通过配位化学合成得到的金属有机骨架化合物(MOFs)在气体贮存、分子分离、催化以及药物缓释等领域具有广阔的应用前景。近年来,MOFs在含能材料领域,特别是在高能钝感材料领域的应用潜力日益突出。按照MOFs空间骨架结构的分类,分别综述了一维、二维以及三维MOFs材料的合成及表征,着重讨论了不同空间结构的MOFs材料所具有的能量特性和钝感特性。可以预见,含能MOFs将为设计与合成新一代高能、低感度的绿色含能材料提供一个崭新的研究思路。
Metal organic framework (MOFs) obtained through coordination chemistry synthesis has a wide application potential in fields of gas reservation,molecular isolation,catalysis and drug sustained release.In recent years,MOFs has a growing potential in energetic materials fields,especially in high energy insensitive filler.According to the classification of space structure of MOFs,the synthesis and characterization of one-dimensional,two-dimensional and three-dimensional MOFs were reviewed.The discussion on energy features and insensitive features with different structure were highlighted.It is expected that energetic MOFs can provide a whole new solution on designing and synthesizing the new generation of high-energy,low-sensitivity and green energetic materials.
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基金资助
总装备部预先研究项目(004040204)
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