功能化石墨烯材料在气体检测方面的应用研究进展

张星和, 杨晓娜, 符翠丽

化工新型材料 ›› 2018, Vol. 46 ›› Issue (7) : 9 -13.

PDF (1212KB)
化工新型材料 ›› 2018, Vol. 46 ›› Issue (7) : 9-13.
综述与专论

功能化石墨烯材料在气体检测方面的应用研究进展

    张星和, 杨晓娜, 符翠丽
作者信息 +

Research progress of functional graphene material for gas-detecting application

  • Zhang Xinghe, Yang Xiaona, Fu Cuili
Author information +
文章历史 +
PDF (1240K)

摘要

石墨烯是一种具有单原子层厚度的二维蜂窝状碳材料,由于其具有奇异的比表面积效应、光电效应和机械强度等优点,在能源、环境、军事和航天等领域得到了大量的研究。石墨烯材料的功能化可对其结构、物化性质和光电性质等方面进行有益调整,从而拓宽了其对化学物质的检测范围。主要综述了近期利用化学改性、纳米颗粒修饰和聚合物复合方法对石墨烯材料进行功能化改性的研究进展,以及功能化石墨烯材料在提高灵敏度和选择性等气体传感特性方面的应用,并对该领域存在的挑战和前景进行了展望。

Abstract

Graphene,a two-dimensional carbon material only with a structure of honeycomb lattice which having a single-atom-thick layer,has attractive much research in many fields including energy,environment,military and aerospace,due to its fantastic properties of specific surface,photoelectric effect and mechanical strength.Functionalizing endows graphene favorable tailors such as the structure,physicochemical and photoelectrical properties,extending the detecting range of chemical species.It was discussed that the recent advancements in the functionalizing of graphene utilizing the methods of chemical modification,nanoparticle decoration and polymer hybrid,and the applications of functional graphene materials in improved gas sensing properties including sensitivity and selectivity.Finally,the remaining challenges and perspectives of this enticing field were provided.

关键词

石墨烯 / 改性 / 修饰 / 混合气体检测

Key words

grapheme / modification / decoration / hybrid gas-detecting

引用本文

引用格式 ▾
功能化石墨烯材料在气体检测方面的应用研究进展[J]. 化工新型材料, 2018, 46(7): 9-13 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Patra M K,Manzoor K,Manoth M,et al.Nanotechnology applications for chemical and biological sensors[J].Defence Science Journal,2008,58(5):636-649.
[2] Sharma S,Madou M.A new approach to gas sensing with nanotechnology[J].Phil Trans R Soc A,2012,370(1967):2448-2473.
[3] Varghese S H,Nair R,Nair B G,et al.Sensors based on carbon nanotubes and their applications:a review[J].Current Nanoscience,2010,6(4):331-346.
[4] Hill E W,Vijayaragahvan A,Novoselov K.Graphene sensors[J].IEEE Sensors Journal,2011,11(12):3161-3170.
[5] Mao S,Lu G H,Chen J H.Nanocarbon-based gas sensors:progress and challenges[J].Journal of Materials Chemistry A,2014,2(16):5573-5579.
[6] Llobet E.Gas sensors using carbon nanomaterials:a review[J].Sensors and Actuators B:Chemical,2013,179:32-45.
[7] Hu P A,Zhang J,Li L,et al.Carbon nanostructure-based field-effect transistors for label-free chemical/biological sensors[J].Sensors,2010,10(5):5133-5159.
[8] Yuan W J,Shi G Q.Graphene-based gas sensors[J].Journal of Materials Chemistry A,2013,1(35):10078-10091.
[9] He Q Y,Wu S X,Yin Z Y,et al.Graphene-based electronic sensors[J].Chemical Science,2012,3(6):1764-1772.
[10] Liu Y X,Dong X C,Chen P.Biological and chemical sensors based on graphene materials[J].Chemical Society Reviews,2012,41(6):2283-2307.
[11] Basu S,Bhattacharyya P.Recent developments on graphene and graphene oxide based solid state gas sensors[J].Sensors and Actuators B:Chemical,2012,173:1-21.
[12] Yavari F,Koratkar N.Graphene-based chemical sensors[J].Journal of Physical Chemistry Letters,2012,3:1746-1753.
[13] Zhou L,Shen F,Tian X,et al.Stable Cu2O nanocrystals grown on functionalized graphene sheets and room temperature H2S gas sensing with ultrahigh sensitivity[J].Nanoscale,2013,5(4):1564-1569.
[14] Cui S,Pu H,Mattson E C,et al.Ag nanocrystal as a promoter for carbon nanotube-based room-temperature gas sensors[J].Nanoscale,2012,4(19):5887-5894.
[15] Cui S,Pu H,Lu G,et al.Fast and selective room-temperature ammonia sensors using silver nanocrystal-functionalized carbon nanotubes[J].ACS Applied Materials and Interfaces,2012,4(9):4898-4904.
[16] Dong X C,Fu D L,Fang W J,et al.Doping single-layer graphene with aromatic molecules[J].Small,2009,5(12):1422-1426.
[17] Dong X C,Long Q,Wei A,et al.The electrical properties of graphene modified by bromophenyl groups derived from a diazonium compound[J].Carbon,2012,50(4):1517-1522.
[18] Georgakilas V,Otyepka M,Bourlinos A B,et al.Functionalization of graphene:covalent and non-covalent approaches,derivatives and applications[J].Chem Rev,2012,112(11):6156-6214.
[19] Lv R T,Terrones M.Towards new graphene materials:doped graphene sheets and nanoribbons[J].Mater Lett,2012,78:209-218.
[20] Maiti U N,Lee W J,Lee J M,et al.25th Anniversary article:chemically modified/doped carbon nanotubes & graphene for optimized nanostructures & nanodevices[J].Adv Mater,2014,26(1):40-67.
[21] Kong X K,Chen C L,Chen Q W.Doped graphene for metal-free catalysis[J].Chem SocRev,2014,43(8):2841-2857.
[22] Wang D W,Su D S.Heterogeneous nanocarbon materials for oxygen reduction reaction[J].Energy Environ Sci,2014,7(2):576-591.
[23] Usachov D,Vilkov O,Grüneis A,et al.Nitrogen-doped graphene:efficient growth,structure,and electronic properties[J].Nano Letters,2011,11(12):5401-5407.
[24] Niu F,Tao L M,Deng Y C,et al.Phosphorus doped graphene nanosheets for room temperature NH3 sensing[J].New Journal of Chemistry,2014,38(6):2269-2272.
[25] Lv R T,Chen G G,Li Q,et al.Ultrasensitive gas detection of large-area boron-doped grapheme[J].Proceedings of the National Academy of Sciences,2015,112(47):14527-14532.
[26] Niu F,Liu J M,Tao L M,et al.Nitrogen and silica co-doped graphene nanosheets for NO2 gas sensing[J].Journal of Materials Chemistry A,2013,1(20):6130-6133.
[27] Su P G,Shieh H C.Flexible NO2 sensors fabricated by layer-by-layer covalent anchoring and in situ reduction of graphene oxide[J].Sensors and Actuators B:Chemical,2014,190:865-872.
[28] Yoo S,Li X,Wu Y,et al.Ammonia gas detection by tannic acid functionalized and reduced graphene oxide at room temperature[J].Journal of Nanomaterials,2014,2014:1-6.
[29] Kaniyoor A,Jafri R I,Arockiadoss T,et al.Nanostructured Pt decorated graphene and multi walled carbon nanotube based room temperature hydrogen gas sensor[J].Nanoscale,2009,1(3):382-386.
[30] Li W W,Geng X M,Guo Y F,et al.Reduced graphene oxide wlectrically contacted graphene sensor for highly sensitive nitric oxide detection[J].ACS Nano,2011,5(9):6955-6961.
[31] Gutes A,Hsia B,Sussman A,et al.Graphene decoration with metal nanoparticles:towards easy integration for sensing applications[J].Nanoscale,2012,4(2):438-440.
[32] Chung M G,Kim D H,Seo D K,et al.Flexible hydrogen sensors using graphene with palladium nanoparticle decoration[J].Sensors and Actuators B:Chemical,2012,169:387-392.
[33] Pak Y,Kim S M,Jeong H,et al.Palladium-decorated hydrogen-gas sensors using periodically aligned graphene nanoribbons[J].ACS Applied Materials & Interfaces,2014,6(15):13293-13298.
[34] Mao S,Cui S M,Lu G H,et al.Tuning gas-sensing properties of reduced graphene oxide using tin oxide nanocrystals[J].Journal of Materials Chemistry,2012,22:11009-11013.
[35] Liu S,Yu B,Zhang H,et al.Enhancing NO2 gas sensing performances at room temperature based on reduced graphene oxide-ZnO nanoparticles hybrids[J].Sensors and Actuators B:Chemical,2014,202:272-278.
[36] Zhang H,Feng J C,Fei T,et al.SnO2 nanoparticles-reduced graphene oxide nanocomposites for NO2 sensing at low operating temperature[J].Sensors and Actuators B:Chemical,2014,190:472-478.
[37] Huang L,Wang Z P,Zhang J K,et al.Fully printed,rapid-response sensors based on chemically modified graphene for detecting NO2 at room temperature[J].ACS Applied Materials & Interfaces,2014,6(10):7426-7433.
[38] Mohammadi-Manesh E,Vaezzadeh M,Saeidi M.Cu- and CuO-decorated graphene as a nanosensor for H2S detection at room temperature[J].Surface Science,2015,636:36-41.
[39] Bai S L,Chen C,Luo R X,et al.Synthesis of MoO3/reduced graphene oxide hybrids and mechanism of enhancing H2S sensing performances[J].Sensors and Actuators B:Chemical,2015,216:113-120.
[40] Meng H,Yang W,Ding K,et al.Cu2O nanorods modified by reduced graphene oxide for NH3 sensing at room temperature[J].Journal of Materials Chemistry A,2015,3(3):1174-1181.
[41] Wang C,Liang S M,Bi H P,et al.Reduced graphene oxide decorated with CuO-ZnO hetero-junctions:towards high selective gas-sensing property to acetone[J].Journal of Materials Chemistry A,2014,2(43):18635-18643.
[42] Cui S M,Wen Z H,Mattson E C,et al.Indium-doped SnO2 nanoparticle-graphene nanohybrids:simple one-pot synthesis and their selective detection of NO2[J].Journal of Materials Chemistry A,2013,1(14):4462-4467.
[43] Mangu R,Rajaputra S,Singh V P.MWCNT-polymer composites as highly sensitive and selective room temperature gas sensors[J].Nanotechnology,2011,22(21):215502-215512.
[44] Srivastava S,Sharma S S,Agrawal S,et al.Study of chemiresistor type CNT doped polyaniline gas sensor[J].Synthetic Metals,2010,160(5-6):529-534.
[45] Huang X L,Hu N T,Gao R G,et al.Reduced graphene oxide-polyaniline hybrid:preparation,characterization and its applications for ammonia gas sensing[J].Journal of Materials Chemistry,2012,22(42):22488-22495.
[46] Parmar M,Balamurugan C,Lee D W.PANI and graphene/PANI nanocomposite films-comparative toluene gas sensing behavior[J].Sensors,2013,13(12):16611-16624.
[47] Ye Z B,Jiang Y D,Tai H L,et al.The investigation of reduced graphene oxide/P3HT composite films for ammonia detection[J].Integrated Ferroelectrics,2014,154(1):73-81.
[48] Xie T,Xie G Z,Zhou Y,et al.Thin film transistors gas sensors based on reduced graphene oxide poly(3-hexylthiophene) bilayer film for nitrogen dioxide detection[J].Chemical Physics Letters,2014,614:275-281.
[49] Mishra S K,Tripathi S N,Choudhary V,et al.SPR based fibre optic ammonia gas sensor utilizing nanocomposite film of PMMA/reduced graphene oxide prepared by in situ polymerization[J].Sensors and Actuators B:Chemical,2014,199:190-200.
[50] Hong J,Lee S,Seo J,et al.A highly sensitive hydrogen sensor with gas selectivity using a PMMA membrane-coated Pd nanoparticle/single-layer graphene hybrid[J].ACS Applied Materials & Interfaces,2015,7(6):3554-3561.
[51] Yang Y J,Yang X J,Yang W Y,et al.Porous conducting polymer and reduced graphene oxide nanocomposites for room temperature gas detection[J].RSC Adv,2014,4(80):42546-42553.
[52] Seekaew Y,Lokavee S,Phokharatkul D,et al.Low-cost and flexible printed grapheme-PEDOT:PSS gas sensor for ammonia detection[J].Organic Electronics,2014,15(11):2971-2981.

基金资助

保山学院校级课题(14BZ004)

AI Summary AI Mindmap
PDF (1212KB)

670

访问

0

被引

导航
相关文章

AI思维导图

/