随着人们生活水平的提高,传统涂料已经难以满足人们的需求。由于纳米材料具有许多特殊的性能,将其运用到涂料中可以显著提高涂料的性能并赋予涂料新的功能。介绍了纳米材料的几种改性方法,综述了纳米材料在隔热涂料、抗菌涂料、抗老化涂料、防腐涂料和超疏水涂料中的应用并对该领域的研究进行了展望。
With the improvement of people's living standards,traditional coatings have been difficult to meet the needs of people.Nanomaterial can significantly improve the performance of coatings and give coatings new functions due to its special properties.Several modification methods of nanomaterial were introduced.The applications of nanomaterial in heat insulation coatings,antibacterial coatings,anti-aging coatings,anticorrotive coatings,and superhydrophobic coatings were reviewed.The future research focus and development direction about nanocoating fields were pointed out.
[1] 梁伟欣.功能纳米涂料的研究进展[J].江西建材,2016(10):63-64.
[2] 马榴强.精细化工工艺学[M].北京:化学工业出版业,2008,156-157.
[3] Li G L,Xu L Q,Tang X,et al.Hairy hollow microspheres of fluorescent shell and temperature-responsive brushes via combined distillation-precipitation polymerization and thiol-ene click chemistry[J].Macromolecules,2010,43(13):5797-5803.
[4] 王林芳,马磊,王爱琴,等.氨基硅烷修饰的SBA-15用于CO2的吸附[J].催化学报,2007,28(9):805-810.
[5] 崔新爱.双亲性磁性纳米材料制备及应用研究[D].西安:陕西师范大学,2008.
[6] Sun G,Chang Y,Li S,et al.pH-responsive controlled release of antitumour-active polyoxometalate from mesoporous silica materials[J].Dalton Transactions,2009(23):4481-4487.
[7] Jesionowski T,Krysztafkiewicz A.Influence of silane coupling agents on surface properties of precipitated silicas[J].Applied Surface Science,2001,172(1):18-32.
[8] Salim M A,Misran H,Othman S Z,et al.Synthesis and characterizations of SiO2-Ag core-shell nanostructure using fatty alcohols as surface modifiers[J].Applied Mechanics & Materials,2015,773-774(6):199-203.
[9] 郑凤英,钱沙华,李顺兴,等.3,5-二硝基水杨酸表面修饰纳米TiO2吸附对硝基苯酚[J].环境科学,2006,27(6):1140-1143.
[10] Guo L L,Li Q X,Tang X,et al.Hairy hollow microspheres of fluorescent shell and temperature-responsive brushes via combined distillation-precipitation polymerization and thiol-ene click chemistry[J].Macromolecules,2010,43(43):5797-5803.
[11] Abdollahi M,Rouhani M,Salarizadeh P,et al.Using fumed silica nanoparticles modified with hydrophilic sulfonated polymers in the proton exchange nanocomposite membranes[J].Polymer Science,2015,57(5):667-674.
[12] Gao X,Chen K,Liang S,et al.Effects of raw and poly(propylene oxide) grafted nanosilica on the morphology and thermal and mechanical properties of polyurethane foam[J].Journal of Applied Polymer Science,2015,132(32):42400-42410.
[13] 刘成楼.纳米ATO透明隔热涂料的研制[J].现代涂料与涂装,2010,13(2):6-9.
[14] 许辉,汪牡丹,涂进春,等.SiO2气凝胶对复合隔热涂料性能的影响[J].材料导报,2013,27(14):100-103.
[15] Cayton R,Brotzman R W,Kullberg M.Substantially transparent,abrasion-resistant films containing surface-treated nanocrystalline particles:US,6896958 B1[P].2005-05-24.
[16] 徐瑞芬,许秀艳,付国柱.纳米TiO2在涂料中的抗菌性能研究[J].北京化工大学学报(自然科学版),2002,29(5):45-48.
[17] 王岩,王长平,林伦.磷酸盐抗菌粉体的研究及应用[J].硅酸盐通报,2004,23(3):91-93.
[18] 赵春艳,王静,冀志江,等.银系抗菌剂在内墙抗菌涂料中的性能研究[J].涂料工业,2014,44(10):48-51.
[19] 敖卫华,丁浩,沈凯.滑石-TiO2复合白色颜料的制备及其在涂料中的应用[J].中国粉体技术,2017(1):19-22.
[20] 丁浩,崔程琳,孙思佳.SiO2-TiO2复合颜料在涂料中的应用研究[J].涂料工业,2015,45(11):60-64.
[21] 江娟,周纯,黎彧,等.一种抗菌抗老化硅溶胶/高分子乳液复合涂料及其制备方法和应用:CN,106519859A[P].2017-03-22.
[22] Zhang Z,Zhang W,Li D,et al.Mechanical and anticorrosive properties of graphene/epoxy resin composites coating prepared by in-situ method[J].International Journal of Molecular Sciences,2015,16(1):2239-2251.
[23] Dolatzadeh F,Moradian S,Jalili M M.Influence of various surface treated silica nanoparticles on the electrochemical properties of SiO2/polyurethane nanocoatings[J].Corrosion Science,2011,53(12):4248-4257.
[24] 季金苟,杨斌,夏之宁,等.纳米复合氟改性丙烯酸树脂超疏水自清洁涂层的制备[J].材料研究学报,2011,25(4):422-426.
[25] Ding X,Zhou S,Gu G,et al.A facile and large-area fabrication method of superhydrophobic self-cleaning fluorinated polysiloxane/TiO2 nanocomposite coatings with long-term durability[J].Journal of Materials Chemistry,2011,21(17):6161-6164.
[26] 王雪,王少凯,黄蕊,等.超疏水涂料的制备及性能研究[J].化学与粘合,2017,39(5):313-324.
基金资助
国家自然科学基金(21276121)
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