TiO2/活性碳纤维膜光催化降解甲醛的研究

段雅楠, 张兴惠*, 李梦绮

化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 127 -130.

PDF (1733KB)
化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 127-130.
新材料与新技术

TiO2/活性碳纤维膜光催化降解甲醛的研究

    段雅楠, 张兴惠*, 李梦绮
作者信息 +

Experimental study on TiO2/ACF photocatalytic degradation of formaldehyde

  • Duan Yanan, Zhang Xinghui, Li Mengqi
Author information +
文章历史 +
PDF (1773K)

摘要

以磷酸铝(AlPO4)为粘结剂,活性碳纤维(ACF)为载体,二氧化钛(TiO2)为原料,采用添加粘结剂超声波辅助浸渍提拉法制备了固载型复合催化材料体二氧化钛/活性碳纤维膜(TiO2/ACF膜),并对其进行了表征。研究结果表明,加入AlPO4对TiO2/ACF膜降解甲醛有较好的促进效果,制得的TiO2/ACF膜通过高温再生后仍具有较好的降解活性,当甲醛的初始浓度为8.04mg/m3,环境相对湿度为65%,气体流速为1.5m/s时,经过循环使用5次的TiO2/ACF膜对甲醛气体的降解率达到82.1%。

Abstract

With aluminum phosphate (AlPO4) as binder,activated carbon fiber (ACF) as carrier,titanium dioxide (TiO2) as raw material,TiO2/ACF membrane was prepared used method was to add the binder,using ultrasonic instrument,using dipping pulling method,also carried on the experiment of SEM.Research results showed that adding AlPO4 had good promoting effect for ACF/TiO2 membrane degradation of formaldehyde.ACF/TiO2 membrane after high temperature regenerative still had good biodegradation activity.When the initial concentration of formaldehyde was 8.04mg/m3,environment relative humidity was 65%,gas flow velocity of 1.5m/s,the degradation rate of ACF/TiO2 film for formaldehyde gas after five cycle reached 82.1%.

关键词

粘结剂 / 光催化 / 甲醛 / 复合催化材料体

Key words

binder / photocatalysis / formaldehyde / composite catalytic material

引用本文

引用格式 ▾
TiO2/活性碳纤维膜光催化降解甲醛的研究[J]. 化工新型材料, 2018, 46(2): 127-130 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Fujisliima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38.
[2] Hager S,Bauer R,Kudielka G.Photocatalytic oxidation of gaseous chlorinated organics over titanium dioxide[J].Chemosphere,2000,41(8):1219-1225.
[3] Chen H,Nanayakkara C E,Grassian V H.Titanium dioxide photocatalysis in atmospheric chemistry[J].Chemical Reviews,2012,112(11):5919-5948.
[4] 杨全红,郑经堂,工茂章,等.用SEM和XRD研究改性活性炭纤维的结构[J].新型炭材料,1998,13(4):60-64.
[5] 余纯丽,任建敏,傅敏,等.活性炭纤维的改性及其微孔结构[J].环境科学学报,2008,28(4):714-719.
[6] 蔡健,胡将军,张雁.改性活性炭纤维对甲醛吸附性能的研究[J].环境科学与技术,2004,27(3):16-19.
[7] Yao Shuhua,Li Jinyang.Immobilization of TiO2 nanoparticles on activated carbon fiber and its photodegradation performance for organic pollutants[J].Particuology,2010,8(3):272-278.
[8] 刘建华,杨蓉,李松梅.TiO2/ACF光催化再生复合材料的研究进展[J].材料工程,2006(8):61-65.
[9] Shi J W,Cui H J,Chen J W,et al.TiO2/activated carbon fibers photocatalyst:Effects of coating procedures on the microstructure,adhesion property,and photocatalytic ability[J].Journal of Colloid and Interface Science,2012,388(1):201-208.
[10] 李波,李百战,李娟,等.ACF担载TiO2光催化降解甲醛的影响因素研究[J].中国科技论文,2008,3(5):347-350.
[11] 员汝胜,郑经堂,关蓉波,等.TiO2在微孔型活性炭纤维上的固载及其对苯酚的光催化降解[J].新型碳材料,2005,20(1):45-50.
[12] 何冰,黄健翔.磷酸铝添加量对纳米TiO2光催化活性的影响[J].广东化工,2014,41(15):84-85.
[13] 杨慧全.基于亚克力材料的产品设计研究[J].机械设计,2014,31(2):27-28.
[14] Piera E,Ayllon J A,Domenech X,et al.TiO2 deactivation during gas-phase photocatalytic oxidation of ethanol[J].Catalysis Today,2002,76(2):259-270.
[15] Fujishima A.TiO2 photocatalysis and related surface phenomena[J].Surface Science Reports,2008,63(12):515-582.
[16] 刘守新,陈广胜,孙承林.活性炭的光催化再生机理[J].环境化学,2005,24(4):405-408.
[17] 孙智博,尹贻东,范乃英,等.TiO2负载硅胶催化剂的制备和光催化活性[J].材料研究学报,2014,28(8):633-640.

基金资助

山西省科技攻关项目(20140313007-3)

AI Summary AI Mindmap
PDF (1733KB)

639

访问

0

被引

导航
相关文章

AI思维导图

/