纳米Cu-SiO2复合粒子改性聚醚砜超滤膜的制备及分离性能研究

喻文娟1, 金亚铃2, 胡滋苗2, 黄健2

化工新型材料 ›› 2018, Vol. 46 ›› Issue (7) : 118 -122.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (7) : 118-122.
新材料与新技术

纳米Cu-SiO2复合粒子改性聚醚砜超滤膜的制备及分离性能研究

    喻文娟1, 金亚铃2, 胡滋苗2, 黄健2
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Research on fabrication and separation performance of polyethersulfone ultrafiltration membrane incorporated by mCu-SiO2 nanocomposite

  • Yu Wenjuan1, Jin Yaling2, Hu Zimiao2, Huang Jian2
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摘要

将纳米Cu负载至介孔二氧化硅(mSiO2)表面制得mSiO2-Cu抗菌材料,利用相转化法制备出聚醚砜(PES)/mSiO2-Cu抗污染复合膜,研究了mSiO2-Cu含量对PES超滤膜结构、抗污染及分离性能的影响。结果表明,当mSiO2-Cu质量分数为2%时,PES/mSiO2-Cu复合膜的纯水通量可达185L/(m2·h),是PES基膜的1.9倍,该复合膜对蛋白具有良好的抗污染性能。将PES/mSiO2-Cu复合膜应用于河水处理,结果表明PES/mSiO2-Cu复合膜具有良好的总有机碳去除率和稳定性。

Abstract

Antifouling performance is one of the most important issues in polymer membrane surface engineering,fabrication of anti-fouling membrane for the development of membrane separation technology is of great important.The copper nanoparticles were immobilized on the mesoporous silica surface to prepare mSiO2-Cu nanocomposites and the polyethersulfone nanocomposite membrane was fabricated by incorporating the mSiO2-Cu nanoparticles.The influence of particles on the membrane structure,antifouling and separation performances were evaluated.The results indicated that the pure water flux of membrane with 2% of mSiO2-Cu can reach 185L/(m2·h),which was 1.9 times that of PES basement membrane.The composite membrane had good antifouling property to the protein.When applied to the actual river water treatment,the results showed that PES/mSiO2-Cu membrane had good TOC removal rate and stability.

关键词

抗污染 / 纳米Cu介孔二氧化硅 / 复合膜

Key words

antifouling / copper nanoparticles mSiO2 / nanocomposite membrane

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纳米Cu-SiO2复合粒子改性聚醚砜超滤膜的制备及分离性能研究[J]. 化工新型材料, 2018, 46(7): 118-122 DOI:

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参考文献

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基金资助

浙江省基础公益研究计划项目(LGF18B060001);丽水市公益性技术应用研究计划项目(2017GYX24);浙江省大学生科技创新活动计划(2017R431005)

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