纳米无机粒子协同聚磷酸铵阻燃高分材料的研究进展

高喜平1,2, 李小童3, 齐晨晨1, 张兴刚2, 陆昶1*, 张用兵2

化工新型材料 ›› 2019, Vol. 47 ›› Issue (5) : 27 -31.

PDF (1160KB)
化工新型材料 ›› 2019, Vol. 47 ›› Issue (5) : 27-31.
综述与专论

纳米无机粒子协同聚磷酸铵阻燃高分材料的研究进展

    高喜平1,2, 李小童3, 齐晨晨1, 张兴刚2, 陆昶1*, 张用兵2
作者信息 +

Research progress of synergistic flame retarded polymer material with APP and nano inorganic particle

  • Gao Xiping1,2, Li Xiaotong3, Qi Chenchen1, Zhang Xinggang2, Lu Chang1, Zhang Yongbing2
Author information +
文章历史 +
PDF (1187K)

摘要

综述了近年来纳米无机粒子用作聚磷酸铵(APP)阻燃协效剂对高分子材料阻燃改性的研究现状和进展,介绍了几种无机纳米粒子(包括纳米蒙脱土、纳米SiO2、纳米CaCO3、碳纳米管和石墨烯)的阻燃特点,并指出今后纳米无机粒子协同阻燃的发展方向。

Abstract

The recent research progress of nano inorganic particles used as flame retardant synergists of ammonium polyphosphate (APP) in flame-retardant polymers was reviewed.The flame retardant characteristicses of nano inorganic particles such as nano-montmorillonite,nano silica,nano calcium carbonate,carbon nanotubes,grapheme were introduced respectively,and then the development trend of nano inorganic particles as the flame retardant synergists in future was prospected.

关键词

聚磷酸铵 / 纳米无机粒子 / 无卤阻燃 / 协同效应

Key words

ammonium polyphosphate / nano inorganic particle / halogen-free flame retardancy / synergistic effect

引用本文

引用格式 ▾
纳米无机粒子协同聚磷酸铵阻燃高分材料的研究进展[J]. 化工新型材料, 2019, 47(5): 27-31 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 孟小庆,周志明,董立春,等.石墨烯在聚合物中的阻燃应用研究[J].化工新型材料,2016,44(11):8-10.
[2] Guo J B,He M,Li Q F,et al.Synergistic effect of organo-montmorillonite on intumescent flame retardant ethyleneoctene copolymer[J].Journal of Applied Polymer Science,2013,129(4):2063-2069.
[3] 于立娟,孙鹏,李广义,等.阻燃剂的研究进展[J].上海塑料,2013(3):21-24.
[4] Ba M W,Liang B,Wang C S.Synthesis and characterization of a novel charring agent and its application in intumescent flame retardant polyethylene system[J].Fibers and Polymers,2017,18(5):907-914.
[5] 王增加,李辅安,李翠云.阻燃剂的研究进展[J].化工新型材料,2004,32(10):11-13.
[6] Makhlou G,Hassan M,Nour M,et al.A novel intumescent flame retardant:synthesis and its application for linear low-density polyethylene[J].Arabian Journal for Science and Engineering,2017,42(10):4339-4349.
[7] 李福君,屈皓,范瑞兰.磷-氮膨胀型阻燃剂的研究与应用[J].化工新型材料,2015,43(10):237-239.
[8] 屈红强,武君琪,刘磊,等.聚磷酸铵阻燃剂表面改性研究进展[J].中国塑料,2012,26(12):93-97.
[9] Demir H,Arkis E,Balkose D,et al.Synergistic effect of natural zeolites on flame retardant additives[J].Polymer Degradation and Stability,2005,89(3):478-483.
[10] Lewin M.Some comments on the modes of action of nanocomposites in the flame retardancy of polymers[J].Fire and Materials,2003,27(1):1-7.
[11] 叶春雪,杨荣杰,仪德启.钙基纳米蒙脱土/聚磷酸铵复合物的结构与性质[J].复合材料学报,2013,30(3):1-6.
[12] Suparanon T,Surisaeng J,Phusunti N,et al.Synergistic efficiency of tricresyl phosphate and montmorillonite on the mechanical characteristics and flame retardant properties of polylactide and poly(butylene succinate) blends[J].Chinese Journal of Polymer Science,2018,36:620-631.
[13] 夏建盟,杨友强,姜向新.高效耐水无卤阻燃聚丙烯材料研究[J].塑料工业,2015,43(10):109-112.
[14] 丁耀莹,仪德启,杨荣杰.耐水型膨胀阻燃剂对阻燃聚丙烯性能的影响[J].合成树脂及塑料,2016,33(5):7-10.
[15] 洪晓东,秦昌强,赵爽,等.纳米MMT对APP/MCA复合阻燃EP性能的影响[J].工程塑料应用,2014,42(6):26-30.
[16] Wang Y H,Zhang S,Wu X M,et al.Effect of montmorillonite on the flame-resistant and mechanical properties of intumescent flame-retardant poly(butylenes succinate) composites[J].Journal of Thermal Analysis and Calorimetry,2017,128(3):1417-1427.
[17] Pang H C,Ning G L,Tian P,et al.Nanoengineering of brucite@SiO2 for enhanced mechanical properties and flame retardant behaviors[J].Polymer Degradation and Stability,2015,120:410-418.
[18] Jiao C M,Chen X L.Influence of fumed silica on the flame-retardant properties of ethylene vinyl acetate/aluminum hydroxide composites[J].Journal of Applied Polymer Science,2011,120(3):1285-1289.
[19] Zhou S J,Qian Y,Chen X L,et al.In situ synthesis of layered double hydroxides-silicon dioxide hybrids and its flame retardancy in EVA composites[J].Journal of Thermal Analysis and Calorimetry,2018,doi:10.1007/s10973-018-7331-7.
[20] 岳小鹏,蔺奕存.EVA/纳米SiO2阻燃复合材料的性能研究[J].陕西科技大学学报,2017,35(2):50-55.
[21] 俞纪贤,杨文,徐卫兵,等.纳米二氧化硅增强增韧膨胀型阻燃共聚聚丙烯性能的研究[J].塑料助剂,2015(3):33-38.
[22] Yang K,Xu M J,Li B.Synthesis of N-ethyl triazine-piperazine copolymer and flame retardancy and water resistance of intumescent flame retardant polypropylene[J].Polymer Degradation and Stability,2013,98(7):1397-1406.
[23] Chen X L,Jiang Y F,Liu J B,et al.Smoke suppression properties of fumed silica on flame-retardant thermoplastic polyurethane based on ammonium polyphosphate[J].Journal of Thermal Analysis and Calorimetry,2015,120:1-12.
[24] 任宇婷,许苗军,高冉,等.碳酸钙/甲基乙基硅橡胶对EBA的阻燃及热降解行为[J].塑料,2014,43(2):68-71.
[25] Shah A U R,Prabhakar M N,Song J.Current advances in the fire retardancy of natural fiber and bio-based composites-A review[J].International Journal of Precision Engineering and Manufacture-Green Technology,2017,4(2):247-262.
[26] 李驰祥,姜修磊,刘涛,等.纳米碳酸钙/IFR对聚丙烯发泡材料的协效阻燃[J].塑料,2015,45(2):40-43.
[27] 杨守生,王学宝,陈英辉.膨胀阻燃剂/CaCO3协效阻燃环氧树脂[J].消防科学与技术,2013,32(2):194-196.
[28] Kaseem M,Hamad K,Deri F,et al.A review on recent researches on polylactic acid/carbon nanotube composites[J].Polymer Bulletin,2017,74:2921-2937.
[29] 毕波,王学宝.纳米碳材料在聚合物阻燃中的应用研究进展[J].材料工程,2017,45(5):135-144.
[30] Durkin D P,Gallagher M J,Frank B P,et al.Phosphorus-functionalized multi-wall carbon nanotubes as flame-retardant additives for polystyrene and poly(methyl methacrylate)[J].Journal of Thermal Analysis and Calorimetry,2017,130:735-753.
[31] Hesami M,Bagheri R,Masoomi M.Combination effects of carbon nanotubes,MMT and phosphorus flame retardant on fire and thermal resistance of fiber-reinforced epoxy composites[J].Iranian Polymer Journal,2014,23(6):469-476.
[32] 王东卫,赵强,张潇娴,等.碳纳米管/高分子阻燃复合材料研究进展[J].化工新型材料,2012,40(7):4-6.
[33] Yan L,Xu Z S,Zhang J.Flame retardant and smoke suppression mechanism of multi-walled carbon nanotubes on high-impact polystyrene nanocomposites[J].Iranian Polymer Journal,2016,25(7):623-633.
[34] 周磊,李东泽,于燕燕,等.包覆CNT和膨胀阻燃剂在聚丙烯基体中的协效阻燃性[J].塑料工业,2015,43(6):101-105.
[35] 王芳,郝建薇,李茁实,等.碳材料表面特性及形貌对阻燃环氧树脂燃烧和热解行为的影响[J].高分子学报,2016(7):860-870.
[36] Chen G K,Zhao X L,Shi C L.Synergistic effect between carbon nanoparticle and intumescent flame retardant on flammability and smoke suppression of copolymer thermoplastic polyurethane[J].Journal of Materials Science,2018,53(8):6053-6064.
[37] Sang B,Li Z W,Li X H et al.Graphene-based flame retardants:a review[J].Journal of Materials Science,2016,51(18):8271-8295.
[38] 陈南,钟贵林,张国峰.石墨烯在聚合物阻燃材料中的应用及作用机理[J].应用化学,2018,35(3):307-316.
[39] Yan W,Zhang M Q,Yu J,et al.Synergistic flame-retardant effect of epoxy resin combined with phenethyl-bridged DOPO derivative and graphene nanosheets[J].Chinese Journal of Polymer Science,2018,doi:10.1007/s10118-019-2175-6.
[40] 刘迪,梁兵,王长松.无卤阻燃环氧树脂的性能研究[J].化工新型材料,2018,46(2):63-66.
[41] 洪晓东,林海云.改性氧化石墨烯协同聚磷酸铵阻燃环氧树脂的性能[J].工程塑料应用,2015,43(9):35-39.

基金资助

国家自然科学基金(51673059);河南省科技攻关项目(182102210290);河南省高等学校重点科研项目(17A150009);河南科技大学SRTP项目(2018145);河南科技大学博士启动基金(13480052)

AI Summary AI Mindmap
PDF (1160KB)

1177

访问

0

被引

导航
相关文章

AI思维导图

/