化工新型材料

化工新型材料 ›› 2018, Vol. 46 ›› Issue (11) : 31-34.

综述与专论

聚合物本质阻燃改性研究新进展

^2,3

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作者信息 +

Research progress in inherent flame retardance modification of polymer

Mao Zhengzhou¹, Wu Yancheng^2,3, Wang Zhaoyang²

Author information +

文章历史 +

Received		Published
2017-07-04		2018-11-20
Issue Date	Revised Date
2018-12-04	2017-07-04

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摘要

聚合物本质阻燃改性通过共聚的方式,将磷、氮、硅和卤素等阻燃元素或耐高温单体直接引入聚合物主链或侧链中,以提高聚合物材料的阻燃性,克服了一般添加型阻燃剂易于从聚合物表面迁移或挥发的缺点,且除提高阻燃性能外对聚合物的其他性能影响较小。按照聚合物材料和引入阻燃元素的不同类型,综述了近3年聚合物本质阻燃改性的研究进展,展望了其发展方向,指出无卤型反应性新单体的设计是聚合物本质阻燃改性的关键。

Abstract

Overcoming the disadvantages of adding additive that the flame retardant is easy to move or evaporate from the polymer matrix,the inherent flame retardance modification of polymer exhibits superior flame retardance,it can greatly enhance the flame-retardant property without changing other properties.Inherent flame retardance modification of polymer usually is realized via copolymerization with a functional monomer containing flame retardant elements,such as P,N,Si and halogen.Classifying as different polymer and flame retardant type,the recent progresses in the inherent flame retardance modification of polymer were reviewed and prospected their development direction.It can be pointed out that the design of non-halogen reactive monomer was the key to the modification of inherent flame retardance of polymer.

关键词

聚合物 / 阻燃剂 / 本质阻燃改性 / 反应性单体 / 研究进展

Key words

polymer / flame retardant / inherent flame retardance modification / reactive monomer / research progress

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] 张利芬,杨先贵,王公应.反应型阻燃剂在聚合物中的应用研究进展[J].工程塑料应用,2014,42(7):114-117.
[2] Chen L,Wang Y Z.A review on flame retardant technology in China.Part Ⅰ:Development of flame retardants[J].Polym Adv Technol,2010,21(1):1-26.
[3] 许虹,计红梅,张振雄,等.聚酯纤维阻燃改性进展[J].合成技术及应用,2016,31(3):21-24.
[4] Wang J S,Zhao H B,Ge X G,et al.Novel flame-retardant and antidripping branched polyesters prepared via phosphorus-containing ionic monomer as end-capping agent[J].Ind Eng Chem Res,2010,49(9):4190-4196.
[5] 马敬红,龚静华,杨曙光,等.分子内阻燃PET纤维的结构性能[J].纺织学报,2012,33(6):107-110.
[6] Zhang Y,Chen L,Zhao J J,et al.Phosphorus-containing PET ionomer:from ionic aggregates to flame retardance and restricted melt-dripping[J].Polym Chem,2014,5(6):1982-1991.
[7] Zhang Y,Ni Y P,He M X,et al.Phosphorus-containing copolyesters:the effect of ionic group and its analogous phosphorus heterocycles on their flame-retardant and anti-dripping performances[J].Polymer,2015,60:50-61.
[8] Jing X K,Wang X S,Guo D M,et al.The high-temperature self-crosslinking contribution of azobenzene groups to the flame retardance and anti-dripping of copolyesters[J].J Mater Chem A,2013,1(32):9264-9272.
[9] Dong X,Chen L,Duan R T,et al.Phenylmaleimide-containing PET-based copolyester:cross-linking from 2π+π cycloaddition toward flame retardance and anti-dripping[J].Polym Chem,2016,7(15):2698-2708.
[10] Guo D M,Chen X Q,Tang L,et al.PET-based copolyesters with bisphenol A or bisphenol F structural units:Their distinct differences in pyrolysis behaviours and flameretardant performances[J].Polym Degrad Stab,2015,120:158-168.
[11] Guo D M,Fu T,Ruan C,et al.A new approach to improving flame retardancy,smoke suppression and anti-dripping of PET:via arylene-ether units rearrangement reactions at high temperature[J].Polymer,2015,77:21-31.
[12] Fu T,Guo D M,Wu J N,et al.Inherent flame retardation of semi-aromatic polyesters via binding small-molecule free radicals and charring[J].Polym Chem,2016,7(8):1584-1592.
[13] Zhao X M,Guerrero F R,Lorca J,et al.New superefficiently flame-retardant bioplastic poly(lactic acid):flammability,thermal decomposition behavior,and tensile properties[J].ACS Sustainable Chem Eng,2016,4(1),202-209.
[14] Jing J,Zhang Y,Fang Z P.Diphenolic acid based biphosphate on the properties of polylactic acid:synthesis,fire behavior and flame retardant mechanism[J].Polymer,2017,108:29-37.
[15] 杨立新,胡秀丽,黄宇彬,等.阻燃型聚乳酸基聚氨酯的合成与表征[J].应用化学,2016,33(1):47-52.
[16] Yuan X Y,Wang D Y,Chen L,et al.Inherent flame retardation of bio-based poly(lactic acid) by incorporating phosphorus linked pendent group into the backbone[J].Polym Degrad Stab,2011,96(9):1669-1675.
[17] Wang D Y,Song Y P,Lin L,et al.A novel phosphorus-containing poly(lactic acid) toward its flame retardation[J].Polymer,2011,52(2):233-238.
[18] 毛郑州,李建晓,薛福玲,等.阻燃剂苯并咪唑的微波合成研究进展[J].化学研究与应用,2012,24(4):497-502.
[19] 莫广珍,吴彦城,王群芳,等.胺甲基苯并咪唑改性聚乳酸的合成与表征[A].全国高分子学术论文报告会[C].苏州:2015.217.
[20] Xiong J F,Luo S H,Wang Q F,et al.Synthesis and characterization of a novel flame retardant,poly(lactic acid-co-3,3′-diaminobenzidine)[J].Des Monomers Polym,2013,16(4):389-397.
[21] Xiong J F,Wang Q F,Peng P,et al.Design,synthesis and characterization of a potential flame retardant poly(lactic acid-co-pyrimidine-2,4,5,6-tetramine) via direct melt polycondensation[J].J Appl Polym Sci,2014,131(10):40275.
[22] 汪朝阳,熊金峰.一种相容性聚乳酸阻燃剂的制备方法:中国,201210207082.8[P].2014-02-05.
[23] Wang X L,Chen L,Wu J N,et al.Flame-retardant pressure-sensitive adhesives derived from epoxidized soybean oil and phosphorus-containing dicarboxylic acids[J].ACS Sustainable Chem Eng,2017,5(4):3353-3361.
[24] Wirasaputra A,Yao X H,Zhu Y M,et al.Flame-retarded epoxy resins with a curing agent of DOPO-triazine based anhydride[J].Macromol Mater Eng,2016,301:982-991.
[25] Zhang Y C,Xu B Q,Xu G L,et al.Preparation of phosphorous- and nitrogen-containing epoxy emulsion and its flame retardancy[J].Polym Bull,2016,73(5):1393-1403.
[26] Chang H C,Lin H T,Lin C H,et al.Facile preparation of a phosphinated bisphenol and its low water-absorption epoxy resins for halogen-free copper clad laminates[J].Polym Degrad Stab,2013,98(1):102-108.
[27] Xu W H,Wirasaputra A,Liu S M,et al.Highly effective flame retarded epoxy resin cured by DOPO-based co-curing agent[J].Polym Degrad Stab,2015,122:44-51.
[28] Luo Q Q,Yuan Y C,Dong C L,et al.High performance fire-retarded epoxy imparted by a novel phenophosphazine-containing antiflaming compound at ultra-low loading[J].Mater Lett,2016,169:103-106.
[29] Yu B,Shi Y Q,Yuan B H,et al.Enhanced thermal and flame retardant properties of flame-retardant-wrapped graphene/epoxy resin nanocomposites[J].J Mater Chem A,2015,3(15),8034-8044.
[30] Yu B,Xing W Y,Guo W W,et al.Thermal exfoliation of hexagonal boron nitride for effective enhancements on thermal stability,flame retardancy and smoke suppression of epoxy resin nanocomposites via sol-gel process[J].J Mater Chem A,2016,4(19),7330-7340.
[31] 李跃文,陈兴华.聚氨酯阻燃改性研究进展[J].现代塑料加工应用,2014,26(5):53-56.
[32] Chen M J,Chen C R,Tan Y,et al.Inherently flame-retardant flexible polyurethane foam with low content of phosphorus-containing cross-linking agent[J].Ind Eng Chem Res,2014,53(3):1160-1171.
[33] Ding H-Y,Wang J F,Liu J,et al.Preparation and properties of a novel flame retardant polyurethane quasi-prepolymer for toughening phenolic foam[J].J Appl Polym Sci,2015,132(35):42424.
[34] Wazarkar K,Kathalewar M,Sabnis A.Improvement in flame retardancy of polyurethane dispersions by newer reactive flame retardant[J].Prog Org Coat,2015,87:75-82.
[35] Ge H,Wang W,Pan Y,et al.An inherently flame-retardant polyamide containing a phosphorus pendent group prepared by interfacial polymerization[J].RSC Adv,2016,6(85):81802-81808.
[36] Xie X X,Wang Z,Zhang K,et al.Novel phosphorous-nitrogen containing poly(aryl ether ketone)s:synthesis,characterization,and thermal properties[J].Des Monomers Polym,2013,16(1):38-46.
[37] 张兴迪,党国栋,王冬佶.含磷阻燃耐高温聚芳醚/聚芳醚酮共聚物合成与表征[J].高分子学报,2016(4):449-456.
[38] Hu W Z,Zhan J,Hong N N,et al.Flame retardant polystyrene copolymers:preparation,thermal properties,and fire toxicities[J].Polym Adv Technol,2014,25(6):631-637.
[39] Jiang S H,Zhu Y L,Hu Y,et al.In situ synthesis of a novel transparent poly(methyl methacrylate) resin with markedly enhanced flame retardancy[J].Polym Adv Technol,2016,27(2):266-272.