生物可降解塑料是一类可由自然界微生物作用使其降解的高分子聚合物。由于其具有良好的生物降解性及生物相容性使其成为当前高分子材料领域研究的热点。但在具体实际应用中仍然存在一些不足,因此国内外研究人员也对其开展了相应的改性研究。首先对高分子生物可降解塑料的种类、合成、优劣势以及应用进行了比较,继而综述了近年来生物可降解塑料改性的研究进展,并对化学改性和物理改性进行了比较,最后对生物可降解塑料改性中存在的问题进行了分析并对其在未来的发展应用作出了总结与展望。
Biodegradable plastics are a class of polymer materials that can be degraded by the action of natural microorganisms.Because of its good degradation,low production cost and good mechanical properties,it has become the hotpoint of current research.But there are still some shortcomings in the practical application,so domestic and foreign experts and scholars are studying its modified research.The types,synthesis,advantages and disadvantages of polymer biodegradable plastics were compared.Secondly,the practical application in recent years was analyzed,and the chemical and physical modification were compared.The problems of biodegradable plastic modification were analyzed,and its future development and application were summary and outlined.
[1] Wang Y,Li F,Wang Z Y,et al.Purification and properties of an extracellular polyhydroxybutyrate depolymerase from pseudomonas mendocina DSWY0601[J].Chemical Research in Chinese Universities,2012,28(3):459-464.
[2] Luckachan G E,Pillai C K S.Biodegradable polymers-a review on recent trends and emerging perspectives[J].Journal of Polymers & the Environment,2011,19(3):637-676.
[3] Brodhagen M,Peyron M,Miles C,et al.Biodegradable plastic agricultural mulches and key features of microbial degradation[J].Applied Microbiology and Biotechnology,2015,99(3):1039-56.
[4] Tokiwa Y,Calabia B P.Biodegradability and biodegradation of polyesters[J].Journal of Polymers & the Environment,2007,15(4):259-267.
[5] Koller M,Braunegg G.Potential and prospects of continuous polyhydroxyalkanoate (PHA) production[J].Bioengineering,2015,2(2):94-121.
[6] Phasawat C,Vimolvan P,Saowaroj C,et al.Biodegradable plastics prepared from poly(lactic acid),poly(butylene succinate) and microcrystalline cellulose extracted from waste-cotton fabric with a chain extender[J].Journal of Polymers & the Environment,2015,23:114-125.
[7] Li F,Qi L,Yang J,et al.Polyurethane/conducting carbon black composites:structure,electric conductivity,strain recovery behavior,and their relationships[J].Journal of Applied Polymer Science,2015,75(1):68-77.
[8] Rasal R M,Janorkar A,Hirt D E.Poly(lactic acid) modifications[J].Progress in Polymer Science,2010,35(3):338-356.
[9] 陆海旭.生物可降解塑料的发展现状与趋势[J].化学工业,2016,34(3):7-14.
[10] Sudesh K,Abe H,Doi Y.Synthesis,structure and properties of polyhydroxyalkanoates:biological polyesters[J].Progress in Polymer Science,2000,25(10):1503-1555.
[11] Kumar P,Ray S,Kalia V C.Production of co-polymers of polyhydroxyalkanoates by regulating the hydrolysis of biowastes[J].Bioresource Technology,2016,200:413.
[12] Wang S,Lu A,Zhang L.Recent advances in regenerated cellulose materials[J].Progress in Polymer Science,2016,53:169-206.
[13] Van Soest J J G,Knooren N.Influence of glycerol and water content on the structure and properties of extruded starch plastic sheets during aging[J].Journal of Applied Polymer Science,2015,64(7):1411-1422.
[14] Davachi S M,Kaffashi B.Polylactic acid in medicine[J].Polymer-Plastics Technology and Engineering,2015,54(9):944-967.
[15] 潘文静,白桢慧,苏婷婷,等.生物降解塑料聚乳酸(PLA)的改性研究进展[J].应用化工,2017,46(5):977-981.
[16] Cho K,Lee J,Kwon K.Hydrolytic degradation behavior of poly(butylene succinate)s with different crystalline morphologies[J].Journal of Applied Polymer Science,2015,79(6):1025-1033.
[17] 王斌,许斌.聚丁二酸丁二醇酯(PBS)的现状及进展[J].化工设计,2014,24(3):3-7.
[18] John J,Tang J,Yang Z,et al.Synthesis and characterization of anhydride-functional polycaprolactone[J].Journal of Polymer Science Part A:Polymer Chemistry,2015,35(6):1139-1148.
[19] Shuai C,Wu P,Zhong Y,et al.Polyetheretherketone/poly(glycolic acid) blend scaffolds with biodegradable properties[J].Journal of Biomaterials Science Polymer Edition,2016,7(14):1.
[20] Wang F.Carbon dioxide as a raw material for biodegradable plastics[J].Bulletin of the Chinese Academy of Sciences,2011,25(1):54-55.
[21] 高兆营,江南,刘慧芳,等.生物降解塑料聚丁二酸丁二酯的改性研究进展[J].工程塑料应用,2015,43(5):136-140.
[22] Merabet S,Riahi F,Douibi A.The physical modification of a natural rubber-polypropylene thermoplastic elastomer blend by azobisformamide blowing agent[J].Isrn Polymer Science,2012,2012(1):383-398.
[23] Sharhan O,Yahaya A H,Nasef M.Preparation and characterization of poly(3-hydroxybutyric acid)/poly(vinyl acetate) blend films[J].Asian Journal of Chemistry,2015,27(3):979-983.
[24] Shankar S,Oun A A,Rhim J W.Preparation of antimicrobial hybrid nano-materials using regenerated cellulose and metallic nanoparticles[J].International Journal of Biological Macromolecules 2017,32(2):1-30.
[25] Li Y,Lin S,Wei Z Y,et al.Mechanical properties and crystallization behavior of poly(butylene succinate) composites reinforced with basalt fiber[J].Journal of Thermal Analysis & Calorimetry,2015,122(1):261-270.
[26] Hu X Y,Su T T,Li P,et al.Blending modification of PBS/PLA and its enzymatic degradation[J].Polymer Bulletin,2018,75(2):1-14.
[27] Labrecque L V,Kumar R A,Davé V,et al.Citrate esters as plasticizers for poly(lactic acid)[J].Journal of Applied Polymer Science,2015,66(8):1507-1513.
[28] Ramamoorthy S K,Bakare F,Herrmann R,et al.Performance of biocomposites from surface modified regenerated cellulose fibers and lactic acid thermoset bioresin[J].Cellulose,2015,22(4):2507-2528.
[29] Arrieta M P,López J,López D,et al.Development of flexible materials based on plasticized electrospun PLA-PHB blends:structural,thermal,mechanical and disintegration properties[J].European Polymer Journal,2015,73:433-446.
[30] Jin T X,Liu C,Zhou M,et al.Crystallization,mechanical performance and hydrolytic degradation of poly(butylene succinate)/graphene oxide nanocomposites obtained via in situ polymerization[J].Composites:Part A,2015,68:193-201.
[31] Farah N H,Salmah H,Marliza M.Effect of butyl methacrylate on properties of regenerated cellulose coconut shell biocomposite films[J].Procedia Chemistry,2016,19:335-339.
[32] Zheng F,Mi Q H,Zhang K,et al.Synthesis and characterization of poly(propylene carbonate)/modified sepiolite nanocomposites[J].Polymer Composites,2016,37(1):21-27.
[33] Cui A,Xue S,He M,et al.The effects on thermal stability of polyglycolic acid by adding dihydrazide metal chelators[J].Polymer Degradation & Stability,2017,137:238-243.
[34] Hajlane A,Kaddami H,Joffe R.Chemical modification of regenerated cellulose fibres by cellulose nano-crystals:towards hierarchical structure for structural composites reinforcement[J].Industrial Crops & Products,2017,100:41-50.
[35] 陈小英,徐鼐,庞素娟,等.PLA增强改性PBAT共混物的制备及性能研究[J].化工新型材料,2016,44(6):122-125.
[36] Muthuraj R,Misra M,Mohanty A K.Biodegradable poly(butylene succinate) and poly(butylene adipate-co-terephthalate) blends:reactive extrusion and performance evaluation[J].Journal of Polymers & the Environment,2014,22(3):336-349.
[37] Liu H F,Gao Z Y,Hu X Y,et al.Preparation and characterization of poly(3-hydroxybutyric acid)/poly(vinyl acetate) blend films[J].Asian Journal of Chemistry,2017,25:156-164.
[38] Xu P,Zeng Q,Cao Y,et al.Interfacial modification on polyhydroxyalkanoates/starch blend by grafting in-situ[J].Carbohydrate Polymers,2017,174(15):716-722.
[39] Wu C S,Liao H T,Jhang J J.Palm fibre-reinforced hybrid composites of poly(butylene succinate):characterisation and assessment of mechanical and thermal properties[J].Polymer Bulletin,2013,70(12):3443-3462.
[40] Zhang X Z,Zhang Y.Reinforcement effect of poly(butylene succinate)(PBS)-graftedcellulose nanocrystal on toughened PBS/polylactic acid blends[J].Carbohydrate Polymers,2016,140(20):374-382.
[41] Wei L,Mcdonald A G.Peroxide induced cross-linking by reactive melt processing of two biopolyesters:poly(3-hydroxybutyrate) and poly(L-lactic acid) to improve their melting processability[J].Journal of Applied Polymer Science,2015,132(13):4233-4247.
[42] Wang B,Zhang P,Song W,et al.Modification of polyglycolic acid and poly lactic-co-glycolic acid fibers by ultrasonic treatment for enhancing hydrophilicity and cytocompatibility[J].Journal of Industrial Textiles,2016,45(4):516-530.
[43] Gao J,Bai H,Zhou X,et al.Observation of strong nano-effect via tuning distributed architecture of graphene oxide in poly(propylene carbonate)[J].Nanotechnology,2014,25(2):1-11.
[44] Pajoumshariati S,Yavari S K,Shokrgozar M A.Physical and biological modification of polycaprolactone electrospun nanofiber by panax ginseng extract for bone tissue engineering application[J].Annals of Biomedical Engineering,2016,44(5):1808-1820.
基金资助
国家自然科学基金(31570097)