对两种不同改性氰酸酯树脂的介电性能、玻璃化转变温度、流变性及力学性能进行了研究。结果表明:70℃下树脂体系黏度为20Pa·s,具有良好的工艺性,适用于热熔法生产预浸料;树脂具有优异的介电性能,介电常数为3.1~3.6,介电损耗角正切值为0.005~0.009;耐温性优异,B类树脂玻璃化转变温度达到240℃。该树脂体系是适合耐高温高性能透波材料应用的树脂基体。
The dielectric performance,glass transition temperature,rheological and mechanical properties of two kinds of modified cyanate ester resin were studied.The results indicated that the resin viscosity under 70℃ for 20Pa·s had good manufacturability to suit for melting prepared prepreg.The resin had excellent dielectric properties,that the dielectric constant reached 3.1~3.6,and the dielectric loss of 0.005~0.009 was shown.The glass transition temperature of B resin reached 240℃.The resin could be used for the resin matrix of high temperature resistance and high performance microwave-transparence materials.
[1] 阎福胜,王志强,梁国政,等.双酚A型氰酸酯树脂的性能[J].高分子材料科学与工程,2000,16(4):170-172.
[2] 任鹏刚,梁国政,张增平,等.双酚A型二氰酸酯及其环氧改性体系的反应性研究[J].材料工程,2008,36(4):28-32.
[3] Prokopec R,Humer K,Maix R K,et al.Influence ofvarious catalysts on the radiation resistance and the mechanical properties of cyanate ester/epoxy insulation systems[J].Fusion Engineering and Design,2009,84(7-11):1544-1547.
[4] Koh H C Y,Dai J,Tan E,et al.Catalytic effect of 2,2′-diallyl bisphenol a on thermal curing of cyanate esters[J].Journal of Applied Polymer Science,2006,101(3):1775-1786.
[5] 嵇培军,杨明,白树成,等.环氧树脂/双马树脂/氰酸酯共聚物复合材料性能研究[C].哈尔滨:第十五届全国复合材料学术会议论文集,2008.
[6] 赵磊,孟季茹,梁国正,等.改性氰酸酯树脂的研究进展[J].玻璃钢/复合材料,2005,34(5):38-42.
[7] 马万翔.E-51环氧树脂改性双酚A型氰酸酯树脂的研究[J].热固性树脂,2011,26(1):6-10.
[8] 虞莲雯.改性双马来酰亚胺/氰酸酯树脂固化工艺的研究[J].玻璃钢/复合材料,2008,37(2):35-37.