羟基吡啶型离子液体及其复配体系对CO2的吸收性能研究

金羿, 卫慧凯, 段东红*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (7) : 209 -211.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (7) : 209-211.
科学研究

羟基吡啶型离子液体及其复配体系对CO2的吸收性能研究

    金羿, 卫慧凯, 段东红*
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Investigation of CO2 absorption property of hydroxypyridine ionic liquid and their complex system

  • Jin Yi, Wei Huikai, Duan Donghong
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摘要

合成并考察了羟基吡啶型离子液体(IL)与1,8-二氮杂二环十一碳-7-烯(DBU)进行复配对二氧化碳(CO2)的吸收性能。研究结果表明,由四丁基氢氧化磷([P4444][OH])与3-羟基吡啶(3-Hp)制得的羟基吡啶型IL[3-羟基吡啶四丁基磷盐([P4444][3-Op])]有较好的吸收性能,吸收容量达到1.06mol CO2/mol IL,DBU与[P4444][3-Op]复配后的[P4444][3-Op]/DBU对CO2的吸收容量可达到1.2mol CO2/mol IL,采用复配方式能有效提高羟基吡啶型IL的吸收容量。

Abstract

The hydroxypyridine ionic liquids were synthesized.The absorbance capacity of 1,8-Diazabicyclo [5.4.0] undec-7-ene (DBU) and [P4444][3-Op] mixed absorption solvent to CO2 was investigated.Experimental results showed that the absorption capacity of the hydroxypyridine ionic liquids [P4444][3-Op] by the reaction of tetrabutylphosphonium hydroxide and 3-hydroxypyridine was better,whose absorption capacity could be achieved to 1.06mol CO2/mol IL.The absorption capacity of complex solution can be achieved to 1.2mol CO2/mol IL,which improved the absorptive capacity of ionic liquids.

关键词

羟基吡啶型离子液体 / 吸收容量 / CO2捕集 / 复配

Key words

hydroxypyridine ionic liquid / absorbance capacity / CO2 capture / complex solution

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羟基吡啶型离子液体及其复配体系对CO2的吸收性能研究[J]. 化工新型材料, 2018, 46(7): 209-211 DOI:

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参考文献

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基金资助

山西省煤基重点科技攻关项目(MD2014-09)

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