化工新型材料

化工新型材料 ›› 2018, Vol. 46 ›› Issue (12) : 27-30.

综述与专论

AgInS₂量子点的合成与应用研究进展

刘应凡, 毛凯明

作者信息 +

Synthesis and application research progress of AgInS₂ quantum dot

Liu Yingfan, Mao Kaiming

Author information +

文章历史 +

Received
2018-04-28
Issue Date	Revised Date
2019-01-07	2018-04-28

PDF (1226K)

摘要

近年来,Ⅰ—Ⅲ—Ⅵ族三元量子点AgInS₂具有发光波长随尺寸组分可调、荧光寿命长、Stokes位移大、在可见光区和近红外区吸光系数大等优异的光电性能。与含Cd、Hg等有毒元素的量子点相比,AgInS₂量子点毒性低、绿色环保,在生物医学应用中前景广阔。总结了近几年国内外关于AgInS₂量子点研究的最新成果,对其合成方法与应用进行了概述。

Abstract

Ternary Ⅰ—Ⅲ—Ⅵ₂ type AgInS₂ quantum dots (QDs) have been given broad attention in recent years due to their superior optical performance,such as size- and composition-dependent emission wavelength,long fluorescence lifetime,large stokes shift,and can emit in the near-infrared region with high extinction coefficients.Compared with the QDs containing heavy metal toxic elements such as Cd,Hg and so on,AgInS₂ QDs have the advantages of low toxicity and green environmental protection,making them have a bright future in biological application.The latest achievements in the research of AgInS₂ quantum dots at home and abroad in recent years were summarized,and outlined the synthesis methods and applications.

关键词

AgInS₂量子点 / 合成 / 应用

Key words

AgInS₂ quantum dots / synthesis methods / applications

引用本文

引用格式 ▾

AgInS₂量子点的合成与应用研究进展[J]. 化工新型材料, 2018, 46(12): 27-30 DOI:

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Deng D W,Chen Y Q,Cao J,et al.High-quality CuInS₂/ZnS quantum dots for in vitro and in vivo bioimaging[J].Chem Mater,2012,24(15):3029-3027.
[2] Shen H B,Cao W R,Shewmon N T,et al.High-efficiency,low turn-on voltage blue-violet quantum-dot based light-emitting diodes[J].Nano Lett,2015,15(2):1211-1216.
[3] Yang H B,Miao J W,Hung S F,et al.Stable quantum dot photoelectrolysis cell for unassisted visible light solar water splitting[J].ACS Nano,2014,8(10):10403-10413.
[4] Luo M,Liu Y,Hu J C,et al.One-pot synthesis of CdS and Ni-doped CdS hollow spheres with enhanced photocatalytic activity and durability[J].ACS Appl Mater Interfaces,2012,4(3):1813-1821.
[5] Pan Y,Li Y R,Zhao Y,et al.Synthesis and characterization of quantum dots:a case study using PbS[J].J Chem Educ,2015,92(11):1860-1865.
[6] Sharifi S,Bahzadi S,Laurent S,et al.Toxicity of nanomaterials[J].Chem Soc Rev,2012,41(6):2323-2343.
[7] Tadjarodi A,Cheshmekhavar A H,Imani M.Preparation of AgInS₂ nanoparticles by a facile microwave heating technique;study of effective parameters,optical and photovoltaic characteristics[J].Appl Surf Sci,2012,263(48):449-456.
[8] Jara D H,Yoon S J,Stamplecoskie K G,et al.Size-dependent photovoltaic performance of CuInS₂ quantum dot sensitized solar cells[J].Chem Mater,2014,26(24):7221-7228.
[9] Du C F,You T,Jiang L,et al.Controllable synthesis of ultrasmall CuInSe₂ quantum dots for photovoltaic application[J].RSC Adv,2014,4(64):33855-33860.
[10] Liu S Y,Su X G.The synthesis and application of Ⅰ—Ⅲ—Ⅵ type quantum dots[J].RSC Adv,2014,4(82):43415-43428.
[11] Liu L W,Hu R,Law W C,et al.Optimizing the synthesis of red-and near-infrared CuInS₂ and AgInS₂ semiconductor nanocrystals for bioimaging[J].Analyst,2013,138(20):6144-6253.
[12] Hamanaka Y,Ozawa K,Kuzuya T.Enhancement of donor-acceptor pair emissions in colloidal AgInS₂ quantum dots with high concentrations of defects[J].J Phys Chem C,2014,118(26):14562-14568.
[13] Burda C,Chen X B,Narayanan R,et al.Chemistry and properties of nanocrystals of different shapes[J].Chem Rev,2005,105(4):1025-1102.
[14] Chang J Y,Wang G Q,Cheng C Y,et al.Strategies for photoluminescence enhancement of AgInS₂ quantum dots and their application as bioimaging probes[J].J Mater Chem,2012,22(21):10609-10618.
[15] Song J L Q,Jiang T T,Guo T Y,et al.Facile synthesis of water-soluble Zn-doped AgIn₅S₈/ZnS core/shell fluorescent nanocrystals and their biological application[J].Inorg Chem,2015,54(4):1627-1633.
[16] Zhong H Z,Bai Z L,Zou B S.Tuning the luminescence properties of colloidal Ⅰ—Ⅲ—Ⅵ semiconductor nanocrystals for optoelectronics and biotechnology applications[J].J Phys Chem Lett,2012,3(21):3167-3175.
[17] Regulacio M D,Win K Y,Lo S L,et al.Aqueous synthesis of highly luminescent AgInS₂-ZnS quantum dots and their biological applications[J].Nanoscale,2013,5(6):2322-2327.
[18] Tan L J,Liu S P,Li X Q,et al.A new strategy for synthesizing AgInS₂ quantum dots emitting brightly in near-infrared window for in vivo imaging[J].Colloid Surface B,2015,125:222-229.
[19] Grzegorz G,Piotr B,Kamila G,et al.A simple route to alloyed quaternary nanocrystals Ag-In-Zn-S with shape and size control[J].Inorg Chem,2014,53(10):5002-5012.
[20] Zeng Z,Wang A Q,Ping L L,et al.Encapsulation of lanthanides in ternary Ⅰ—Ⅲ—Ⅵ AgInS₂ nanocrystals and their physical properties[J].Mater Lett,2015,141:225-227.
[21] Xiang W D,Xie C P,Wang J,et al.Studies on highly luminescent AgInS₂ and Ag-Zn-In-S quantum dots[J].J Alloys Compd,2014,588(5):114-121.
[22] Tang X S,Ho W B A,Xue J M.Synthesis of Zn-Doped AgInS₂ Nanocrystals and their fluorescence properties[J].J Phys Chem C,2012,116(117):9769-9773.
[23] Mao B D,Chuang C H,Lu F,et al.Study of the partial Ag-to-Zn cation exchange in AgInS₂/ZnS nanocrystals[J].J Phys Chem C,2013,117(1):648-656.
[24] Xiong W W,Yang G H,Wu X C,et al.Microwave-assisted synthesis of highly luminescent AgInS₂/ZnS nanocrystals for dynamic intracellular Cu(Ⅱ) detection[J].J Phys Chem B,2013,1(33):4160-4165.
[25] Shamirian A,Appelbe O,Zhang Q B,et al.A toolkit for bioimaging using near-infrared AgInS₂/ZnS quantum dots[J].J Phys Chem B,2015,3(41):8188-8196.
[26] Fahmi M Z,Chang J Y.Potential application of oleylamine-encapsulated AgInS₂-ZnS quantum dots for cancer cell labeling[J].Procedia Chem,2016,18:112-121.
[27] Tsuji I,Kato H,Kobayashi H,et al.Photocatalytic H₂ evolution reaction from aqueous solutions over band structure-controlled (AgIn)_xZn_2(1-x)S₂ solid solution photocatalysts with visible-light response and their surface nanostructures[J].J Am Chem Soc,2004,126(41):13406-13413.
[28] Dai M,Ogawa S,Kameyama T,et al.Tunable photoluminescence from the visible to near-infrared wavelength region of non-stoichiometric AgInS₂ nanoparticles[J].J Mater Chem,2012,22(25):12851-12858.
[29] Xie R,Rutherford M,Peng X.Formation of high-quality Ⅰ—Ⅲ—Ⅵ semiconductor nanocrystals by tuning relative reactivity of cationic precursors[J].J Am Chem Soc,2009,131(15):5691-5697.
[30] Mao B D,Chuang C H,Wang J W,et al.Synthesis and photophysical properties of ternary Ⅰ—Ⅲ—Ⅵ AgInS₂ nanocrystals:intrinsic versus surface states[J].J Phys Chem C,2011,115(18):8945-8954.
[31] Mao B D,Chuang C H,McCleese C,et al.Near-infrared emitting AgInS₂/ZnS nanocrystals[J].J Phys Chem C,2014,118(25):13883-13889.
[32] Akin M,Bongartz R,Walter J G,et al.PAMAM-functionalized water soluble quantum dots for cancer cell targeting[J].J Mater Chem,2012,22(23):11529-11536.
[33] Tyrakowski C M,Snee P T.A primer on the synthesis,water-solubilization,and functionalization of quantum dots,their use as biological sensing agents,and present status[J].Phys Chem Chem Phys,2014,16(3):837-855.
[34] Shinchi H,Wakao M,Nagata N,et al.Cadmium-free sugar-chain-immobilized fluorescent nanoparticles containing low-toxicity ZnS-AgInS₂ cores for probing lectin and cells[J].Bioconjugate Chem,2014,25(2):286-295.
[35] Liu Y F,Yu J S.Selective synthesis of CdTe and high luminescence CdTe/CdS quantum dots:the effect of ligands[J].J Colloid Interf Sci,2009,333(2):690-698.
[36] Zhang W H,Sui C X,Wang X,et al.Characterization of Cr(V)-induced genotoxicity using CdTe nanocrystals as fluorescent probes[J].Analyst,2014,139(24):6357-6360.
[37] Liu Y F,Xie B,Yin Z G,et al.Synthesis of highly stable CdTe/CdS quantum dots with biocompatibility[J].Eur J Inorg Chem,2010(10):1501-1506.
[38] Liu Y F,Yu J S.In situ synthesis of highly luminescent glutathione-capped CdTe/ZnS quantum dots with biocompatibility[J].J Colloid Interf Sci,2010,351(1):1-9.
[39] Liu Y F,Wang G Q,Zhao J B,et al.Synthesis of chiral silver nanoclusters capped with small molecules[J].Colloid Surface A,2013,426(21):12-17.
[40] Liu Y F,Wang L,Bu C B,et al.Synthesis of luminescent Ag nanoclusters with antibacterial activity[J].J Nanomater,2015,2015:1-8.
[41] 刘应凡,张艳辉,王国庆.半导体发光Ag₂S量子点合成及应用[J].河南师范大学学报,2016,44(1):92-99.
[42] Liu Y F,Wang L,Zhang Y H,et al.Synthesis and characterization of chiral Ag₂S and Ag₂S-Zn nanocrystals[J].RSC Adv,2014,4(95):53142-53148.
[43] Jin H,Gui R J,Wang Z H,et al.Facile fabrication of water-dispersible AgInS₂ quantum dots and mesoporous AgInS₂ nanospheres with visible photoluminescence[J].RSC Adv,2015,5(84):68287-68292.
[44] Ma Q,Su X G.Near-infrared quantum dots:synthesis,functionalization and analytical applications[J].Analyst,2010,135(8):1867-1877.
[45] Kang X J,Yang Y C,Wang L,et al.Warm white light emitting diodes with gelatin-coated AgInS₂/ZnS core/shell quantum dots[J].ACS Appl Mater Interface,2015,7(50):27713-27719.
[46] Lü W,LüW Z,Zhao Q,et al.A novel efficient Mn⁴⁺ activated Ca₁₄Al₁₀Zn₆O₃₅ phosphor:application in red-emitting and white LEDs[J].Inorg Chem,2014,53(22):11985-11990.
[47] Zhang Q,Wang C F,Ling L T,et al.Fluorescent nanomaterial-derived white lightemitting diodes:what's going on[J].J Mater Chem C,2014,2(22):4358-4373.
[48] Wang A Q,Shen H B,Zang S P,et al.Bright,efficient,and color-stable violet ZnSe-based quantum dot light-emitting diodes[J].Nanoscale,2015,7(7):2951-2959.
[49] Bhaumic S,Pal A J.Light-emitting diodes based on solution-processed nontoxic quantum dots:oxides as carrier-transport layers and introducing molybdenum oxide nanoparticles as a hole-inject layer[J].ACS Appl Mater Interfaces,2014,6(14):11348-11356.
[50] Chen G Y,Seo J W,Yang C H,et al.Nanochemistry and nanomaterials for photovoltaics[J].Chem Soc Rev,2013,42(21):8304-8338.
[51] Han J H,Liu Z F,Guo K Y,et al.High-efficiency AgInS₂-modified ZnO nanotube array photoelectrodes for All-Solid-State hybrid solar cells[J].ACS Appl Mater Interfaces,2014,6(19):17119-17125.