磁性氧化石墨烯的制备及其对Cu2+的吸附性能

赵云, 马江权*, 张传栋, 李正萍, 黄小婷, 罗鹏阳

化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 99 -102.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 99-102.
新材料与新技术

磁性氧化石墨烯的制备及其对Cu2+的吸附性能

    赵云, 马江权*, 张传栋, 李正萍, 黄小婷, 罗鹏阳
作者信息 +

Preparation of magnetic GO and its adsorption performance on Cu2+

  • Zhao Yun, Ma Jiangquan, Zhang Chuandong, Li Zhengping, Huang Xiaoting, Luo Pengyang
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摘要

制备了一种磁性氧化石墨烯(GO-Fe3O4),并对其吸附铜离子(Cu2+)的性能进行了研究。研究了不同pH和初始浓度对GO-Fe3O4去除Cu2+的影响。研究结果表明:改性四氧化三铁(Fe3O4@SiO2)成功被接枝在GO的边缘,GO与Fe3O4@SiO2质量配合比为4∶1,制得的GO-Fe3O4,在303℃,pH为4.5,Cu2+初始质量浓度为124.5mg/L条件下,GO-Fe3O4对Cu2+的平衡吸附容量达到76.5mg/g。GO-Fe3O4在使用第7次时,对Cu2+吸附容量仍可达到55mg/g,具有良好的吸附性能。

Abstract

A magnetic GO (GO-Fe3O4) was synthesized,and studied its adsorption performance on Cu2+.Studying the adsorption capability of Cu2+ on GO-Fe3O4 under different pH values and initial Cu2+ concentrations.The results showed that,Fe3O4@SiO2 was successfully grafted on the edge of GO.The equilibrium adsorption capacity of Cu2+ on GO-Fe3O4 produced by the mass ratio of GO to Fe3O4@SiO2 4∶1 was 76.5mg/g while the reaction temperature was 303℃,the pH value was 4.5 and the initial mass concentration of Cu2+ was 124.5mg/L.After seven time cycle the adsorption capacity of Cu2+ on GO-Fe3O4 can still reach 55mg/g,which displayed excellent absorption capacity.

关键词

氧化石墨烯 / 磁性吸附剂 / 铜离子

Key words

GO / magnetic adsorbent / Cu2+

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磁性氧化石墨烯的制备及其对Cu2+的吸附性能[J]. 化工新型材料, 2018, 46(2): 99-102 DOI:

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基金资助

镇江市工业支撑项目(GY2014037)

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