从电极表面成膜及钝化集流体等方面,分别阐述锰酸锂、镍锰酸锂、三元、富锂锰基这4种锰系正极材料常用电解液添加剂的作用机理,综述了锰系正极材料电解液添加剂的研究进展,指出深入研究电解液复合添加剂的协同作用,有助于提高锂离子电池的性能。
From the aspects of film formation on the electrode surface and the passivation of current collectors,the work mechanisms of electrolyte additives that usually used in four types of manganese-based anode materials(such as lithium manganate,lithium nickel manganese,ternary and lithium-rich manganese) were separately described,and reviewed the research progress of electrolyte additives for manganese-based anode materials.Besides,it was pointed out that the synergistic effect of electrolyte additives is studied in depth,which helps to improve the performance of lithium-ion batteries.
[1] 姚路.废旧锂离子电池正极材料回收再利用研究[D].新乡:河南师范大学,2016.
[2] 吴贤文.电解液对LiMn2O4和LiNi0.5Mn1.5O4电化学性能改善及其机理研究[D].长沙:中南大学,2013.
[3] Yamagiwa K,Morita D,Yabuuchi N,et al.Improved high-temperature performance and surface chemistry of graphite/LiMn2O4,Li-ion cells by fluorosilane-based electrolyte additive[J].Electrochimica Acta,2015,160:347-356.
[4] Wang R,Li X,Wang Z,et al.Manganese dissolution from LiMn2O4,cathodes at elevated temperature:methylene methanedisulfonate as electrolyte additive[J].Journal of Solid State Electrochemistry,2016,20(1):19-28.
[5] Wang R H,Li X,Wang Z,et al.Electrochemical analysis for cycle performance and capacity fading of lithium manganese oxide spinel cathode at elevated temperature using ptoluenesulfonyl isocyanate as electrolyte additive[J].Electrochimica Acta,2015,180:815-823.
[6] Dong T,Zhang S,Zhang L,et al.Improving cycling performance of LiMn2O4 battery by adding an ester-functionalized ionic liquid to electrolyte[J].Australian Journal of Chemistry,2015,68(12):1911-1917.
[7] Xu M,Zhou L,Dong Y,et al.Development of novel lithium borate additives for designed surface modification of high voltage LiNi0.5Mn1.5O4 cathodes[J].Energy & Environmental Science,2016,9(4):1308-1319.
[8] Liu J,Song X,Zhou L,et al.Fluorinated phosphazene derivative-a promising electrolyte additive for high voltage lithium ion batteries:from electrochemical performance to corrosion mechanism[J].Nano Energy,2018:S2211285518300971.
[9] Lin H B,Huang W Z,Rong H B,et al.Improving cyclic stability and rate capability of LiNi0.5Mn1.5O4,cathode via protective film and conductive polymer formed from thiophene[J].Journal of Solid State Electrochemistry,2015,19(4):1123-1132.
[10] Qi Xin,Blizanac B,Dupasquier A,et al.Influence of thermal treated carbon black conductive additive on the performance of high voltage spinel Cr-doped LiNi0.5Mn1.5O4 composite cathode electrode[J].Journal of the Electrochemical Society,2015,162(3):339-343.
[11] Yu Q,Chen Z,Xing L,et al.Enhanced high voltage performances of layered lithium nickel cobalt manganese oxide cathode by using trimethylboroxine as electrolyte additive[J].Electrochimica Acta,2015,176:919-925.
[12] Wang Z,Xing L,Li J,et al.Trimethyl borate as an electrolyte additive for high potential layered cathode with concurrent improvement of rate capability and cyclic stability[J].Electrochimica Acta,2015,184:40-46.
[13] Wang L,Ma Y,Wang P,et al.Interface modifications by tris (2,2,2-trifluoroethyl) borate for improving the high-voltage performance of LiNi1/3Co1/3Mn1/3O2/cathode[J].Journal of the Electrochemical Society,2017,164(9):1924-1932.
[14] He M,Su C C,Peebles C,et al.Mechanistic insight in the function of phosphite additives for protection of LiNi0.5Co0.2Mn0.3O2 cathode in high voltage Li-ion cells[J].ACS Applied Materials & Interfaces,2016,8(18):11450.
[15] Rong H,Xu M,Zhu Y,et al.A novel imidazole-based electrolyte additive for improved electrochemical performance of high voltage nickel-rich cathode coupled with graphite anode lithium ion battery[J].Journal of Power Sources,2016,332:312-321.
[16] He M,Su C C,Feng Z,et al.High voltage LiNi0.5Mn0.3Co0.2O2/graphite cell cycled at 4.6V with a FEC/HFDEC-based electrolyte[J].Advanced Energy Materials,2017,7(15):1700109.
[17] Li J,Xing L,Zhang L,et al.Insight into self-discharge of layered lithium-rich oxide cathode in carbonate-based electrolytes with and without additive[J].Journal of Power Sources,2016,324:17-25.
[18] Cameron Peebles,He Meinan,Feng Zhenxing,et al.Investigation of glutaric anhydride as an electrolyte additive for graphite/LiNi0.5Mn0.3Co0.2O2 full cells[J].Journal of the Electrochemical Society,2017,164(2):173-179.
[19] Nurpeissova A,Park D I,Kim S S,et al.Epicyanohydrin as an interface stabilizer agent for cathodes of Li-ion batteries[J].Journal of the Electrochemical Society,2015,163(2):171-177.
[20] Kang K S,Choi S,Song J H,et al.Effect of additives on electrochemical performance of lithium nickel cobalt manganese oxide at high temperature[J].Journal of Power Sources,2014,253:48-54.
[21] Deng B,Wang H,Ge W,et al.Investigating the influence of high temperatures on the cycling stability of a LiNi0.6Co0.2Mn0.2O2,cathode using an innovative electrolyte additive[J].Electrochimica Acta,2017,236:61-71.
[22] Qiu W,Xia J,Chen L,et al.A study of methyl phenyl carbonate and diphenyl carbonate as electrolyte additives for high voltage LiNi0.8Mn0.1Co0.1O2/graphite pouch cells[J].Journal of Power Sources,2016,318:228-234.
[23] Li J,Liu H,Xia J,et al.The impact of electrolyte additives and upper cut-off voltage on the formation of a rocksalt surface layer in LiNi0.8Mn0.1Co0.1O2 electrodes[J].Journal of the Electrochemical Society,2016,164(4):655-665.
[24] Zhou Z,Ma Y,Wang L,et al.Triphenyl phosphite as an electrolyte additive to improve the cyclic stability of lithium-rich layered oxide cathode for lithium-ion batteries[J].Electrochimica Acta,2016,216:44-50.
[25] Ma Y,Zhou Y,Du C,et al.A new anion receptor for improving the interface between lithium- and manganese-rich layered oxide cathode and the electrolyte[J].Chemistry of Materials,2017,29(5):2141-2149.
[26] Cha J,Han J G,Hwang J,et al.Mechanisms for electrochemical performance enhancement by the salt-type electrolyte additive,lithium difluoro(oxalato)borate,in high-voltage lithium-ion batteries[J].Journal of Power Sources,2017,357:97-106.
[27] Zheng X,Wang X,Cai X,et al.Constructing a protective interface film on layered lithium-rich cathode using an electrolyte additive with special molecule structure[J].ACS Applied Materials & Interfaces,2016,8(44):30116.
基金资助
国家自然科学基金(51502124、21766017);白银市科技计划项目(2017-2-11G)