石墨烯作为高导热、高导电、高比表面积的二维材料,在物理、化学等诸多领域具有重要的应用价值。目前高品质石墨烯低成本宏量制备,仍是阻碍下游产业化应用的瓶颈之一。液相剥离石墨制备石墨烯具有工艺简单、成本低、易于放大等特点,是当前规模化制备领域研究的热点。基于近年来液相剥离制备石墨烯的研究进展,综述了不同石墨烯前驱体和剥离方法对石墨烯品质、产率的影响,阐述了石墨烯宏量制备技术的发展动态。
Graphene is two-dimensional material which has high thermal conductivity,high conductivity and high specific surface area.It has potential applications in physics,chemistry and many other fields.The large scale preparation of high quality graphene at a low-cost is still a bottleneck for application in downstream industry.Therefore,the graphene preparation by exfoliating graphite in liquid is a hotspot,because of the feature of simple process,low cost,high-yield and others.The progress in graphene preparation by liquid exfoliation in recent years was reviewed,and summarized the influence of different graphene precursors and exfoliation methods on graphene's quality and yield.The recent development trends of large scale preparation of graphene was presented.
[1] Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2] Geim A K,Novoselov K S,The rise of graphene[J].Nature Materials,2007,6(3):183-191.
[3] Balandin A A,Ghosh S,Bao W Z,et al.Superior thermal conductivity of single-layer graphene[J].Nano Letters,2008,8(3):902-907.
[4] Liu T Y,Kim C J.Turning a surface superrepellent even to completely wetting liquids[J].Science,2014,346(6213):1096-1100.
[5] Bolotin K I,Sikes K J,Jiang Z,et al.Ultrahigh electron mobility in suspended graphene[J].Solid State Communications,2008,146(9/10):351-355.
[6] Chae H K,Siberio-Perez D Y,Kim J,et al.A route to high surface area,porosity and inclusion of large molecules in crystals[J].Nature,2004,427(6974):523-527.
[7] Hernandez Y,Nicolosi V,Lotya M,et al.High-yield production of graphene by liquid-phase exfoliation of graphite[J].Nature Nanotechnology,2008,3(9):563-568.
[8] Cai W,Piner R D,Stadermann F J,et al.Synthesis and solid-state NMR structural characterization of 13C-labeled graphite oxide[J].Science,2008,321(5897):1815-1817.
[9] Mitura S,Mitura K,Niedzielski P,et al.Nanocrystalline diamond,its synthesis,properties and applications[J].Journal of Achievements in Materials & Manufacturing Engineering,2006,16(1/2):9-16.
[10] Niyogi S,Bekyarova E,Itkis M E,et al.Solution properties of graphite and graphene[J].Journal of the American Chemical Society,2006,128(24):7720-7721.
[11] Li X,Zhang G,Bai X,et al.Highly conducting graphene sheets and Langmuir-Blodgett films[J].Natrue Nanotechnology,2008,3(9):538-542.
[12] Spanu L,Sorella S,Galli G.Nature and strength of interlayer binding in graphite[J].Physical Review Letters,2009,103(19):196401.
[13] Schafhaeutl C.Ueber die verbindungen des kohlenstoffes mit silicium,eisen und andern metallen,welche die verschiedenen arten von gusseisen,stahl und schmiedeeisen bilden[J].Journal fur Praktische Chemie-practical Applications and Applied Chemistry,1840,19(1):159-174.
[14] Naz A,Kausar A,Siddiq M.Influence of graphite filler on physicochemical characteristics of polymer/graphite composites:a review[J].Polymer-Plastics Technology and Engineering,2015,55(6):604-625.
[15] Hamilton C E,Lomeda J R,Sun Z Z,et al.High-yield organic dispersions of unfunctionalized graphene[J].Nano Letters,2009,9(10):3460-3462.
[16] Fu W,Kiggans J,Overbury S H,et al.Low-temperature exfoliation of multilayer-graphene material from FeCl3 and CH3NO2 co-intercalated graphite compound[J].Chemical Communications,2011,47(18):5265-5267.
[17] Khan U,O'Neill A,Lotya M,et al.High-concentration solvent exfoliation of graphene[J].Small,2010,6(7):864-871.
[18] Liu W W,Wang J N.Direct exfoliation of graphene in organic solvents with addition of NaOH[J].Chemical Communications,2011,47(24):6888-6890.
[19] Niu L,Li M,Tao X,et al.Salt-assisted direct exfoliation of graphite into high-quality,large-size,few-layer graphene sheets[J].Nanoscale,2013,5(16):7202-7208.
[20] Yang H,Hernandez Y,Schlierf A,et al.Asimple method for graphene production based on exfoliation of graphite in water using 1-pyrenesulfonic acid sodium salt[J].Carbon,2013,53:357-365.
[21] Chen J,Shi W,Fang D,et al.A binary solvent system for improved liquid phase exfoliation of pristine graphene materials[J].Carbon,2015,94:405-411.
[22] Siddique J A,Attia N F,Geckeler K E.Polymer nanoparticles as a tool for the exfoliation of graphene sheets[J].Materials Letters,2015,158:186-189.
[23] Guardia L,Fernández-Merino M J,Paredes J I,et al.High-throughput production of pristine graphene in an aqueous dispersion assisted by non-ionic surfactants[J].Carbon,2011,49(5):1653-1662.
[24] Paton K R,Varrla E,Backes C,et al.Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids[J].Nature Materials,2014,13(6):624-630.
[25] Barwich S,Coleman J N,Mobius M E.Yielding and flow of highly concentrated,few-layer graphene suspensions[J].Soft Matter,2015,11(16):3159-3164.
[26] Tran T S,Park S J,Yoo S S,et al.High shear-induced exfoliation of graphite into high quality graphene by Taylor-Couette flow[J].RSC Advances,2016,6(15):12003-12008.
[27] Wu H,Zhao W,Chen G.One-pot in situ ball milling preparation of polymer/graphene nanocomposites[J].Journal of Applied Polymer Science,2012,125(5):3899-3903.
[28] Damm C,Nacken T J,Peukert W.Quantitative evaluation of delamination of graphite by wet media milling[J].Carbon,2015,81:284-294.
[29] Mao M,Chen S,He P,et al.Facile and economical mass production of graphene dispersions and flakes[J].Journal of Materials Chemistry A,2014,2(12):4132-4135.
[30] Varrla E,Paton K R,Backes C,et al.Turbulence-assisted shear exfoliation of graphene using household detergent and a kitchen blender[J].Nanoscale,2014,6(20):11810-11819.
[31] Liu C,Hu G.Effect of nitric acid treatment on the preparation of graphene sheets by supercritical N,N-dimethylformamide exfoliation[J].Industrial & Engineering Chemistry Research,2014,53(37):14310-14314.
[32] Li L,Xu J,Li G,et al.Preparation of graphene nanosheets by shear-assisted supercritical CO2 exfoliation[J].Chemical Engineering Journal,2016,284:78-84.
[33] Hadi A,Karimi-Sabet J,Moosavian S M A,et al.Optimization of graphene production by exfoliation of graphite in supercritical ethanol:a response surface methodology approach[J].The Journal of Supercritical Fluids,2016,107:92-105.
[34] Liu X,Zheng M,Xiao K,et al.Simple,green and high-yield production of single- or few-layer graphene by hydrothermal exfoliation of graphite[J].Nanoscale,2014,6(9):4598-4603.
[35] Al-Hazmi F S,Al-Harbi G H,Beall G W,et al.Synthesis and structure of high quality graphene prepared via solvothermal exfoliation of intercalated graphite flakes[J].Superlattices and Microstructures,2015,86:270-274.
[36] Qian M,Zhou Y S,Gao Y,et al.Production of few-layer graphene through liquid-phase pulsed laser exfoliation of highly ordered pyrolytic graphite[J].Applied Surface Science,2012,258(22):9092-9095.
[37] Liang S,Shen Z,Yi M,et al.Effects of processing parameters on massive production of graphene by jet cavitation[J].Journal of Nanoscience and Nanotechnology,2015,15(4):2686-2694.
[38] Hummers W S,Offeman R E.Preparation of graphitic oxide[J].Journal ofthe American Chemical Society,1958,80(6):1339.
[39] Marcano D C,Kosynkin D V,BerlinJ M,et al.Improved synthesis of graphene oxide[J].ACS Nano,2010,4(8):4806-4814.
[40] Peng L,Xu Z,Liu Z,et al.An iron-based green approach to 1-h productionofsingle-layer graphene oxide[J].Nature Communications,2015(6):5716-5724.
[41] Vallés C,NúnezJ D,Benito A M,et al.Flexible conductive graphene paper obtained by direct and gentle annealing of graphene oxide paper[J].Carbon,2012,50:835-844.
[42] Pham V H,Hur S H,Kim E J,et al.Highly efficient reduction of graphene oxide using ammonia borane[J].Chemical Communications,2013,49:6665-6667.
[43] Yang S,Bruller S,Wu Z S,et al.Organic radical-assisted electrochemical exfoliation for the scalable production of high-quality graphene[J].Journal of the American Chemical Society,2015,137(43):13927-13932.
[44] Shinde D B,Brenker J,Easton C D,et al.Shear assisted electrochemical exfoliation of graphite to graphene[J].Langmuir,2016,32(14):3552-3559.
[45] Wang J,Manga K K,Bao Q,et al.High-yield synthesis of few-layer graphene flakes through electrochemical expansion of graphite in propylene carbonate electrolyte[J].Journal of the American Chemical Society,2011,133(23):8888-8891.
[46] Janowska I,Chizari K,Ersen O,et al.Microwave synthesis of large few-layer graphene sheets in aqueous solution of ammonia[J].Nano Research,2010,3(2):126-137.
[47] Wu L,Li W,Li P,et al.Powder,paper and foam of few-layer graphene prepared in high yield by electrochemical intercalation exfoliation of expanded graphite[J].Small,2014,10(7):1421-1429.
[48] Shih C J,Vijayaraghavan A,Krishnan R,et al.Bi- and trilayer graphene solutions[J].Nature Nanotechnology,2011,6(7):439-445.
[49] Lou H,Zhu D,Yuan L,et al.Fabrication of high-concentration aqueous graphene suspensions dispersed by sodium lignosulfonate and its mechanism[J].The Journal of Physical Chemistry C,2015,119(40):23221-23230.
[50] Matsumoto M,Saito Y,Park C,et al.Ultrahigh-throughput exfoliation of graphite into pristine “single-layer” graphene using microwaves and molecularly engineered ionic liquids[J].Nature Chemistry,2015,7(9):730-736.
[51] Eigler S.Graphite sulphate-a precursor to graphene[J].Chemical Communications,2015,51(15):3162-3165.
[52] Dimiev A M,Ceriotti G,Metzger A,et al.Chemical mass production of graphene nanoplatelets in approximately 100% yield[J].ACS Nano,2016,10(1):274-279.
[53] La D D,Bhargava S,Bhosale S V.Improved and a simple approach for mass production of graphene nanoplatelets material[J].Chemistry Select,2016,1(5):949-952.
[54] Geng X,Guo Y,Li D,et al.Interlayer catalytic exfoliation realizing scalable production of large-size pristine few-layer graphene[J].Scientific Reports,2013(3):1134-1139.
[55] Lin S,Dong L,Zhang J,et al.Room-temperature intercalation and #1000-fold chemical expansion for scalable preparation of high quality graphene[J].Chemistry of Materials,2016,28(7):2138-2146.
基金资助
国家重点研发计划(2016YFA0203301)