微胶囊相变材料(MCPCM)因特有的储放热性能,受到国内外学者的广泛关注。对原位聚合法和界面聚合法制备微胶囊相变材料研究进展进行了介绍,总结了制备过程中改进微胶囊致密性、稳定性差,导热性低以及降低游离甲醛等问题的方法,阐述了通过浸轧、涂层和熔融纺丝的方法将微胶囊整理到织物上,得到具有蓄热调温功能的纺织品的相关成果。最后,展望了微胶囊相变的研究方向,指出兼具环保性、高致密性、高热稳定性以及导热性良好的微胶囊相变材料具有广阔的应用前景。
The heat release characteristics of microcapsule phase change materials have attracted wide attention from scholars at home and abroad.The two preparing methods of microcapsule phase change material (MCPCM) were introduced,particularly the in-situ polymerization and interfacial polymerization methods.It summed up the ways of improving the microcapsules' density,poor stability,low thermal conductivity,and reducing free formaldehyde.Microcapsules were finished on the fabric with thermal storage and temperature regulation functions by padding,coating and melt spinning ways.Finally,the research direction was prospected in terms of MCPCM and pointed out that MCPCM with environmental protection,high density,high thermal stability and good thermal conductivity had a broad application prospect.
[1] 冷光辉,蓝志鹏,葛志伟,等.储热材料研究进展[J].储能科学与技术,2015,4(2):119-130.
[2] Sharma A,Tyagi V V,Chen C R,et al.Review on thermal energy storage with phase change materials and applications[J].Renewable & Sustainable Energy Reviews,2009,13(2):318-345.
[3] 师欢,王毅,冯辉霞,等.微胶囊相变材料研究进展[J].应用化工,2013,42(1):122-127.
[4] Zhao C Y,Zhang G H.Review on microencapsulated phase change materials (MEPCMs):fabrication,characterization and applications[J].Renewable & Sustainable Energy Reviews,2011,15(8):3813-3832.
[5] 李钰,邢建伟,陆少峰.微胶囊相变材料研究进展[J].粘接,2014(12):87-91.
[6] 史汝琨,王瑞,刘星,等.相变微胶囊调温织物的制备及其热性能研究[J].化工新型材料,2016,44(4):109-111.
[7] 史汝琨,王瑞,刘星,等.相变微胶囊/SMS智能调温织物的制备及性能研究[J].材料导报,2015,29(14):26-30.
[8] Lou Y H,Liu X Y,Liu X M,et al.Preparation and thermal transfer of phase change microcapsule on the fabric[J].Advanced Materials Research,2012,490-495(3):969-973.
[9] 李淑慧,邵竞尧,张鹏中,等.相变储能微胶囊的制备及其复合材料的研究进展[J].应用化工,2015,44(5):937-940.
[10] 魏堃,马骉.化学法制备相变材料微胶囊的研究进展[J].现代化工,2014,34(10):72-75.
[11] 申天伟,陆少锋,辛成,等.微胶囊相变材料的研究进展[J].纺织导报,2017(1):69-73.
[12] 马烽,李永超,陈明辉,等.密胺树脂/硬脂酸丁酯相变微胶囊的制备[J].材料工程,2010,31(7):42-45.
[13] Xin C,Tian Y,Wang Y,et al.Effect of curing temperature on the performance of microencapsulated low melting point paraffin using urea-formaldehyde resin as a shell[J].Textile Research Journal,2013,84(8):831-839.
[14] Yeliz Konuklu,Halime Paksoy O,Murat Unal,et al.Microencapsulation of a fatty acid with poly(melamine-urea-formaldehyde)[J].Energy Conversion & Management,2014,80(4):382-390.
[15] Li W,Wang J,Wang X,et al.Effects of ammonium chloride and heat treatment on residual formaldehyde contents of melamine-formaldehyde microcapsules[J].Colloid & Polymer Science,2007,285(15):1691-1697.
[16] Sumiga B,Knez E,Vrtačnik M,et al.Production of melamine-formaldehyde PCM microcapsules with ammonia scavenger used for residual formaldehyde reduction[J].Acta Chimica Slovenica,2011,58(1):14-25.
[17] Chen L,Xu L,Shang H,et al.Microencapsulation of butyl stearate as a phase change material by interfacial polycondensation in a polyurea system[J].Energy Conversion & Management,2009,50(3):723-729.
[18] 喻胜飞,罗武生.石蜡/聚脲相变微胶囊的制备及表征[J].材料工程,2015,43(7):100-104.
[19] Zhan S,Chen S,Chen L,et al.Preparation and characterization of polyurea microencapsulated phase change material by interfacial polycondensation method[J].Powder Technology,2016,292:217-222.
[20] Lu S,Shen T,Xing J,et al.Preparation and characterization of cross-linked polyurethane shell microencapsulated phase change materials by interfacial polymerization[J].Materials Letters,2018,211(15):36-39.
[21] Chen Z,Wang J,Yu F,et al.Preparation and properties of graphene oxide-modified poly(melamine-formaldehyde) microcapsules containing phase change material n-dodecanol for thermal energy storage[J].Journal of Materials Chemistry A,2015,3(21):11624-11630.
[22] Yang Y,Kuang J,Wang H,et al.Enhancement in thermal property of phase change microcapsules with modified silicon nitride for solar energy[J].Solar Energy Materials & Solar Cells,2016,151:89-95.
[23] Park S,Lee Y,Kim Y S,et al.Magnetic nanoparticle-embedded PCM nanocapsules based on paraffin core and polyurea shell[J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2014,450(1):46-51.
[24] 钱惺悦,纪俊玲,戴萍,等.微胶囊相变材料PCM在织物上的应用[J].印染,2014,40(7):12-15.
[25] Paula Sánchez,Victoria Sánchez Fernandez M,Romero A,et al.Development of thermo-regulating textiles using paraffin wax microcapsules[J].Thermochimica Acta,2010,498(1):16-21.
[26] Iqbal K,Sun D.Development of thermo-regulating polypropylene fibre containing microencapsulated phase change materials[J].Renewable Energy,2014,71(11):473-479.
[27] 辛成,陆少锋,申天伟,等.聚氨酯网状相变微胶囊的制备及在棉织物上的应用[J].现代化工,2018,38(8):126-131.