PDF (3539K)
摘要
目前,采油废水随着石油开采难度的增加,治理难度也相应提高。采用静电纺丝技术,以聚偏氟乙烯(PVDF)、聚丙烯腈(PAN)为原料,N,N-二甲基酰胺(DMF)、N-甲基吡咯烷酮(NMP)为溶剂,制得了不同比例的PVDF/PAN纳米纤维膜。并对所做出来的PVDF/PAN纳米纤维膜的形貌和性质进行表征,优选出了最佳比例,在最佳质量比PVDF∶PAN=3∶2的基础上,优选出质量分数12%的PVDF/PAN纳米纤维膜进行实验。结果表明:此膜对采油废水的处理效果显著。
Abstract
Currently,with the increasing difficulty of oil extraction,the processing difficulty of oil production wastewater has been increasing commensurately.The electrospinning was adopted to fabricate PVDF/PAN nanofiber membranes with different ratios,using PVDF and PAN as ingredients,DMF and NMP as solutions.The as-prepared membranes were characterized for their morphology and properties in order to determine the optimal ratio.The optimal ratio of PVDF∶PAN being 3∶2,the membrane with the optimal concentration of 12 wt% was selected,the performance was tremendous in processing oil production wastewater.
关键词
静电纺丝
/
纳米纤维膜
/
聚丙烯腈
Key words
electrospinning
/
nanofiber membrane
/
PAN
静电纺聚丙烯腈纳米纤维膜的制备及性能研究[J].
化工新型材料, 2019, 47(3): 55-58 DOI:
[1] 赵义侠.实心针静电纺纳米纤维成型机理及双尺度纳米纤维复合过滤材料的研究[D].天津:天津工业大学,2016.
[2] 李青.三维花状金属氧化物纳米材料的合成及其电化学性能研究[D].长沙:湖南大学,2014.
[3] 欧平.铁的氧化物和羟基氧化物纳米材料的合成、表征及性能研究[D].杭州:浙江大学,2007.
[4] 冯慧.纳米晶体材料中微结构演变与断裂韧度研究[D].长沙:湖南大学,2014.
[5] 王永芝,杨清彪,李耀先.纳米纤维的性质及应用进展[J].化工新型材料,2004,32(12):9-12.
[6] Shen J,Li Z,Wu Y,et al.Dendrimer-based preparation of mesoporous alumina nanofibers by electrospinning and their application in dye adsorption[J].Chemical Engineering Journal,2015,264:48-55.
[7] Lai C C,Lo C T.Preparation of nanostructural carbon nanofibers and their electrochemical performance for supercapacitors[J].Electrochimica Acta,2015,183:85-93.
[8] Ma C,Wang X,Ma Y,et al.Carbon nanofiber/graphene composite paper for flexible supercapacitors with high volumetric capacitance[J].Materials Letters,2015,145:197-200.
[9] 李永建,李从举.空气过滤用静电纺纳米纤维材料的研究进展[J].化工新型材料,2012,40(3):18-21.
[10] 纪明辉,魏平原,孟庆飞.纳米纤维的制备及性能[J].高科技纤维与应用,2002,27(3):11-14,33.
[11] 李蕾.静电纺丝壳聚糖纳米纤维膜的制备及对六价铬离子吸附的研究[D].北京:中国科学院大学,2016.
[12] 吴韶华.静电纺取向纳米纤维纱线的制备机理及在生物医学中的应用[D].上海:东华大学,2016.
基金资助
西南石油大学课外开放实验校级重点项目(KSZ17104)