W,et al.Sequential deposition of CH3NH3PbI3 on planar NiO film for efficient planar perovskite solar cells[J].ACS Photonics,2014,1(7):547-553.
[15] Yin X,Yao Z,Luo Q,et al.High efficiency inverted planar perovskite solar cells with solution-processed NiOx hole contact[J].ACS Applied Materials & Interfaces,2017,9(3):2439-2448.
[16] Yin X,Chen P,Que M,et al.Highly efficient flexible perovskite solar cells using solution-derived NiOx hole contacts[J].ACS Nano,2016,10(3):3630-3636.
[17] Liu Z,Zhu A,Cai F,et al.Nickel oxide nanoparticles for efficient hole transport in pin and nip perovskite solar cells[J].Journal of Materials Chemistry A,2017,5(14):6597-6605.
[18] Seo S,Park I J,Kim M,et al.An ultra-thin,un-doped NiO hole transporting layer of highly efficient (16.4%) organic-inorganic hybrid perovskite solar cells[J].Nanoscale,2016,8(22):11403-11412.
[19] Trifiletti V,Roiati V,Colella S,et al.NiO/MAPbI3-xClx/PCBM:a model case for an improved understanding of inverted mesoscopic solar cells[J].ACS Applied Materials & Interfaces,2015,7(7):4283-4289.
[20] Zhu Z,Bai Y,Zhang T,et al.High-performance hole-extraction layer of sol-gel-processed NiO nanocrystals for inverted planar perovskite solar cells[J].Angewandte Chemie,2014,126(46):12779-12783.
[21] Kim J H,Liang P W,Williams S T,et al.High-performance and environmentally stable planar heterojunction perovskite solar cells based on a solution-processed copper-doped nickel oxide hole-transporting layer[J].Advanced Materials,2015,27(4):695-701.
[22] Jung J W,Chueh C C,Jen A K Y.A low-temperature,solution-processable,Cu-doped nickel oxide hole-transporting layer via the combustion method for high-performance thin-film perovskite solar cells[J].Advanced Materials,2015,27(47):7874-7880.
[23] Chen W,Liu F Z,Feng X Y,et al.Cesium doped NiOx as an efficient hole extraction layer for inverted planar perovskite solar cells[J].Advanced Energy Materials,2017,7(19):1700722.
[24] Huang A B,Zhu J T,Zheng J Y,et al.Achieving high-performance planar perovskite solar cells with co-sputtered Co-doping NiOx hole transport layers by efficient extraction and enhanced mobility[J].Journal of Materials Chemistry C,2016,4(46):10839-10846.
基金资助
国家自然科学基金(61540016);黔西南州科技局项目(2019-2-55);贵州省科技厅基金(黔科合字(LH[2016]7036);贵州省大学生创新创业项目(201710666037);贵州省教育厅基金(黔教合KY[2014]318)