高压正极材料磷酸镍锂研究进展

王华丹, 贡纬华, 苏毅*, 李国斌

化工新型材料 ›› 2019, Vol. 47 ›› Issue (7) : 13 -16.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (7) : 13-16.
综述与专论

高压正极材料磷酸镍锂研究进展

    王华丹, 贡纬华, 苏毅*, 李国斌
作者信息 +

Research progress on lithium nickel phosphate high voltage anode material

  • Wang Huadan, Gong Weihua, Su Yi, Li Guobin
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摘要

目前用于锂离子电池商业生产的正极材料已很难适应当今的能源供应需求。近年来,磷酸镍锂(LiNiPO4)因较高的氧化还原电位,大的比容量和高能量密度受到越来越多的关注。尽管如此,LiNiPO4在电子传导以及纯相制备等方面仍存在一定问题。综述了LiNiPO4的研究进展,介绍了LiNiPO4的结构特点及制备方法,并对其发展前景进行了展望。

Abstract

The anode materials currently used in the commercial production of lithium ion batteries have been difficult to adapt to today‘s energy supply needs.In recent years,LiNiPO4 has received more and more attention due to its high oxidation-reduction potential,large specific capacity and energy density.Despite this,LiNiPO4 still has certain deficiencies in terms of electron conduction and pure phase preparation.The latest research progress of LiNiPO4 was reviewed.The structural characteristics and preparation methods of LiNiPO4 were introduced,and prospected the development prospects.

关键词

锂离子电池 / 正极材料 / 磷酸镍锂 / 研究 / 进展

Key words

lithium ion battery / anode material / lithium nickel phosphate / research / progress

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高压正极材料磷酸镍锂研究进展[J]. 化工新型材料, 2019, 47(7): 13-16 DOI:

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参考文献

[1] Prabu M,Selvasekarapandian S,Kulkarni A R,et al.Influence of europium doping on conductivity of LiNiPO4[J].Transactions of Nonferrous Metals Society of China,2012,22(2):342-347.
[2] Wolfenstine J,Allen J.Ni3+/Ni2+,redox potential in LiNiPO4[J].Journal of Power Sources,2005,142(1/2):389-390.
[3] Amine K,Yasuda H,Yamachi M.Olivine LiCoPO4 as 4.8V electrode material for Lithium batteries[J].Electrochemical and Solid-State Letters,2000,3(4):178-179.
[4] Howard W F,Spotnitz R M.Theoretical evaluation of high-energy lithium metal phosphate cathode materials in Li-ion batteries[J].Journal of Power Sources,2007,165(2):887-891.
[5] Biendicho J J,West A R.Thermally-induced cation disorder in LiFePO4[J].Solid State Ionics,2011,203(1):33-36.
[6] Fisher C A J,Prieto V M H,Islam M S.Lithium battery materials LiMPO4(M=Mn,Fe,Co,and Ni):insights into defect association,transport mechanisms,and doping behavior[J].Chemistry of Materials,2008,20(18):5907-5915.
[7] Minakshi M,Singh P,Appadoo D,et al.Synthesis and characterization of olivine LiNiPO4,for aqueous rechargeable battery[J].Electrochimica Acta,2011,56(11):4356-4360.
[8] Toprakci O,Toprakci H A K,Ji L,et al.Fabrication and electrochemical characteristics of LiFePO4 powders for Lithium-ion batteries[J].KONA Powder and Particle Journal,2010,28(3):50-73.
[9] Megaw H D,Templeton D H.Crystal structures:a working approach[J].Physics Today,1974,27(9):53-54.
[10] 黄映恒,蓝建京,童张法,等.含锂磷酸盐LiMPO4(M=Mn、Co、Ni)的制备方法[J].化学工程师,2009,23(6):40-44.
[11] Karthickprabhu S,Hirankumar G,Maheswaran A,et al.Structural and conductivity studies on LiNiPO4,synthesized by the polyol method[J].Journal of Alloys & Compounds,2013,548(3):65-69.
[12] Prabu M,Selvasekarapandian S,Kulkarni A R,et al.Structural,dielectric,and conductivity studies of yttrium-doped LiNiPO4,cathode materials[J].Ionics,2011,17(3):201-207.
[13] Rommel S M,Schall N,Bruenig C,et al.Cheminform abstract:challenges in the synthesis of high voltage electrode materials for lithium-ion batteries:a review on LiNiPO4[J].Cheminform,2014,145(3):385-404.
[14] Delacourt C,Poizot P,Morcrette M,et al.One-step low-temperature route for the preparation of electrochemically active LiMnPO4 powders[J].Cheminform,2004,35(13):93-99.
[15] Nedoseykina T,Min G K,Park S A,et al.0.64 material[J].Electrochimica Acta,2010,55(28):8876-8882.
[16] Herle P S,Ellis B,Coombs N,et al.Nano-network electronic conduction in iron and nickel olivine phosphates[J].Nature Materials,2004,3(3):147-52.
[17] Kandhasamy S,Pandey A,Minakshi M.Polyvinylpyrrolidone assisted sol-gel route LiCo1/3Mn1/3Ni1/3PO4,composite cathode for aqueous rechargeable battery[J].Electrochimica Acta,2012,60(1):170-176.
[18] Ornek A,Bulut E,Can M.Influence of gradual cobalt substitution on lithium nickel phosphate nano-scale composites for high voltage applications[J].Materials Characterization,2015,106(3):152-162.
[19] Fisher C A J,Prieto V M H,Islam M S.Lithium battery materials LiMPO4(M=Mn,Fe,Co,and Ni):insights into defect association,transport mechanisms,and doping behavior[J].Chemistry of Materials,2008,20(18):5907-5915.
[20] Wolfenstine J,Allen J.LiNiPO4-LiCoPO4,solid solutions as cathodes[J].Journal of Power Sources,2004,136(1):150-153.
[21] Tabassam L,Giuli G,Moretti A,et al.Structural study of LiFePO4-LiNiPO4 solid solutions[J].Journal of Power Sources,2012,31(1/2):56-78.
[22] Tucker M C,Doeff M M,Richardson T J,et al.7Li and 31P magic angle spinning nuclear magnetic resonance of LiFePO4-type materials[J].Electrochemical and Solid-State Letters,2002,5(5):A95-A98.
[23] 魏广科,陈桂敏,盛锁江.高电压LiNiPO4正极材料合成改性及研究进展[J].电池工业,2017,21(6):38-43.
[24] Bechir M B,Rhaiem A B,Guidara K.A.c.conductivity and dielectric study of LiNiPO4,synthesized by solid-state method[J].Bulletin of Materials Science,2014,37(3):473-480.
[25] Rommel S M,Rothballer J,Schall N,et al.Characterization of the carbon-coated LiNi1-yCoyPO4,solid solution synthesized by a non-aqueous sol-gel route[J].Ionics,2015,21(2):325-333.
[26] Ouml,Rnek A.Optimization of dielectric heating parameters in the production of high-voltage LiNiPO4-core and carbon-shell ceramics[J].Journal of the American Ceramic Society,2017,100(12):5668-5680.
[27] Xu J,Lai C,Wang B,et al.Modification of LiNiPO4 by metal doping and carbon coating[C]//International Conference on Materials for Renewable Energy & Environment.IEEE,2011:708-711.
[28] Minakshi M,Singh P,Ralph D,et al.Structural characteristics of olivine Li(Mg0.5Ni0.5)PO4,via TEM analysis[J].Ionics,2012,18(6):583-590.
[29] Fujimoto D,Lei Y,Huang Z H,et al.Synthesis and electrochemical performance of LiMnPO4 by hydrothermal method[J].International Journal of Electrochemistry,2014,2014(5):1-9.
[30] Cheruku R,Govindaraj G.Structural and electrical conductivity studies of nanocrystalline olivine type LiNiPO4 material[J].International Journal of Chemtech Research,2014,6(3):2017-2019.
[31] Sanusi A,Navaratnam S,Basirun W J.Synthesis of nanocrystalline olivine LiNiPO4 powder prepared by sol-gel method:thermal analysis and XRD studies[J].Malaysian Journal of Analytical Sciences,2014,18(3):522-526.
[32] Dimesso L,Spanheimer C,Jaegermann W.Investigation of graphitic carbon foams/LiNiPO4 composites[J].Journal of Solid State Electrochemistry,2012,16(12):3791-3798.
[33] Shanmukaraj D,Murugan R.Synthesis and characterization of LiNiyCo1-yPO4,(y=0-1) cathode materials for lithium secondary batteries[J].Ionics,2004,10(1/2):88-92.
[34] Vadivel M A,Muraliganth T,Ferreira P J,et al.Dimensionally modulated,single-crystalline LiMPO4(M=Mn,Fe,Co,and Ni) with nano-thumblike shapes for high-power energy storage[J].Inorganic Chemistry,2009,48(3):946-952.
[35] Ornek A.Influences of different reaction mediums on the properties of high-voltage LiNiPO4 @C cathode material in terms of dielectric heating efficiency[J].Electrochimica Acta,2017,258(2):524-534.
[36] Ornek A,Kazancioglu M Z.A novel and effective strategy for producing core-shell LiNiPO4/C cathode material for excellent electrochemical stability using a long-time and low-level microwave approach[J].Scripta Materialia,2016,122(2):45-49.
[37] Vijayan L,Cheruku R,Govindaraj G.Electrical,optical and magnetic investigations on LiNiPO4,based olivines synthesized by solution combustion technique[J].Materials Research Bulletin,2014,50(2):341-347.
[38] 刘竞雅.5V高电压锂离子电池阴极材料研究进展[J].电源世界,2012(1):53-57.

基金资助

国家自然科学基金项目(21666015)

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