新型环保阻燃抑烟剂羟基锡酸锌的研究进展

李刚,吴琳,于奕峰,葛雪松,张萌,姜义军,陈爱兵

化工新型材料 ›› 2019, Vol. 47 ›› Issue (4) : 226 -229.

PDF (1115KB)
化工新型材料 ›› 2019, Vol. 47 ›› Issue (4) : 226-229.
开发与应用

新型环保阻燃抑烟剂羟基锡酸锌的研究进展

作者信息 +

Research progress of new environmental friendly flame retardant and smoke suppressant hydroxystannate zinc

Author information +
文章历史 +
PDF (1141K)

摘要

随着时代的发展,人们的环保和安全意识逐渐增强,阻燃抑烟剂的发展也面临新的挑战。传统的磷系、三氧化二锑和卤系阻燃抑烟剂,因阻燃抑烟过程中存在污染性气体产生已渐渐跟不上时代的要求,而羟基锡酸锌(ZHS)作为新型环保阻燃抑烟剂得到了科研人员的广泛关注,并在近年取得了一系列的研究进展。综述了羟基锡酸锌的阻燃机理、合成方法和最新的改性研究进展,并对其发展前景做了展望。

Abstract

With the development of times,people's environmental protection and safety awareness have been gradually enhanced,and the development of flame retardant and anti-smoking agent has also faced new challenges.Traditional phosphorus,antimony trioxide and halogen flame retardants,resulting from pollution gas exist in the process of flame retardant smoke suppression have gradually couldn't keep up with the requirements of times.The zinc hydroxystannate (ZHS) as a new type of environmentally friendly flame retardant smoke suppression agent has received the widespread attention of researchers,and made a series of research progress in recent years.The flame retardant mechanism,synthesis method and the latest progress in the modification of zinc hydroxystannate were reviewed.At last,the prospect of its development was prospected.

关键词

环保阻燃抑烟剂 / 羟基锡酸锌 / 研究进展

Key words

environmental protection flame retardant / zinc hydroxystannate / research progress

引用本文

引用格式 ▾
李刚,吴琳,于奕峰,葛雪松,张萌,姜义军,陈爱兵. 新型环保阻燃抑烟剂羟基锡酸锌的研究进展[J]. 化工新型材料, 2019, 47(4): 226-229 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 焦运红,彭飞,徐建中,等.仿生合成羟基锡酸锌包覆碳酸钙及其对PVC的阻燃研究[J].化学工程师,2011,25(5):5-8.
[2] Sang B,Li Z,Yu L,et al.Preparation of zinc hydroxystannate-titanate nanotube flame retardant and evaluation its smoke suppression efficiency for flexible polyvinyl chloride matrix[J].Materials Letters,2017,204:133-137.
[3] 张小燕,卢其勇.阻燃剂的生产状况及发展前景[J].塑料工业,2011,39(4):1-5.
[4] Qu H,Wu W,Zheng Y,et al.Synergistic effects of inorganic tin compounds and Sb2O3,on thermal properties and flame retardancy of flexible poly(vinyl chloride)[J].Fire Safety Journal,2011,46(7):462-467.
[5] Yang L,Wang Y Y.Smoke suppressant and flame retardant properties of PVC/zinc hydroxystannate composites[J].Advanced Materials Research,2012,512-515:2804-2807.
[6] 李志伟,贺洁,李小红,等.无机锡化物阻燃聚氯乙烯研究进展[J].中国塑料,2012,26(9):1-5.
[7] 刘成娟,陈葵,纪利俊,等.环氧树脂包覆聚磷酸铵微胶囊的制备及其对聚丙烯的阻燃效果[J].复合材料学报,2015,32(3):728-736.
[8] 柳素景.建筑膜材PVC涂层ZHS/Sb2O3协同阻燃性能研究[D].杭州:浙江理工大学,2015.
[9] Wang W,Ma Z,Liang R,et al.Synthesis and photocatalytic performance of SnZn(OH)6 with different morphologies[J].Journal of Materials Research,2013,28(12):1582-1588.
[10] Cusack P A,Monk A W,Pearce J A,et al.An investigation of inorganic tin flame retardants which suppress smoke and carbon monoxide emission from burning brominated polyester resins[J].Fire & Materials,1989,14(1):23-29.
[11] Su X,Yi Y,Tao J,et al.Synergistic effect of zinc hydroxystannate with intumescent flame-retardants on fire retardancy and thermal behavior of polypropylene[J].Polymer Degradation & Stability,2012,97(11):2128-2135.
[12] Sagadevan S,Singh J,Pal K,et al.Hydrothermal synthesis of zinc stannate nanoparticles spectroscopic investigation[J].Journal of Materials Science Materials in Electronics,2017,28:11268-11274.
[13] 王炳山,袁建军,韩文华,等.ZnO/ZnSnO3纳米复合物的制备及其HCHO气敏性研究[J].材料导报,2015,29(20):47-50.
[14] Li H,Hong W,Cui Y,et al.High photocatalytic activity of C-ZnSn(OH)6 catalysts prepared by hydrothermal method[J].Journal of Molecular Catalysis A Chemical,2013,378(11):164-173.
[15] 王海,王春征,刘彩红,等.羟基锡酸锌包覆硫酸钡的制备以及在软PVC中的阻燃应用[J].塑料,2013,42(3):20-23.
[16] 徐建中,刘建州,谢吉星,等.均匀沉淀法制备锡酸锌与锡酸锌包覆纳米碳酸钙的研究[J].无机盐工业,2009,41(5):28-30.
[17] 焦运红,陈金杰,吴静,等.两种形貌的羟基锡酸锌对聚氯乙烯的阻燃作用[J].中国塑料,2016,30(12):75-80.
[18] Fu X,Huang D,Qin Y,et al.Effects of preparation method on the microstructure and photocatalytic performance of ZnSn(OH)6[J].Applied Catalysis B Environmental,2014,148-149(648):532-542.
[19] Wu W,Qu H,Li Z,et al.Thermal behavior and flame retardancy of flexible poly(vinyl chloride) treated with zinc hydroxystannate and zinc stannate[J].Journal of Vinyl & Additive Technology,2010,14(1):10-15.
[20] Hu J,Hsu H K,Ju T,et al.Zinc stannate ohmic contacts for p-type gallium nitride:US,9246062B2[P].2016-01-26.
[21] Han J,Liang G,Gu A,et al.A novel inorganic-organic hybridized intumescent flame retardant and its super flame retarding cyanate ester resins[J].Journal of Materials Chemistry A,2013,1(6):2169-2182.
[22] Gao T T,Li Z W,Yu L G,et al.Preparation of zinc hydroxystannate nanocomposites coated by organophosphorus and investigation of their effect on mechanical properties and flame retardancy of poly(vinyl chloride)[J].Rsc Advances,2015,5(120):99291-99298.
[23] Qu H,Wu W,Xie J,et al.Zinc hydroxystannate-coated metal hydroxides as flame retardant and smoke suppression for flexible poly vinyl chloride[J].Fire & Materials,2010,33(4):201-210.
[24] Wang C Z,Wu W H,Ye X,et al.Zinc hydroxystannate-coated mineral grade Mg(OH)2 as flame-retardant and smoke suppression for flexible PVC[J].Advanced Materials Research,2013,652-654(s20-21):481-484.
[25] 苍琼,李锦春,任强,等.羟基锡酸锌包覆埃洛石对PVC/ABS共混物阻燃性能的影响[J].高分子材料科学与工程,2015,31(1):88-92.
[26] Liu X,Wu W,Qi Y,et al.Synthesis of a hybrid zinc hydroxystannate/reduction graphene oxide as a flame retardant and smoke suppressant of epoxy resin[J].Journal of Thermal Analysis & Calorimetry,2016,126(2):1-7.
[27] 张予东,李宾杰,徐翔民,等.纳米ZnSn(OH)6对软质PVC阻燃和抑烟性能的影响[J].应用化学,2007,24(3):286-290.
[28] 高婷婷.羟基锡酸锌基纳米杂化阻燃剂的制备及其在聚合物中阻燃性能的研究[D].郑州:河南大学,2016.
[29] 李志伟,黄永山,李小红,等.一种新型ZHS-MF复合阻燃剂的制备及其在软质PVC中的应用[J].复合材料学报,2013,30(4):29-34.

基金资助

国家自然科学基金(21676070);河北自然科学基金(B2015208109);河北人才工程培训计划(A201500117)

AI Summary AI Mindmap
PDF (1115KB)

800

访问

0

被引

导航
相关文章

AI思维导图

/