TiO2纳米管负载改性方法研究进展

陈奇慧, 程凯, 王俊磊, 王雪芹*

化工新型材料 ›› 2019, Vol. 47 ›› Issue (9) : 28 -31.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (9) : 28-31.
综述与专论

TiO2纳米管负载改性方法研究进展

    陈奇慧, 程凯, 王俊磊, 王雪芹*
作者信息 +

Research progress on doping modification of TiO2 nanotube

  • Chen Qihui, Cheng Kai, Wang Junlei, Wang Xueqin
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文章历史 +
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摘要

TiO2纳米管作为一种几何结构规整、稳定性高、无毒的半导体光催化剂,受到科研人员的广泛关注。由于TiO2纳米管禁带宽度较宽,因此对可见光的吸收利用受到限制,光生电子-空穴对的再复合使得TiO2纳米管光生电子利用率较低。元素负载改性法可显著提高TiO2纳米管光生电子利用率并拓宽其光吸收范围,而元素负载方法是成功实现元素负载并调控TiO2纳米管反应活性的重要手段之一。综述了浸渍法、电化学沉积法、光化学沉积法、化学气相沉积法、离子溅射法和化学浴沉积法等用于负载改性TiO2纳米管的方法,并展望了其未来发展方向。

Abstract

TiO2 nanotubes has attracted great attentions due to its uniform geometric structure,high stability and non-toxic properties.However,the band gap limits its absorption and utilization of visible light,and the high recombination rate suppresses the utilization of photogenerated electrons and holes.Modification of TiO2 nanotubes by loading other elements can significantly increase its photoelectron utilization rate and expand its light absorption range.The research progress on doping TiO2 nanotubes by impregnation,electrochemical deposition,photochemical deposition,chemical vapor deposition,ion sputtering and chemical bath deposition were overviewed.Finally,the future development of TiO2 nanotubes was also prospected.

关键词

TiO2纳米管 / 负载改性 / 光催化 / 反应活性

Key words

TiO2 nanotube / modification / photocatalysis / reaction activity

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TiO2纳米管负载改性方法研究进展[J]. 化工新型材料, 2019, 47(9): 28-31 DOI:

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参考文献

[1] Ghicov A,Schmuki P.Self-ordering electrochemistry:a review on growth and functionality of TiO2 nanotubes and other self-aligned MO(x) structures[J].Chemical Communications,2009,40(32):2791-2808.
[2] Hoffmann M R,Choi W,Bahnemann D W.Environmental applications of semiconductor photocatalysis[J].Chemical Reviews,1995,95(1):69-96.
[3] Fujishima A,Zhang X,Tryk D A.TiO2 photocatalysis and related surface phenomena[J].Surface Science Reports,2008,63(12):515-582.
[4] Xie Y.Photoelectrochemical application of nanotubular titania photoanode[J].Electrochimica Acta,2006,51(17):3399-3406.
[5] Akbarzadeh R,Umbarkar S B,Sonawane R S,et al.Vanadia-titania thin films for photocatalytic degradation of formaldehyde in sunlight[J].Applied Catalysis A:General,2010,374(1):103-109.
[6] Mazierski P,Nischk M,Golkowska M,et al.Photocatalytic activity of nitrogen doped TiO2 nanotubes prepared by anodic oxidation:the effect of applied voltage,anodization time and amount of nitrogen dopant[J].Applied Catalysis B:Environmental,2016,11(196):77-88.
[7] Xu Y,Lv K,Xiong Z,et al.Rate enhancement and rate inhibition of phenol degradation over irradiated anatase and rutile TiO2 on the addition of NaF:new insight into the mechanism[J].Journal of Physical Chemistry C,2007,111(111):19024-19032.
[8] Fujishima A,Zhang X,Tryk D A.Heterogeneous photocatalysis:from water photolysis to applications in environmental cleanup[J].International Journal of Hydrogen Energy,2007,32(14):2664-2672.
[9] Paulose M,Mor G K,Varghese O K,et al.Visible light photoelectrochemical and water-photoelectrolysis properties of titania nanotube arrays[J].Journal of Photochemistry and Photobiology A:Chemistry,2006,178(1):8-15.
[10] 刘雅琼,杨德凤,朱新宇.锌铁氧化物共复合二氧化钛纳米管的制备及其CO2光电催化还原性能[J].石油炼制与化工,2017,48(10):95-100.
[11] 沈悠曲,王德平,叶松.载银TiO2纳米管阵列的制备及性能(英文)[J].硅酸盐学报,2014,42(3):402-408.
[12] Yang H,Zhang K.Sol-gel synthesis of TiO2 nanoparticles and photocatalytic degradation of methyl orange in aqueous TiO2 suspensions[J].Journal of Alloys and Compounds,2006,413(1/2):302-306.
[13] Wang C,Ying J Y.Sol-gel synthesis and hydrothermal processing of anatase and rutile titania nanocrystals[J].Chemistry of Materials,2012,11(11):3113-3120.
[14] Nah Y C,Paramasivam I,Schmuki P.Doped TiO2 and TiO2 nanotubes:synthesis and applications[J].Chemphyschem,2010,11(13):2698-2713.
[15] 张煜,刘兆阅,翟锦.Cu2O/TiO2纳米管阵列异质结的制备及其可见光光电响应性质[J].化学学报,2013,71(5):793-797.
[16] Liang F,Zhang J,Zheng L,et al.Selective electrodeposition of Ni into the intertubular voids of anodic TiO2 nanotubes for improved photocatalyticproperties[J].Journal of Materials Research,2013,28(3):405-410.
[17] Wang C,Sun L,Yun H,et al.Sonoelectrochemical synthesis of highly photoelectrochemically active TiO2 nanotubes by incorporating CdS nanoparticles[J].Nanotechnology,2009,20(29):295601.
[18] Wang Y,Zhang X.Enhanced electrochemical capacitance of NiO loaded on TiO2 nanotubes[J].Journal of the Electrochemical Society,2005,152(152):A671-A676.
[19] Cao C,Hu C,Tian J,et al.Pt nanoparticles supported inside TiO2 nanotubes for effective ethanol electrooxidation[J].Journal of the Electrochemical Society,2013,160(11):793-799.
[20] Chien S H,Liou Y C,Kuo M.Preparation and characterization of nanosized Pt/Au particles on TiO2-nanotubes[J].Synthetic Metals,2005,152(1):333-336.
[21] 廖斌,梁宏,张旭,等.光化学沉积Ag纳米颗粒改性二氧化钛纳米管阵列的光催化及光电响应能力研究[J].北京师范大学学报:自然科学版,2011,47(2):154-158.
[22] Agarwal P,Paramasivam I,Shrestha N K,et al.MoO3 in self-organized TiO2 nanotubes for enhanced photocatalytic activity[J].Chemistry-An Asian Journal,2010,5(1):66-69.
[23] 苏雅玲,李轶,杜瑛珣,等.氟掺杂TiO2纳米管的可见光催化活性及第一性原理计算(英文)[J].物理化学学报,2011,27(4):939-945.
[24] Park J H,Kim S,Bard A J.Novel carbon-doped TiO2 nanotube arrays with high aspect ratios for efficient solar water splitting[J].Nano Letters,2006,6(1):24.
[25] Varghese O K,Gong D,Paulose M,et al.Hydrogen sensing using titania nanotubes[J].Sensors and Actuators B:Chemical,2003,93(1/2/3):338-344.
[26] 姜艳丽,刘惠玲,田玫,等.离子溅射沉积法制备Pt-TiO2/Ti催化剂及其性能研究[C].中国功能材料及其应用学术会议,2007:2412-2414.
[27] Ghicov A,Macak J M,Tsuchiya H,et al.Ion implantation and annealing for an efficient N-doping of TiO2 nanotubes[J].Nano Letters,2006,6(5):1080-1082.
[28] 李亭,王罗春,陈冠翰,等.WO3-TiO2改性TiO2纳米管的制备与光催化性能[J].环境工程学报,2016,10(8):4309-4313.

基金资助

黑龙江省自然科学基金项目(QC2017005);东北石油大学校青年基金项目(NEPUBS201508);东北石油大学“国家基金”培育基金项目(2017PYQZL-06);东北石油大学校科研启动经费资助项目

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