温敏性糖基P(NIPAM-co-OVSGal)微凝胶的相转变研究

蔡豪1, 张仪娜1, 郑永利1, 权静1,2*

化工新型材料 ›› 2020, Vol. 48 ›› Issue (4) : 141 -144.

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化工新型材料 ›› 2020, Vol. 48 ›› Issue (4) : 141-144.
科学研究

温敏性糖基P(NIPAM-co-OVSGal)微凝胶的相转变研究

    蔡豪1, 张仪娜1, 郑永利1, 权静1,2*
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Phase transformation of P (NIPAM-co-OVSGal) thermosensibive carbohydrate-based microgel

  • Cai Hao1, Zhang Yina1, Zheng Yongli1, Quan Jing1,2
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摘要

结合酶促法和无皂乳液聚合法制备了温敏微凝胶P(NIPAM-co-OVSGal),通过红外光谱(FT-IR)和核磁共振氢谱(1H-NMR)对微凝胶的结构进行确认表征;变温紫外-可见分光光度计(UV-Vis)测得微凝胶的低临界溶解温度(LCST)值为33.4℃;光散射技术(LLS/DLS)和透射电子显微镜(TEM)研究了微凝胶的体积相转变行为。结果表明,微凝胶为均匀分散的球形,流体力学半径(Rh)和均方旋转半径(Rg)均随温度的升高而逐渐减小,说明微凝胶的相转变是个连续变化的过程。

Abstract

P(NIPAM-co-OVSGal) thermosensitive microgels were synthesized by combination of enzymatic reaction and soap-free emulsion polymerization.FT-IR and 1H-NMR were used to analysis the structure and composition of microgels.UV-visible spectroscopy test showed that the low critical solution temperature (LSCT) of microgels was 33.4℃.Measurements by light scattering technology (LLS/DLS) and transmission electron microscope (TEM) aimed to researched volume phase transformation behavior and it turned out that microgels were uniformly dispersed sphere,Rh and Rg both decreased as the temperature increased,and process of volume phase transformation was continuous.

关键词

温敏微凝胶 / LCST / 体积相转变

Key words

thermosensitive micregel / LCST / volume phase transformation

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温敏性糖基P(NIPAM-co-OVSGal)微凝胶的相转变研究[J]. 化工新型材料, 2020, 48(4): 141-144 DOI:

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