聚合离子液体嵌段共聚物的合成研究进展

王俊豪, 沈越, 金妮, 李致轩, 海智宝, 雷良才, 李海英*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (9) : 60 -64.

PDF (1201KB)
化工新型材料 ›› 2018, Vol. 46 ›› Issue (9) : 60-64.
综述与专论

聚合离子液体嵌段共聚物的合成研究进展

    王俊豪, 沈越, 金妮, 李致轩, 海智宝, 雷良才, 李海英*
作者信息 +

Review of the synthesis of polymeric ionic liquid block copolymer

  • Wang Junhao, Shen Yue, Jin Ni, Li Zhixuan, Hai Zhibao, Lei Liangcai, Li Haiying
Author information +
文章历史 +
PDF (1229K)

摘要

聚合离子液体嵌段共聚物(PILs-block-copolymer)是一种集离子液体和高聚物特性为一体的新型材料,在电池、吸附分离、药物释放等领域有诸多应用。近年来,新型聚合离子液体嵌段共聚物的合成受到研究者广泛的关注,迄今为止,已有多种类型的含有聚合离子液体链段的嵌段共聚物被报道。活性可控聚合技术是合成具有明确结构的离子液体嵌段共聚物的主要方法。对近年来该领域的研究进行了综述。

Abstract

Polymeric ionic liquid block copolymer is a new type of polymers that combine the advantages of both ionic liquid and block copolymer together,has many applications in electric battery,adsorption and separation,drug release and so on.Recent years,the synthesis of new PILs-block-copolymer has been led to great interest by researchers,so far,several types of PILs-block-copolymer were reported.Controlled polymerization techniques were the main method to structure block copolymer,the particular controlled synthesis of polymeric ionic liquid block copolymer was introduced.

关键词

离子液体 / 聚合离子液体 / 可控聚合 / 嵌段共聚物

Key words

ionic liquid / poly(ionic liquid)s / controlled polymerization / block copolymer

引用本文

引用格式 ▾
聚合离子液体嵌段共聚物的合成研究进展[J]. 化工新型材料, 2018, 46(9): 60-64 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1]Meek K M,Elabd Y A.Polymerized ionic liquid block copolymers for electrochemical energy[J].Journal of Materials Chemistry A,2015,3(48):24187-24194.
[2]Banerjee A,Theron R,Scott R W J.Redispersion of transition metal nanoparticle catalysts in tetraalkylphosphonium ILs[J].Chemical Communications,2013,49(31):3227-3229.
[3]张红燕,刘崴崴,王华平.以离子液体为溶剂的原子转移自由基聚合[J].高分子通报,2007,(3):17-22.
[4]Murugesan S,Akkineni A,Chou B P,et al.Room temperature electrodeposition of molybdenum sulfide for catalytic and photoluminescence applications[J].ACS nano,2013,7(9):8199-8205.
[5]吕晓文,李露,林章碧,等.离子液体再生纤维素水凝胶的形成机理及其在凝胶电泳中的应用[J].高分子学报,2011,(9):1026-1032.
[6]Sun M,Feng J,Wang X,et al.Dicationic imidazolium ionic liquid modified silica as a novel reversed-phase/anion-exchange mixed-mode stationary phase for high-performance liquid chromatography[J].Journal of Separation Science,2014,37(16):2153-2159.
[7]Jain N,Kumar A,Chauhan S,et al.Chemical and biochemical transformations in ionic liquids[J].Tetrahedron,2005,61(5):1015-1060.
[8]何晓燕,徐晓君,周文瑞,等.聚离子液体的合成及应用[J].高分子通报,2013,(5):17-28.
[9]Ohno H,Ito K.Room-temperature molten salt polymers as a matrix for fast ion conduction[J].Chemistry Letters,1998,(8):751-752.
[10]Ye Y,Elabd Y A.Anion exchanged polymerized ionic liquids:high free volume single ion conductors[J].Polymer,2011,52(5):1309-1317.
[11]Stancik C M,Lavoie A R,Schütz J,et al.Micelles of imidazolium-functionalized polystyrene diblock copolymers investigated with neutron and light scattering[J].Langmuir,2004,20(3):596-605.
[12]Stancik C M,Lavoie A R,Achurra P A,et al.A neutron scattering study of the structure and water partitioning of selectively deuterated copolymer micelles[J].Langmuir,2004,20(21):8975-8987.
[13]Ye Y,Choi J H,Winey K I,et al.Polymerized ionic liquid block and random copolymers:effect of weak microphase separation on ion transport[J].Macromolecules,2012,45(17):7027-7035.
[14]Weber R L,Ye Y,Banik S M,et al.Thermal and ion transport properties of hydrophilic and hydrophobic polymerized styrenic imidazolium ionic liquids[J].Journal of Polymer Science Part B:Polymer Physics,2011,49(18):1287-1296.
[15]Ohno H.Molten salt type polymer electrolytes[J].Electrochimica Acta,2001,46(10):1407-1411.
[16]Carrasco P M,Tzounis L,Mompean F J,et al.Thermoset magnetic materials based on poly(ionic liquid)s block copolymers[J].Macromolecules,2013,46(5):1860-1867.
[17]Carrasco P M,Luzuriaga A R D,Constantinou M,et al.Influence of anion exchange in self-assembling of polymeric ionic liquid block copolymers[J].Macromolecules,2011,44(12):4936-4941.
[18]Schneider Y,Modestino M A,Mcculloch B L,et al.Ionic conduction in nanostructured membranes based on polymerized protic ionic liquids[J].Macromolecules,2013,46(4):1543-1548.
[19]Agudelo N A,Elsen A M,He H,et al.ABA triblock copolymers from two mechanistic techniques:polycondensation and atom transfer radical polymerization[J].Journal of Polymer Science Part A Polymer Chemistry,2015,53(2):228-238.
[20]McCullough L A,Dufour B,Matyjaszewski K.Incorporation of poly(2-acrylamido-2-methyl-N-propanesulfonic acid) segments into block and brush copolymers by ATRP[J].Journal of Polymer Science Part A Polymer Chemistry,2009,47(20):5386-5396.
[21]Karjalainen E,Khlebnikov V,Korpi A,et al.Complex interactions in aqueous PIL-PNIPAm-PIL triblock copolymer solutions[J].Polymer,2015,58:180-188.
[22]段然,吉虎,孙跃文,等.PMM-b-QPDMAEMA的合成及其抗菌活性[J].合成化学,2016,24(11):950-955.
[23]Wiesenauer E F,Edwards J P,Scalfani V F,et al.Synthesis and ordered phase separation of imidazolium-based alkyl-ionic diblock copolymers made via ROMP[J].Macromolecules,2011,44(13):5075-5078.
[24]Wiesenauer E F,Nguyen P T,Newell B S,et al.Imidazolium-containing,hydrophobic-ionic-hydrophilic ABC triblock copolymers:synthesis,ordered phase-separation,and supported membrane fabrication[J].Soft Matter,2013,9(33):7923-7927.
[25]Suga T,Sakata M,Aoki K,et al.Synthesis of pendant radical- and ion-containing block copolymers via ring-opening metathesis polymerization for organic resistive memory[J].Acs Macro Letters,2014,3(8):703-707.
[26]Meek K M,Sharick S,Ye Y,et al.Bromide and hydroxide conductivity-morphology relationships in polymerized ionic liquid block copolymers[J].Macromolecules,2015,48(14):4850-4862.
[27]Cotanda P,Sudre G,Modestino M A,et al.High anion conductivity and low water uptake of phosphonium containing diblock copolymer membranes[J].Macromolecules,2014,47(21):7540-7547.
[28]Cheng S,Beyer F L,Mather B D,et al.Phosphonium-containing ABA triblock copolymers:controlled free radical polymerization of phosphonium ionic liquids[J].Macromolecules,2011,44(16):6509-6517.
[29]Green M D,Choi J H,Winey K I,et al.Synthesis of imidazolium-containing ABA triblock copolymers:role of charge placement,charge density,and ionic liquid incorporation[J].Macromolecules,2012,45(11):4749-4757.
[30]Detrembleur C,Debuigne A,Hurtgen M,et al.Synthesis of 1-vinyl-3-ethylimidazolium-based ionic liquid (Co) polymers by cobalt-mediated radical polymerization[J].Macromolecules,2011,44(16):6397-6404.
[31]Coupillaud P,Fèvre M,Wirotius A,et al.Precision synthesis of poly(ionic liquid)-based block copolymers by cobalt-mediated radical polymerization and preliminary study of their self-assembling properties[J].Macromolecular Rapid Communications,2014,35(4):422-430.
[32]Cordella D,Debuigne A,Jérôme C,et al.One-pot synthesis of double poly(ionic liquid) block copolymers by cobalt-mediated radical polymerization-induced self-assembly (CMR-PISA) in water[J].Macromolecular Rapid Communications,2016,37(14):1181-1187.

基金资助

国家自然科学基金(21544008)

AI Summary AI Mindmap
PDF (1201KB)

695

访问

0

被引

导航
相关文章

AI思维导图

/