双金属类MOF材料的制备及应用

牛照栋1, 周玲玲1, 关清卿1, 陈秋玲1, 庙荣荣1, 季炜1, 何亮2*

化工新型材料 ›› 2019, Vol. 47 ›› Issue (8) : 5 -8.

PDF (1134KB)
化工新型材料 ›› 2019, Vol. 47 ›› Issue (8) : 5-8.
综述与专论

双金属类MOF材料的制备及应用

    牛照栋1, 周玲玲1, 关清卿1, 陈秋玲1, 庙荣荣1, 季炜1, 何亮2*
作者信息 +

Preparation and application of bimetallic MOFs

  • Niu Zhaodong1, Zhou Lingling1, Guan Qingqing1, Chen Qiuling1, Miao Rongrong1, Ji Wei1, He Liang2
Author information +
文章历史 +
PDF (1160K)

摘要

金属有机骨架(MOFs)是一种多孔材料,具有较高的孔隙率、大的比表面积和均匀分散的活性位点等特性,得到了研究者的广泛关注。主要介绍了双金属类MOFs材料的制备方法,及其在气体储存和非均相催化等领域的应用。其中,着重介绍了掺杂的金属活性组分对二氧化碳(CO2)的吸附及苯酚催化加氢的作用机理,并展望了未来的发展前景。

Abstract

Metal-organic frameworks (MOFs) is a porous material with high porosity,large specific surface area and uniformly dispersed active sites,and have been attracted attentions for researchers.The major research direction of bimetallic MOFs materials preparation and its application in gas storage and heterogeneous catalysis were reviewed.The adsorption mechanisms of CO2 and the catalytic hydrogenation of phenol by doping metal active components were analyzed,and the prospect of its development was also given.

关键词

双金属有机骨架 / 二氧化碳 / 非均相催化

Key words

bimetallic MOFs / CO2 / heterogeneous catalysis

引用本文

引用格式 ▾
双金属类MOF材料的制备及应用[J]. 化工新型材料, 2019, 47(8): 5-8 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] M-Nguez E G,Coronado E.Magnetic functionalities in MOFs:from the framework to the pore[J].Chemical Society Reviews,2018,47(2):533-557.
[2] He T,Xu X,Ni B,et al.Fast and scalable synthesis of uniform zirconium-,hafnium-based metal-organic framework nanocrystals[J].Nanoscale,2017,9(48):19209-19215.
[3] Smj R,Bavykina A,Hajek J,et al.Metal-organic and covalent organic frameworks as single-site catalysts[J].Chemical Society Reviews,2017,46(11):3134-3184.
[4] Easun T L,Moreau F,Yan Y,et al.Structural and dynamic studies of substrate binding in porous metal-organic frameworks[J].Chemical Society Reviews,2016,46(11):239-274.
[5] 谷俊杰,王彬,牛照栋,等.金属有机骨架材料的合成及其催化应用[J].昆明理工大学学报(自然科学版),2017,42(4):87-93.
[6] 牛照栋,关清卿,陈秋玲,等.膦酸类金属-有机骨架材料对CO2的吸附性能研究进展[J].化工进展,2017,36(5):1782-1790.
[7] 周玲玲,汤立红,宁平,等.金属有机骨架材料在气体吸附与分离中的应用研究进展[J].材料导报,2017,31(19)112-121.
[8] Hu Z,Zhao D.Metal-organic frameworks with lewis acidity:synthesis,characterization,and catalytic applications[J].Crystengcomm,2017,19(29)4066-4081.
[9] Fujita M,Kwon Y J,Washizu S,et al.Preparation,clathration ability,and catalysis of a two-dimensional square network material composed of cadmium(Ⅱ) and 4,4′-bipyridine[J].Journal of the American Chemical Society,1994,116(3):1151-1152.
[10] Bhattacharjee S,Lee Y R,Puthiaraj P,et al.metal-organic frameworks for catalysis[J].Catalysis Surveys from Asia,2015,19(4):203-222.
[11] Falcaro P,Ricco R,Yazdi A,et al.Application of metal and metal oxide nanoparticles@MOFs[J].Coordination Chemistry Reviews,2016,307:237-254.
[12] Guan Q,Wang B,Chai X,et al.Comparison of Pd-UiO-66 and Pd-UiO-66-NH2 catalysts performance for phenol hydrogenation in aqueous medium[J].Fuel,2017,205:130-141.
[13] Eerahim A M,Bandosz T J.Ce(Ⅲ) doped Zr-Based MOFs as excellent NO2 adsorbents at ambient conditions[J].ACS Applied Materials & Interfaces,2013,5(21):10565-10573.
[14] Hoskins B F,Robson R.Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods.A reappraisal of the Zn(CN)2 and Cd(CN)2 structures and the synthesis and structure of the diamond-related frameworks[J].Journal of the American Chemical Society,1990,112(4):1199-1205.
[15] Cohen S M.Postsynthetic methods for the functionalization of metal-organic frameworks[J].Chemical Reviews,2012,112(2):970-1000.
[16] Gardner G B,Venkataraman D,Moore J S,et al.Spontaneous assembly of a hinged coordination network[J].Nature,1995,374(6525):792-795.
[17] Kubo M,Shimojima A,Okubo T.Effect of lithium doping into MIL-53(Al) through thermal decomposition of anion species on hydrogen adsorption[J].Journal of Physical Chemistry C,2012,116(18):10260-10265.
[18] Song X,Kim T K,Kim H,et al.Post-synthetic modifications of framework metal ions in isostructural metal-organic frameworks:core-shell heterostructures via selective transmetalations[J].Chemistry of Materials,2012,24(15):3065-3073.
[19] Song X,Oh M,Lah M S.Hybrid bimetallic metal-organic frameworks:modulation of the framework stability and ultralarge CO2 uptake capacity[J].Inorganic Chemistry,2013,52(19):10869-10876.
[20] Zhou Z,Mei L,Ma C,et al.A novel bimetallic MIL-101(Cr,Mg) with high CO2 adsorption capacity and CO2/N2 selectivity[J].Chemical Engineering Science,2016,147:109-117.
[21] Li R,Ren X,Feng X,et al.A highly stable metal- and nitrogen-doped nanocomposite derived from Zn/Ni-ZIF-8 capable of CO2 capture and separation[J].Chemical Communications,2014,50(52):6894-6897.
[22] Kim H R,Yoon T U,Kim S I,et al.Beyond pristine MOFs:carbon dioxide capture by metal-organic frameworks (MOFs)-derived porous carbon materials[J].RSC Advances,2017,7(3):1266-1270.
[23] Zhao C,Song W,Lercher J A.Aqueous phase hydroalkylation and hydrodeoxygenation of phenol by dual functional catalysts comprised of Pd/C and H/La-BEA[J].ACS Catalysis,2012,2(12):2714-2723.
[24] Zhang D,Guan Y,Hensen E J M,et al.Porous MOFs supported palladium catalysts for phenol hydrogenation:a comparative study on MIL-101 and MIL-53[J].Catalysis Communications,2013,41(21):47-51.
[25] Claus L P,Berndt H,Mohr C,et al.Pd/MgO:catalyst characterization and phenol hydrogenation activity[J].Journal of Catalysis,2000,192(1):88-97.
[26] Guan Q,Zeng Y,Shen J,et al.Selective hydrogenation of phenol by phosphotungstic acid modified Pd/Ce-AlOx catalyst in high-temperature water system[J].Chemical Engineering Journal,2016,299:63-73.
[27] Li A,Shen K,Chen J,et al.Highly selective hydrogenation of phenol to cyclohexanol over MOF-derived non-noble Co-Ni@NC catalysts[J].Chemical Engineering Science,2017,166:66-76.

基金资助

国家自然科学基金(21767015)

AI Summary AI Mindmap
PDF (1134KB)

2321

访问

0

被引

导航
相关文章

AI思维导图

/