A series of PVA red-light films were fabricated thought doping the pure red-light Eu-complex Eu(TTA)2TPY-OCH3 into PVA matrix,then the structures and properties of PVA fluorescent films were characterized and analyzed by FT-IR,UV-Vis,PL,DSC and TGA,etc.The results showed that with the increase of concentration of europium complexes,the emission intensity of film gradually strengthen which the content of europium complexes from 1% to 7%,and the Tg of PVA fluorescence film decreased with the increase of europium complexes content.In addition,Td-5% decomposition temperature of films all were from 230℃ to 240℃,which had better thermal stability and can be meet their application in many fields.
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基金资助
国家自然科学基金(21404017);重庆市创新能力建设项目以及重庆市社会事业与民生保障创新专项(cstc2013kjrc-qnrc50003和cstc2016shmszx80052);重庆市教委科学技术研究项目(KJ1709223)
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