我国是一个干旱缺水严重的国家,其中农业耗水量最多,占总耗水量的70%以上,如何提高水资源利用率,减少农业耗水量是急需解决的问题。高吸水性树脂的出现,为解决上述问题提供了可能。越来越多的研究发现,高吸水性树脂用于农业生产,不但可以保水保肥,还能促进植物生长。对合成聚合物类、生物质类、有机-无机复合类高吸水性树脂进行了详细介绍,对其在农业生产中的最新应用研究进行概述,并对其在应用中存在的一些问题进行讨论,指出今后重点是对高吸水倍率、高机械强度的生物基吸水树脂的研发。
Drought and water shortage is serious in our country.While the water consumption in agriculture is the largest,accounting for more than 70% of the total water consumption.How to improve the utilization rate of water resources and reduce agricultural water consumption is an urgent problem to be solved.The emergence of superabsorbent resins has made it possible to solve the above problems.More and more studies have found that the application of superabsorbent resin in agriculture not only can save water and fertilizer,but also can promote plant growth.Synthetic polymers,biomass and organic-inorganic composite superabsorbent were introduced,and the latest research on their application in agriculture was summarized with discussing the existing problems in practical application.And it was pointed out that the focus in the future was on the development of bio-based water-absorbing resins with high water absorbency and high mechanical strength.
[1] 卢炜,眭晓,刘静,等.高吸水性树脂的应用现状[J].产业与科技论坛,2016,15(23):63-64.
[2] 张小磊,李磊,王文彬,等.三-(二甲胺基甲基)苯酚改性高吸水性树脂的制备与性能[J].高分子材料科学与工程,2016,32(5):139-143.
[3] Ani N C,Jamari S S,Yaacob W S N W.Effect of cross-linker concentration on the synthesis and swelling behaviour of superabsorbent polymers (SAP) using graft polymerization techniques[J].Key Engineering Materials,2017,719:62-66.
[4] Kazemi F,Mohamadnia Z,Kaboudin B,et al.Synthesis,characterization and swelling behavior investigation of hydrogel based on AAm and AA using CdS nanorods as photocatalyst initiator under different irradiations[J].Journal of Photochemistry & Photobiology,A:Chemistry,2016,330(1):102-109.
[5] Li J,Zhang K,Zhang M,et al.Fabrication of a fast-swelling superabsorbent resin by inverse suspension polymerization[J].Journal of Applied Polymer Science,2017,135(15):46142-46150.
[6] Fekete T,Borsa J,Takács E,et al.Synthesis and characterization of superabsorbent hydrogels based on hydroxyethylcellulose and acrylic acid[J].Carbohydrate Polymers,2017,166:300-308.
[7] Meng Y,Ye L.Synthesis and swelling property of the starch-based macroporous superabsorbent[J].Journal of Applied Polymer Science,2017,134(21):44855-44865.
[8] Liu T G,Wang Y T,Guo J,et al.One-step synthesis of corn starch urea based acrylate superabsorbents[J].Journal of Applied Polymer Science,2017,134(32):45175-45185.
[9] Klinpituksa P,Kosaiyakanon P,Potthast A.Superabsorbent polymer based on sodium carboxymethyl cellulose grafted polyacrylic acid by inverse suspension polymerization[J].International Journal of Polymer Science,2017(9):1-6.
[10] Guan H,Li J,Zhang B,et al.Synthesis,properties,and humidity resistance enhancement of biodegradable cellulose-containing superabsorbent polymer[J].Journal of Polymers,2017,2017:1-8.
[11] Fernando T N,Ariadurai S A,Disanayaka C K,et al.Development of radiation grafted super absorbent polymers for agricultural applications[J].Energy Procedia,2017,127:163-177.
[12] 刘佳.羽毛蛋白基半互穿网络高吸水性树脂的制备及其性能研究[D].济南:山东大学,2014.
[13] Cuadri A A,Romero A,Bengoechea C,et al.Natural superabsorbent plastic materials based on a functionalized soy protein[J].Polymer Testing,2016,58:126-134.
[14] Kim H J,Koo J M,Kim S H,et al.Synthesis of super absorbent polymer using citric acid as a bio-based monomer[J].Polymer Degradation and Stability,2017,144:128-136.
[15] Ye Z,Tang M,Hong X,et al.Sustainable composite super absorbents made from polysaccharides[J].Materials Letters,2016,183:394-396.
[16] Chen Y,Zhang Y,Wang F,et al.Preparation of porous carboxymethyl chitosan grafted poly (acrylic acid) superabsorbent by solvent precipitation and its application as a hemostatic wound dressing[J].Materials Science & Engineering C,2016,63:18-29.
[17] Jamaludin S,Hashim S.The degradability and possible agricultural application of oil palm empty fruit bunch based superabsorbent polymer composites[A].International Conference on Civil,Biological and Environmental Engineering[C].Istanbul:2014,86-90.
[18] 苏小育.椰糠粉基高吸水材料的制备及其性能研究[D].西安:长安大学,2016.
[19] 许晓辉.废弃沙棘枝条基高吸水性复合材料的制备及应用[D].西安:长安大学,2016.
[20] 张太亮,范开鑫,刘婉琴,等.P(AA/AM/APEG)/纳米二氧化硅复合高吸水树脂的合成及性能[J].精细化工,2017,34(2):145-151.
[21] Pathak V M,Kumar N.Dataset on the superabsorbent hydrogel synthesis with SiO2 nanoparticle and role in water restoration capability of agriculture soil[J].Data in Brief,2017,13(10):291-294.
[22] Zakaria M E T,Jamari S S,Ling Y Y,et al.Synthesis of superabsorbent polymer via inverse suspension method:effect of carbon filler[A].5th International Conference on Nano-materials amd Materials Engineering[C].IOP,2017.
[23] Wei Y S,Chen K S,Wu L T.In situ synthesis of high swell ratio polyacrylic acid/silver nanocomposite hydrogels and their antimicrobial properties[J].Journal of Inorganic Biochemistry,2016,164:17-25.
[24] 黄慧青,周林涛,安勐颖,等.保水剂对海滨雀稗抗旱性的影响[J].西南农业学报,2016,29(8):1828-1833.
[25] 岑睿,屈忠义,于健,等.保水剂对半干旱区砂壤土水分运动的影响试验研究[J].干旱区资源与环境,2016,30(2):122-127.
[26] 庞海颖,牛东伟,李彦慧.施用保水剂对仁用杏抗旱生理特性的影响[J].河北农业大学学报,2017,40(4):43-49.
[27] 井大炜,邢尚军,刘方春,等.保水剂施用方式对侧柏根际微生态环境的影响[J].农业机械学报,2016,47(5):146-154.
[28] 马海林,刘方春,马丙尧,等.保水剂对侧柏容器苗根际土壤微生物种群结构及干旱适应能力的影响[J].应用与环境生物学报,2016,22(1):43-48.
[29] 许紫峻,韩舒,师庆东.不同保水剂对土壤物理性质影响的探究[J].节水灌溉,2016(10):10-14.
[30] Gales D C,Trinca L C,Cazacu A,et al.Effects of a hydrogel on the cambic chernozem soil's hydrophysic indicators and plant morphophysiological parameters[J].Geoderma,2016,267:102-111.
[31] Cao Y,Wang B,Guo H,et al.The effect of super absorbent polymers on soil and water conservation on the terraces of the loess plateau[J].Ecological Engineering,2017,102:270-279.
[32] 彭韬,邢学刚,蔡先立,等.保水剂与活性炭改良白云岩石漠化坡地土壤促进植物生长的盆栽试验研究[J].中国岩溶,2016,35(5):525-532.
[33] 李想,张宝娟,李继泉,等.保水剂与有机肥配施对铁尾矿理化性质的改良作用[J].应用生态学报,2017,28(2):554-562.
[34] 李想,张宝娟,李继泉,等.保水剂与有机肥配合施加对铁尾矿基质下植物生长的影响[J].内蒙古农业大学学报(自然科学版),2016,37(3):44-50.
[35] 张俊英,许永利,李富平.2种保水剂在铁尾矿植物复垦中的应用[J].环境科学与技术,2016,39(2):143-147.
[36] 杨杰,曹昀,王秀文,等.保水剂对高羊茅种子萌发及幼苗生理的影响[J].水土保持研究,2017,24(1):351-356.
[37] 程晓彬.保水剂对青稞苗期生长的影响[J].现代农业科技,2017(8):9-10.
[38] 倪芳,蔡卫兵,蒲双双,等.保水剂对土壤含水量及黑麦草种子萌发的影响[J].安徽农业科学,2016,44(27):52-54.
[39] 王越,王宇欣,时光营.纤维素保水剂对基质特性和黄瓜幼苗生长的影响[J].农业机械学报,2016,47(1):162-169.
[40] 陈芳泉,邵惠芳,贾国涛,等.保水剂对烟草光合特性和叶绿素荧光参数的影响[J].中国农业科技导报,2016,18(5):157-163.
[41] 杜清福,商丽丽,韩俊杰,等.保水剂对温室栽培甘薯前期生长及产量的影响[J].山东农业科学,2017,49(2):81-84.
[42] Chehab H,Tekaya M,Mechri B,et al.Effect of the Super Absorbent Polymer Stockosorb® on leaf turgor pressure,tree performance and oil quality of olive trees cv.Chemlali grown under field conditions in an arid region of Tunisia[J].Agricultural Water Management,2017,192:221-231.
[43] 牛舒琪,何傲蕾,丁新宇,等.枯草芽孢杆菌GB03与保水剂互作对小花碱茅生长和耐盐性的影响[J].植物生理学报,2016,52(3):285-292.
[44] 于茜,姜小堂,盛伟,等.保水剂对基质保水性和芹菜幼苗生长的影响[J].江苏农业科学,2016,44(10):208-210.
[45] 谭飞理,翟明普,黎海利.保水剂对臭椿盆栽幼苗生长及光合特性的影响[J].北方园艺,2017(10):74-79.
[46] 王兴刚,秦静雯,吕少瑜,等.基于魔芋葡甘露聚糖的双层包膜多功能缓释复合肥料的制备及其性能研究[J].化工新型材料,2017,45(1):182-184.
[47] Qiao D,Liu H,Yu L,et al.Preparation and characterization of slow-release fertilizer encapsulated by starch-based superabsorbent polymer[J].Carbohydrate Polymers,2016,147:146-154.
[48] 秦端端,姚粉霞,陈亚军,等.保水剂对土壤重金属镉形态及生物有效性的影响[J].农业环境科学学报,2016,35(12):2327-2333.
[49] 胡伟,秦端端,李玉和,等.添加保水剂和栽种黑麦草对土壤不同形态铅转化的影响[J].农业环境科学学报,2017,36(9):1771-1777.
[50] Moghadam H R T.Super absorbent polymer mitigates deleterious effects of arsenic in wheat[J].Rhizosphere,2016,3(1):40-43.
[51] 李源纯,汪宇浩.高吸水性树脂的特点结构与应用[J].化工管理,2015(24):89.
基金资助
国家自然科学基金(31172031);广东省普通高校省级重大科研项目(自然科学)(粤教科函[2015]3号);广州市科技计划项目产学研协同创新重大专项(201704020187)