有机π-共轭材料在光学、电学、磁性、催化和化学传感等领域有着广泛的应用,是当今材料科学研究的热点之一。将磷原子引入有机共轭体系,能够显著地改变分子的电子结构从而达到调控其光学与电子性能的目的,因此有机磷功能材料的开发备受关注。近年来,含有膦烯特征单元的共轭体系,因其展现出显著的发光性能而引起了较多的研究。综述了含磷烯有机π-共轭发光材料的研究工作,并展望了此类功能材料的发展及应用趋势。
Organic π-conjugated materials have broad applications in fields of optics,electricity,magnetics,catalysis and chemical sensors,etc.Introduction of phosphorus into conjugated systems can significantly affect the electronic structure of molecules that improve the optical and electronic nature,thus the research of organophosphorus functional materials has become an active area.Recently,conjugated system featuring phosphaalkene units have inspired many studies due to their noteworthy luminescence.Representative research in the field of luminescent organic π-conjugated materials with phosphaalkene units was summarized,and the development and application trends were also prospected.
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基金资助
安徽省自然科学基金(1608085QB42);安徽省留学人员科技活动择优资助项目(2015);国家级大学生创新创业计划项目(201710361071)
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