氧化石墨烯(GO)由于其独特的物理化学性质而在先进材料领域引起广泛关注。石墨烯作为一种机械强度高的蜂窝状的单分子层二维网络结构碳纳米材料,在分离膜领域表现出了优异的性能。基于石墨烯材料结构特点,对其膜材料的制备方法、传质机理及膜分离技术应用进行了概述,旨在为石墨烯膜材料的推广提供理论基础与实践经验。
Graphene oxide has attracted wide attention in the field of advanced materials because of its unique physical and chemical properties.As a kind of honeycomb monolayer of carbon nano materials with two-dimensional network structure and has high mechanical strength,graphene has excellent performance in the field of separation membrane.Based on the superior characteristics of graphene oxide,the preparation method and membrane separation of graphene oxide membranes were summarized in order to promote the application of graphene oxide materials.
[1] 张祥中.膜法水处理技术应用于生活污水深度处理[J].福建建筑,1994,41(3):39-42.
[2] Laberty-Robert C,Valle K,Perira F,et al.Design and properties of functional hybrid organic-inorganic membranes for fuel cells[J].Chemical Society Reviews,2011,40(2):961-1005.
[3] 方东宇,李伟,陈欢林.敏感性高分子功能膜的研究进展[J].功能高分子学报,2000,19(4):442-446.
[4] Yang Z,Cheng J C,Yang C,et al.CFD-based optimization and design of multi-channel inorganic membrane tubes[J].Chinese Journal of Chemical Engineering,2016,24(10):1375-1385.
[5] Hwang S.Inorganic membranes and membrane reactors[J].Korean Journal of Chemical Engineering,2001,18(6):775-787.
[6] Jiang Z D,Wang J Q.Dehydrogenation of ethylbenzene to styrene in an inorganic membrane reactor[J].Separation Science and Technology,1998,9(33):1379-1385.
[7] 李永生,王金渠.沸石膜的合成、表征与应用[J].化学通报,2001,3(12):755-761.
[8] Wang B,Jackson E A,Hoff J W,et al.Fabrication of zeolite/polymer composite membranes in a roller assembly[J].Microporous and Mesoporous Materials,2016,223:247-253.
[9] Kida K,Maeta Y,Yogo K.Preparation and gas permeation properties on pure silica CHA-type zeolite membranes[J].Journal of Membrane Science,2017,522:363-370.
[10] Corry B.Designing carbon nanotube membranes for efficient water desalination[J].The Journal of Physical Chemistry B,2008,112(5):1427-1434.
[11] Holt J K,Wang Y M.Fast mass transport through sub-2-nanometer carbon nanotubes[J].Science,2006,312(5776):1034-1037.
[12] Hinds B J,Chopra N,Rantell T,et al.Aligned multiwalled carbon nanotube membranes[J].Science,2004,303(5654):62-65.
[13] Kalra A,Garde S,Hummer G.Osmotic water transport through carbon nanotube membranes[J].Proceedings of the National Academy of Sciences of the United States of America,2003,100(18):10175-10180.
[14] 王茜,郭晓燕,邵怀启,等.石墨烯及氧化石墨烯对分离膜改性的方法、效能和作用机理[J].化学进展,2015,27(10):1470-1480.
[15] Han Y,Xu Z,Gao C.Ultrathin graphene nanofiltration membrane for water purification[J].Advanced Functional Materials,2013,23(29):3693-3700.
[16] Shan M,Xue Q,Jing N,et al.Influence of chemical functionalization on the CO2/N2 separation performance of porous graphene membranes[J].Nanoscale,2012,4(17):5477-5482.
[17] Molina J,Bonastre J,Fernndez J,et al.Electrochemical synthesis of polypyrrole doped with graphene oxide and its electrochemical characterization as membrane material[J].Synthetic Metals,2016,220:300-310.
[18] Guo X,Qu L,Zhu S,et al.Preparation of three-dimensional chitosan-graphene oxide aerogel for residue oil removal[J].Water Environment Research,2016,88(8):768-778.
[19] 张婷婷,张国亮,李万斌.氧化石墨烯膜的制备方法研究进展[J].浙江化工,2016,47(9):47-50.
[20] Eda G,Fanchini G,Chhowalla M.Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material[J].Nature Nanotechnology,2008,3(5):270-274.
[21] Li H,Song Z,Zhang X,et al.Ultrathin,molecular-sieving graphene oxide membranes for selective hydrogen separation[J].Science,2013,342(6154):95-98.
[22] 杜红斌.氧化石墨烯复合膜的制备及其性能研究[D].太原:中北大学,2016.
[23] Wu J B,Becerril H A,Bao Z N,et al.Organic solar cells with solution-processed graphene transparent electrodes[J].Applied Physics Letters,2008,92(26):43-48.
[24] Becerril H A,Mao J,Liu Z,et al.Evaluation of solution-processed reduced graphene oxide films as transparent conductors[J].ACS Nano,2008,2(3):463-470.
[25] Gilje S,Han S,Wang M S,et al.A chemical route to graphene for device applications[J].Nano Letters,2007,7(11):3394-3398.
[26] 李太平.石墨烯复合材料的制备及作为DSSCs对电极的应用研究[D].武汉:湖北大学,2013.
[27] Vollmer A,Feng X L,Wang X,et al.Electronic and structural properties of graphene-based transparent and conductive thin film electrodes[J].Applied Physics A,2009,94(1):1-4.
[28] Lee B,Yu H,Jeong G.Controlled synthesis of monolayer graphene toward transparent flexible conductive film application[J].Nanoscale Research Letters,2010,5(11):1768-1773.
[29] Kim K S,Zhao Y,Jang H,et al.Large-scale pattern growth of graphene films for stretchable transparent electrodes[J].Nature,2009,457(5):706-710.
[30] 杨晓洁.氧化石墨烯LB膜的制备与特性研究[D].成都:电子科技大学,2015.
[31] 黄河洲,贺蕴秋,李文有,等.电化学法制备的还原氧化石墨烯薄膜及其光电性能研究[J].发光学报,2014,35(2):142-148.
[32] Yang Y,Bolling L,Priolo M A,et al.Super gas barrier and selectivity of graphene oxide-polymer multilayer thin films[J].Advanced Materials,2013,25(4):503-508.
[33] Chen C,Yang Q,Yang Y,et al.Self-assembled free-standing graphite oxide membrane[J].Advanced Materials,2009,21(29):3007-3011.
[34] Nair R R,Wu H A,Jaireram P N,wt al.Unimpeded permeation of water through helium-leak-tight graphene-based membranes[J].Science,2012,442(335):442-444.
[35] Kim H W,Yoon H W,Yoon S M,et al.Selective gas transport through few-layered graphene and graphene oxide membranes[J].Science,2013,342(6154):91-95.
[36] Sun P,Zhu M,Wang K,et al.Selective ion penetration of graphene oxide membranes[J].ACS Nano,2013,7(1):428-437.
[37] Huang H,Mao Y,Ying Y,et al.Salt concentration,pH and pressure controlled separation of small molecules through lamellar graphene oxide membranes[J].Chemical Communications,2013,49(53):5963-5965.
[38] Hu M,Mi B.Enabling graphene oxide nanosheets as water separation membranes[J].Environmental Science & Technology,2013,47(8):3715-3723.
[39] Joshi R K,Carbone P,Wang F C,et al.Precise and ultrafast molecular sieving through graphene oxide membranes[J].Science,2014,343(6172):752-754.
基金资助
天津市应用基础与前沿技术研究计划(15JCYBJC18000);天津市应用基础与前沿技术研究计划重点项目(14JCZDJC37200)