氯化法制备纳米TiO2氧化机理的研究进展

田林1,3, 黄俊2, 李荣兴2*, 李威1,2, 谢刚1,3, 杨妮1,3, 俞小花2

化工新型材料 ›› 2018, Vol. 46 ›› Issue (8) : 238 -243.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (8) : 238-243. DOI:
开发与应用

氯化法制备纳米TiO2氧化机理的研究进展

    田林1,3, 黄俊2, 李荣兴2*, 李威1,2, 谢刚1,3, 杨妮1,3, 俞小花2
作者信息 +

Research progress of oxidation mechanism of chlorination method for titanium dioxide

  • Tian Lin1,3 Huang Jun2, Li Rongxing2, Li Wei1,2, Xie Gang1,3, Yang Ni1,3, Yu Xiaohua2
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摘要

随着纳米TiO2在光催化、新能源以及医疗杀菌等领域的推广应用,纳米TiO2在国民生产中的作用越来越大,其生产方法也广泛地得到人们的重视。介绍了使用较多的液相法、硫酸法、氯化法制备纳米TiO2的3种方法,综述了各方法的优缺点及研究进展。重点介绍了纳米TiO2主流生产工艺氯化法,分别从氧化反应器设计、结疤的处理及产品形态控制3个方面对研究现状进行分析。重点阐述了氯化法生产纳米TiO2核心工艺TiO2的气相成核、晶核生长反应机理的研究进展。最后根据目前存在的主要问题,提出解决工艺关键技术及微观机理研究的建议和研究方向。

Abstract

The development of promotion and application of nano titanium dioxide in photocatalysis,new energy and medical sterilization is elaborated,The nano titanium dioxide in the fields of national production becomes more and more important,the production method get people’s attention widely.Three preparation methods of nano titanium dioxide which used of more:liquid phase method,sulfuric acid method and chlorination method were introduced,and summarized the advantages and research progress.The chlorination method as mainstream production technology of nanometer titanium dioxide was focused,analyzed the research status from the three aspects of oxidation reactor design,the scarring processing and control of product form.The research progress on the chlorination method of nanometer titanium dioxide core process including TiO2 vapor nucleation and crystal nuclear growth reaction mechanism were focused.Finally,according to the existing problems,the proposal and research direction of solutions for key technology and micro mechanism researches were put.

关键词

TiO2 / 制备方法 / 氯化法 / 关键技术 / 微观机理

Key words

titanium dioxide / preparation method / chlorination / key technology / micro mechanism

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氯化法制备纳米TiO2氧化机理的研究进展[J]. 化工新型材料, 2018, 46(8): 238-243 DOI:

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基金资助

国家自然科学基金(51404123);云南省应用基础研究计划(2013FC003)

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