聚乳酸在纺织、包装、电子电器、汽车、航空等领域的应用日益广泛,但其本身的热稳定性差,对其进行阻燃改性已迫在眉睫。按照反应型阻燃单体的不同,综述了目前对聚乳酸本质阻燃改性的几种主要方法,展望了其未来的发展方向。
Poly (lactic acid)(PLA) are widely used in textile,packaging,electronic appliance,automobile and aviation.However,due to the poor thermal stability of PLA,the flame retardance modification of PLA is becoming an imminent task.Classifying as different reactive monomer,the recent progress in reactive modification for PLA flame retardance were reviewed and their development direction was prospected.
[1] 常少坤,任杰.聚乳酸的阻燃改性研究进展[J].塑料,2010,39(4):85-88.
[2] 周旋,武永刚,李娟,等.聚乳酸阻燃改性研究进展[J].工程塑料应用,2012,40(8):98-103.
[3] 林海娟,方建勇,董丽松.聚乳酸阻燃性能的研究进展[J].高分子通报,2012(3):45-52.
[4] 杨舒宇,李建峰,徐鼐,等.聚乳酸的阻燃改性研究进展[J].化工新型材料,2014,42(8):31-33.
[5] 李志,韦平,任文坛,等.新型聚乳酸阻燃体系研究进展[J].中国塑料,2014,28(6):2-7.
[6] 周露,王新龙.聚乳酸的无卤阻燃研究进展[J].现代塑料加工应用,2014,26(6):60-63.
[7] 张胜,陈宸,谷晓昱,等.聚乳酸的无卤阻燃研究进展[J].塑料,2015,44(4):6-17.
[8] 陈雅君,毛小军,王超,等.聚乳酸的阻燃改性研究进展[J].中国塑料,2015,44(4):6-17.
[9] 何小丽.聚乳酸的增韧阻燃改性研究进展[J].广东化工,2016,43(4):54-56.
[10] 王玉忠.生物基高分子材料的本质阻燃研究[C].天津:全国高分子学术论文报告会,2009.
[11] 杨保平,陈碧碧,郭军红,等.新型本质阻燃高分子材料研究进展[J].化工新型材料,2016,42(8):26-28.
[12] 车晶,杨荣杰,李定华.阻燃聚乳酸树脂研究进展[J].高分子材料科学与工程,2016,42(8):26-28.
[13] 谢吉星.熔融缩聚扩链法制备高分子量聚乳酸[D].北京:北京理工大学,2007.
[14] 谢吉星,杨荣杰.亚磷酸三苯酯扩链制备高分子量聚乳酸[J].高分子材料科学与工程,2008,24(1):20-23.
[15] 邓晶晶,黄宇,羊森林,等.有机磷系化合物反应阻燃聚乳酸的机理与性能[J].工程塑料应用,2009,37(11):54-57.
[16] Yuan X Y,Wang D Y,Chen L,et al.Inherent flame retardation of bio-based poly(lactic acid) by incorporating phosphorus linked pendent group into the backbone[J].Polym Degrad Stab,2011,96(9):1669-1675.
[17] Mauldin T C,Zammarano M,Gilman J W,et al.Synthesis and characterization of isosorbide-based polyphosphonates as biobased flame-retardants[J].Polym Chem,2014,5(17):5139-5146.
[18] Liao F H,Ju Y Q,Dai X,et al.A novel efficient polymeric flame retardant for poly(lactic acid)(PLA):synthesis and its effects on flame retardancy and crystallization of PLA[J].Polym Degrad Stab,2015,120:1669-1675.
[19] Wang D Y,Song Y P,Lin L,et al.A novel phosphorus-containing poly(lactic acid) toward its flame retardation[J].Polymer,2011,52(2):233-238.
[20] 王德义,宋艳明,汪秀丽,等.含磷无卤阻燃型聚乳酸及其制备方法和由其共混的阻燃材料.ZL:200810147907.5[P].2011-08-31.
[21] 汪朝阳,赵耀明.聚磷酸酯阻燃剂研究进展[J].塑料,2003,32(3):1-8.
[22] 李雄武,汪朝阳,侯晓娜,等.可降解磷酸酯聚合物的合成与应用研究进展[J].化学研究,2006,17(1):97-100.
[23] Wei L L,Wang D Y,Chen H B,et al.Effect of a phosphorus-containing flame retardant on the thermal properties and ease of ignition of poly(lactic acid)[J].Polym Degrad Stab,2011,96(9):1557-1561.
[24] Jing J,Zhang Y,Tang X L,et al.Synthesis of a highly efficient phosphorus-containing flame retardant utilizing plant-derived diphenolic acids and its application in poly lactic[J].RSC Adv,2016,6(54):49019-49027.
[25] Wang Z Y,Li X W,Li J N,et al.Synthesis of poly(lactic acid)-poly(phenyl phosphate) via direct polycondensation and its characterization[J].J Polym Res,2009,16(3):255-261.
[26] 王卓渊.1,4-双(2-苯并咪唑基)苯的合成和荧光性质改进[J].化工技术与开发,2009,38(6):1-3.
[27] 王会娅.新型单组分磷氮膨胀阻燃剂的合成[J].化学研究,2010,21(1):32-35.
[28] 盛丽,徐宏杰,房建华,等.可溶性共聚型聚苯并咪唑的合成及性能[J].高等学校化学学报,2010,31(7):1461-1464.
[29] 毛郑州,李建晓,薛福玲,等.阻燃剂苯并咪唑的微波合成研究进展[J].化学研究与应用,2012,24(4):497-502.
[30] 汪朝阳,熊金峰.一种相容性聚乳酸阻燃剂的制备方法.ZL:201210207082.8[P].2014-02-05.
[31] Xiong J F,Luo S H,Wang Q F,et al.Synthesis and characterization of a novel flame retardant,poly(lactic acid-co-3,3′-diaminobenzidine)[J].Des Monomers Polym,2013,16(4):389-397.
[32] Xiong J F,Wang Q F,Peng P,et al.Design,synthesis and characterization of a potential flame retardant poly(lactic acid-co-pyrimidine-2,4,5,6-tetramine) via direct melt polycondensation[J].J Appl Polym Sci,2014,131(10):40275.
[33] Weil E D,Lewin M,Lin H S.Enhanced flame retardancy of polypropylene with magnesium hydroxide,melamine and novolac[J].J Fire Sci,1998,16(5):383-404.
[34] Li L Y,Chen G H,Liu W,et al.The anti-dripping intumescent flame retardant finishing for nylon-6,6 fabric[J].Polym Degrad Stab,2009,94(6):996-1000.
[35] Wang X,Song L,Yang H Y,et al.Synergistic effect of graphene on antidripping and fire resistance of intumescent flame retardant poly(butylene succinate) composites[J].Ind Eng Chem Res,2011,50(9):5376-5383.
[36] 关丽涛,熊金锋,汪朝阳,等.密胺改性聚乳酸工艺研究[J].塑料科技2013,41(8):70-73.
[37] Mo G Z,Xiong J F,Peng P,et al.Structural characterization of serial novel star-shaped biodegradable material poly(lactic acid-co-melamine)[J].Adv Mater Res,2013,781-784:491-494.
[38] Xiong J F,Huo J P,Peng P,et al.Performance characterization of a novel flame retardant material poly(lactic acid-co-melamine)[J].Adv Mater Res,2013,781-784:479-482.
[39] 莫广珍,吴彦城,王群芳,等.胺甲基苯并咪唑改性聚乳酸的合成与表征[C].苏州:全国高分子学术论文报告会,2015.
[40] Chen Y J,Mao X J,Qian L J,et al.Flammability and anti-dripping behaviors of polylactide composite containing hyperbranched triazine compound[J].Integr Ferroelectr,2016,172(1):10-24.
[41] Xi W,Qian L J,Qiu Y,et al.Flame-retardant behavior of bi-group molecule derived from phosphaphenanthrene and triazine groups on polylactic acid[J].Polym Adv Technol,2016,27(6):781-788.
[42] Zhao X M,Guerrero F R,Lorca J,et al.New superefficiently flame-retardant bioplastic poly(lactic acid):flammability,thermal decomposition behavior,and tensile properties[J].ACS Sustainable Chem Eng,2016,4(1):202-209.
[43] Jiang P,Gu X Y,Zhang S,et al.Synthesis,characterization,and utilization of a novel phosphorus/nitrogen-containing flame retardant[J].Ind Eng Chem Res,2015,54(11):2974-2982.
[44] Tao K,Li J,Xu L,et al.A novel phosphazene cyclomatrix network polymer:design,synthesis and application in flame retardant polylactide[J].Polym Degrad Stab,2011,96(7):1248-1254.
[45] Cao Y,Ju Y Q,Liao F H,et al.Improving the flame retardancy and mechanical properties of poly(lactic acid) with a novel nanorod-shaped hybrid flame retardant[J].RSC Adv,2016,6(18):14852-14858.
[46] Zhou L,Ju Y Q,Liao F H,et al.Improve the mechanical property and flame retardant efficiency of the composites of poly(lactic acid) and resorcinol di(phenyl phosphate)(RDP) with ZnO-coated kenaf[J].Fire Mater,2016,40(1):129-140.
[47] Wang B B,Sun X S,Klabunde K.Poly(lactic acid)/multi-hydroxyl magnesium oxide nanocomposites prepared by melt compounding[J].J Biobased Mater Bio,2009,3(2):130-138.
[48] Li Y H,Sun X S.Preparation and characterization of polymer-inorganic nanocomposites by in situ melt polycondensation of l-lactic acid and surface-hydroxylated MgO[J].Biomacromolecules,2010,11:1847-1855.
[49] 杨立新,胡秀丽,黄宇彬,等.阻燃型聚乳酸基聚氨酯的合成与表征[J].应用化学,2016,33(1):47-52.
[50] 廖逢辉,王通文,王新龙.含磷高分子阻燃剂的研究进展[J].塑料助剂,2015(2):6-10.
基金资助
国家自然科学基金(20772035);广东省自然科学基金(2014A030313429);广州市科技计划科学研究专项(201607010251)
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