化工新型材料

化工新型材料 ›› 2018, Vol. 46 ›› Issue (6) : 246-249.

开发与应用

Ni₂P催化剂的制备、反应机理及应用研究进展

作者信息 +

Preparation,mechanism and application of Ni₂P catalyst

Ding Wei, Zhao Yunpeng, Zhao Dezhi, Dai Yongchuan, Yang Zhanxui

Author information +

文章历史 +

Received		Published
2017-02-15		2018-07-03
Issue Date	Revised Date
2018-07-03	2017-02-15

PDF (1212K)

摘要

Ni₂P催化剂为继氮化物和碳化物之后又一新型催化材料,凭借其良好的催化性能和较高的稳定性已被广泛用于多种催化领域。综述了Ni₂P催化剂的发展历程、制备方法,对催化加氢脱氮、脱硫、脱氯和光解水方面的反应机理及应用进行了概述,并对其未来发展趋势进行展望。

Abstract

Ni₂P catalyst is a novel catalytic material with excellent catalytic performance and high stability,and widely used in many fields which follow nitride and carbide.The development of Ni₂P including the preparation method of catalyst,the reaction mechanism of catalytic hydrogenation desulfurization,denitrification,dechlorination and photolysis of water were introduced.Their application were summarized.It was envision that N₂P catalyst would further boost the relevant catalytic application.

关键词

Ni₂P催化剂 / 机理 / 加氢反应 / 光解水

Key words

Ni₂P catalyst / mechanism / hydrogenation reaction / photochemical water splitting

引用本文

引用格式 ▾

Ni₂P催化剂的制备、反应机理及应用研究进展[J]. 化工新型材料, 2018, 46(6): 246-249 DOI:

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] 金耀琴,严盛宏.仿丙烯腈生产过程研究ZC-01阻聚剂的阻聚效果[J].石化技术与应用,2004,22(1):35-37.
[2] Sano Y,Choi K H,Korai Y,et al.Effects of nitrogen and refractory sulfur species removal on the deep HDS of gas oil[J].Applied Catalysis B Enviromental,2004,53(3):169-174.
[3] Sun F,Wu W,Wu Z,et al.Debenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP,Ni₂P,and Ni-Mo-P catalysts[J].Journal of Catalysis,2004,228(2):198-310.
[4] Niquille-Rothlisberger A,Prins R.Hydrodesulfurzation of 4,6-dimethyldibenzothiophene and dibenzonthiophene over alumina-supported Pt,Pd and Pt-Pd catalysts[J].Journal of Catalysis,2006,242(1):207-216.
[5] Shu Y,Oyama S T.Synthesis,characterization,and hydrotreating activity of carbon-supported transition metal phosphides[J].Carbon,2005,43(7):1517-1532.
[6] 宋华,张永江,宋华林,等.柠檬酸对Ni₂P/TiO₂-Al₂O₃催化剂加氢脱硫性能的影响[J].物理化学学报,2012,28(3):661-666.
[7] 宋华,郭云涛,李锋,等.Ni₂P/TiO₂-Al₂O₃催化剂的制备及其加氢脱硫、脱氮性能[J].物理化学学报,2010,26(9):2461-2467.
[8] Robinson R D,Moreau L M,Ha D H,et al.Defining crystalline/amorphous phases of nanoparticles through X-ray absorption spectroscopy and X-ray diffraction:the case of nickel phosphide[J].Chemistry of Materials,2013,25(12):2394-2403.
[9] Infantes-Molinaa A,Ceciliab J A,Paweleca B,et al.Ni₂P and CoP catalysts prepared from phosphite-type precursors for HDS-HDN competitive reactions[J].Applied Catalysis A General,2010,390(1-2):253-263.
[10] Sun Z J,Zheng H F,Li J S,et al.Extraordinarily efficient photocatalytic hydrogen evolution in water using semiconductor nanorods integrated with crystalline Ni₂P co-catalysts[J].Energy Environ Sci,2015,8(9):2668-2676.
[11] 宋华,王健,李锋,等.Ni₂P加氢脱硫催化剂制备方法及改性研究进展[J].石油学报(石油加工),2013,29(6):1906-1108.
[12] Han Z,Eisenberg R.Fuel from water:the photochemical generation of hydrogen from water[J].Accounts of Chemical Research,2014,47(8):2537-2544.
[13] Song L,Zhang S,Wei Q.A new route for synthesizing nickel phosphide catalysts with high hydrodesulfurization activity based on soudium dihydrogenphosphite[J].Catalysis Communications,2011,12(12):1157-1160.
[14] Guan Jie,Wang Yao,Qin Minglei,et al.Synthesis of transition-metal phosphides from oxidic precursors by reduction in hydrogen plasma[J].Jourmal of Solid State Chemistry,2009,182(6):1550-1555.
[15] Song H,Wang J,Wang Z,et al.Effect of titanium content on dibenzothiophene HDS performance over Ni₂P/Ti-MCM-41 catalyst[J].Journal of Catalysis,2014,311(1):257-265.
[16] 于祺,宋华,宋华林,等.还原温度对低温还原法制备的Ni2P/Ti-MCM-41催化剂加氢脱硫性能的影响[J].燃料化学学报,2016,44(8):970-976.
[17] 孙志超,王安杰,李翔,等.免焙烧制备Ni₂P/SiO₂加氢脱硫催化剂[J].石油学报(石油加工),2013,29(5):767-772.
[18] Zhang G J,Tang C,Yang X D,et al.Research progress in preparation and HDS performance of Ni₂P catalyst[J].Contemporary Chemica Industry,2011,40(7):731-733.
[19] Liu Z,Huang X,Zhu Z,et al.A simple mild hydrothermal route for the synthesis of nickel phosphide powders[J].Cheramics International,2010,36(3):1155-1158.
[20] Wang X,Wan F,Gao Y,et al.Synthesis of high-quality Ni₂P hollow sphere via a template-free surfactant-assisted solvothermal route[J].Journal of Crystal Growth,2008,310(10):2569-2574.
[21] 王钰佳,王双甲,刘添智,等.本体磷化镍的水热合成研究[J].应用化工,2016,45(8):1450-1452.
[22] Ding L,Zheng M,Wang A,et al.A novel route to the preparation of carbon supported nickel phosphide catalysts by a microwave heating process[J].Catalysis Letters,2010,135(3-4):305-311.
[23] Guan Q X,Li W.A novel synthetic approach to synthesizing bulk and supported metal phosphides[J].Journal of Catalysis,2010,271:413-415.
[24] Guan Q,Han F,Li W.Catalytic performance and deoxygenation path of methyl palmitate on Ni₂P/SiO₂ synthesized using the thermal decomposition of nickel hypophosphite[J].Rsc Advances,2016,6(37):31308-31315.
[25] 鄢景森,王海彦,李素魁,等.载体对Ni₂P催化剂加氢脱氮反应性能的影响[J].燃料化学学报,2014,42(3):362-369.
[26] Shu Y,Qyama S T.Synthesis,characterization,and hydrotreating activity of carbon-supported transition metal phosphides[J].Carbon,2005,43(7):1517-1532.
[27] Kornyi T I,Vít Z,Poduval Dilip G,et al.SBA-15-supported nickel phosphide hydrotreating catalysts[J].Journal of Catalysis,2008,253(1):119-131.
[28] Bando K K,Wada T,Miyamoto T,et al.Combined in situ analysis of Ni₂P/MCM-41 under hydrodesulfurization conditions-simultaneous observation of QXAFS and FT-IR,14th International Conference on X-Ray absorption fine structure (XAFS14)[J].J Catal,2012,286(4):165-171.
[29] Wei R,Zhu Q,Han F,et al.Comparison of four different synthetic routes of Ni₂P/TiO₂-Al₂O₃ catalysts for hydrodesulfurization of dibenzothiophene[J].Rsc Advances,2015,5(48):38774-38782.
[30] 吴平易,王景艳,兰玲,等.La-Ni₂P/SBA-15/董青石整体式催化剂及加氢脱硫性能[J].工业催化,2014,22(4):272-276.
[31] 轩丽伟,王焕,张吉庆,等.大孔Ni₂P/γ-Al₂O₃催化剂的制备及加氢脱硫性能研究[J].辽宁石油化工大学学报,2012,32(3):25-28.
[32] 宋华,张福勇,徐晓伟,等.镨和铈对低温还原法制备的Ni2P催化剂加氢脱硫活性的影响[J].燃料化学学报,2015,43(9):1128-1133.
[33] Liu X,Chen J,Zhang J.Hydrodechlorination of chlorobenzene over silica-supported nickel phosphide catalysts[J].Industrial & Engineering Chemistry Research,2008,47(15):5362-5368.
[34] Wei R,Zhu Q,Han F,et al.Comparison of four different synthetic routes of Ni₂P/TiO₂-Al₂O₃ catalysts for hydrodesulfurization of dibenzothiophene[J].Rsc Advances,2015,5:38774-38782.
[35] 郭提,陈吉祥,李克伦.水蒸汽处理对Ni₂P/SiO₂催化剂催化氯苯加氢脱氯反应的促进作用[J].催化学报,2012,33(7):1080-1085.
[36] Chen J,Guo T,Li K,et al.A facile approach to enhancing activity of Ni₂P/SiO₂ catalyst for hydrodechlorination of chlorobenzene:promoting effect of water and oxygen[J].Catalysis Science & Technology,2015,5(5):2670-2680.
[37] Stem L A,Feng L,Song F,et al.Ni₂P as a Janus catalyst for water splitting:the oxygen evolution activity of Ni₂P nanoparticles[J].Energy Environ Sci,2015,8:2347-2351.