疏水性棉短绒纤维素/SiO2复合气凝胶的制备及性能研究

郑真, 丁成立*, 李惠萍*, 付静静

化工新型材料 ›› 2018, Vol. 46 ›› Issue (4) : 230 -233.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (4) : 230-233.
开发与应用

疏水性棉短绒纤维素/SiO2复合气凝胶的制备及性能研究

    郑真, 丁成立*, 李惠萍*, 付静静
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Synthesis and property of hydrophobic functionalized cotton linter cellulose/SiO2 composite aerogel

  • Zheng Zhen, Ding Chengli, Li Huiping, Fu Jingjing
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摘要

以棉短绒纤维素为原料,以NaOH/尿素/H2O为绿色溶剂体系,采用溶胶-凝胶法制备纤维素水凝胶,以硅酸钠(Na2SiO3)为硅源,代替传统正硅酸乙酯(TEOS)作为溶剂,通过浸泡法制备了4种纤维素/SiO2复合气凝胶,再利用十六烷基三甲氧基硅烷(HDTMS)对纤维素/SiO2复合气凝胶进行疏水改性,采用傅里叶变换红外光谱(FT-IR)和扫描电子显微镜(SEM)等手段对产物进行表征。结果表明:疏水改性后复合气凝胶三维网状结构的孔隙变小,随着Na2SiO3用量的增加,疏水纤维素/SiO2复合气凝胶的接触角逐渐增大,达到147°,吸油量可达到自身质量的8倍,具有较好的疏水亲油性能。

Abstract

Cellulose hydrogel was obtained by sol-gel transition of cotton linter in a green cost-effective NaOH/urea aqueous solution.The silica source used here was Na2SiO3 instead of traditional tetraethoxysilane (TEOS) by immersing method to prepared four kinds of cellulose/SiO2 composite aerogels and hydrophobically modified with hexadecyl trimethoxy silane (HDTMS).All samples were characterized by Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM).Analysis results showed that the structure of cellulose/SiO2 composite aerogels and the modified products were all three-dimensional network,the pore became smaller after modification,four kinds of hydrophobic cellulose/SiO2 composite aerogels were gradually improved with the increase of the dose of Na2SiO3,and the biggest contact angle was 147°.The oil absorption reached 8 times of their own quality,which with good ability to adsorb oil.

关键词

NaOH/尿素/H2O / Na2SiO3 / 溶胶-凝胶法 / 气凝胶 / 疏水改性

Key words

NaOH/urea/H2O / Na2SiO3 / sol-gel method / aerogel / hydrophobic modification

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疏水性棉短绒纤维素/SiO2复合气凝胶的制备及性能研究[J]. 化工新型材料, 2018, 46(4): 230-233 DOI:

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基金资助

国家自然科学基金(21666035);新疆高层人才研究基金(XJEDU:20161019);新疆维吾尔自治区高校科研项目(BS150224)

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