化工新型材料

化工新型材料 ›› 2019, Vol. 47 ›› Issue (1) : 235-238.

开发与应用

共价有机骨架材料的CO₂捕获性能研究

作者信息 +

Study on carbon dioxide capture of covalent organic frameworks

Liu Xiuying¹, Meng Lingguang², Yu Jingxin¹, Li Xiaodong¹

Author information +

文章历史 +

Received
2017-04-13
Issue Date	Revised Date
2019-03-12	2017-04-13

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摘要

共价有机骨架材料(COFs)作为一类新型的纳米多孔晶体材料,由于具有表面积大、结构多样性、永久孔隙率高和热稳定性高等优点,在CO₂捕获性能方面表现出优异的应用前景。简要介绍了COFs的合成及表征方法、描述CO₂捕获性能的物理量。综述了几类COFs对CO₂捕获性能的研究进展,如含硼类、三嗪类和亚胺类COFs,并对它们的捕获性能进行了比较和总结,指出其优点和局限性。最后对未来的研究方向和发展趋势进行了展望。

Abstract

The increase of carbon dioxide (CO₂) concentration in the atmosphere has caused a series of environmental problems in recent years.Carbon capture and sequestration (CCS) has been proposed to alleviate its concentration.Covalent organic frameworks (COFs) possess many fascinating features,such as large surface area,structural diversity,high permanent porosity,high thermal stability and so on,which enables COFs potential and important applications in CO₂ capture from the mixed gases.The synthesis and characterization of COFs,physical quantities describing CO₂ capture performance and theoretical methods for studying CO₂ performance were briefly introduced.Research progresses of several kinds of COFs on CO₂ capture were reviewed in detail,including boron-based,triazine-based and imine-based COFs.Their CO₂ capture performances were compared,the advantages and limitations were summarized.Finally,a perspective in the field of COFs for CO₂ capture was pointed out.

关键词

共价有机骨架 / 多孔材料 / CO₂捕获 / 温室效应

Key words

covalent organic frameworks / porous material / CO₂ capture / greenhouse effect

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共价有机骨架材料的CO₂捕获性能研究[J]. 化工新型材料, 2019, 47(1): 235-238 DOI:

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