石墨烯基吸附材料研究进展

郑茹, 王帅*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 26 -30.

PDF (1138KB)
化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 26-30.
综述与专论

石墨烯基吸附材料研究进展

    郑茹, 王帅*
作者信息 +

Research development on graphene adsorbent material

  • Zheng Ru, Wang Shuai
Author information +
文章历史 +
PDF (1164K)

摘要

石墨烯是一种由碳原子构成的单层二维纳米材料,具有超高理论比表面积和极强的表面化学活性,被认为是一类具有很好发展潜力的吸附分离材料。综述了石墨烯、氧化石墨烯及其复合材料的制备方法,以及在去除水中重金属离子和有机污染物方面的应用,并对今后石墨烯基吸附材料的研究方向进行了展望。

Abstract

Graphene,emerging as a two-dimensional single-layer carbon material,had been considered to be a promising class of adsorptive separation material for its high specific surface area and strong surface chemical activity.The preparation method of graphene,graphene oxide and composites,and its application in removal of heavy metal ions and organic pollutants were mainly summarized.Finally the future research direction of graphene and its composites was prospected.

关键词

石墨烯 / 氧化石墨烯 / 吸附材料 / 进展

Key words

graphene / graphene oxide / adsorption material / progress

引用本文

引用格式 ▾
石墨烯基吸附材料研究进展[J]. 化工新型材料, 2018, 46(2): 26-30 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Emik S.Preparation and characterization of an IPN type chelating resin containing amino and carboxyl groups for removal of Cu(Ⅱ) from aqueous solutions[J].Reactive and Functional Polymers,2014,75(1):63-74.
[2] Shaaban A F,Fadel D A,Mahmoud A A,et al.Synthesis of a new chelating resin bearing amidoxime group for adsorption of Cu(Ⅱ),Ni(Ⅱ) and Pb(Ⅱ) by batch and fixed-bed column methods[J].Journal of Environmental Chemical Engineering,2014,2(1):632-641.
[3] Deng J H,Zhang X R,Zeng G M,et al.Simultaneous removal of Cd(Ⅱ) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent[J].Chemical Engineering Journal,2013,226(8):189-200.
[4] Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[5] Loh K P,Bao Q,Ang P K,et al.The chemistry of graphene[J].Journal of Materials Chemistry,2010,20(12):2277-2289.
[6] Zhu Y,Murali S,Cai W,et al.Graphene and graphene oxide:synthesis,properties,and applications[J].Advanced Materials,2010,22(35):3906-3924.
[7] Dreyer D R,Park S,Bielawski C W,et al.The chemistry of graphene oxide[J].Chemical Society Reviews,2010,39(1):228-240.
[8] Kovtyukhova N I,Ollivier P J,Martin B R,et al.Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations[J].Chemistry of Materials,1999,11(3):771-778.
[9] Marcano D C,Kosynkin D V,Berlin J M,et al.Improved synthesis of graphene oxide[J].ACS Nano,2010,4(8):4806-4814.
[10] Najafi F,Moradi O,Rajabi M,et al.Thermodynamics of the adsorption of nickel ions from aqueous phase using graphene oxide and glycine functionalized graphene oxide[J].Journal of Molecular Liquids,2015,208:106-113.
[11] Yao T,Xiao Y,Wu X,et al.Adsorption of Eu(Ⅲ) on sulfonated graphene oxide:Combined macroscopic and modeling techniques[J].Journal of Molecular Liquids,2016,215:443-448.
[12] Wu Y,Luo H,Wang H,et al.Adsorption of hexavalent chromium from aqueous solutions by graphene modified with cetyltrimethylammonium bromide[J].Journal of Colloid and Interface Science,2013,394(1):183-191.
[13] Chandra V,Park J,Chun Y,et al.Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal[J].ACS Nano,2010,4(7):3979-3986.
[14] Zhao G,Song S,Wang C,et al.Determination of triazine herbicides in environmental water samples by high-performance liquid chromatography using graphene-coated magnetic nanoparticles as adsorbent[J].Analytica Chimica Acta,2011,708(1/2):155-159.
[15] Wang X,Yu J.Application of Fe3O4/graphene oxide composite for the separation of Cs(Ⅰ) and Sr(Ⅱ) from aqueous solution[J].Journal of Radioanalytical and Nuclear Chemistry,2015,303(1):807-813.
[16] Liu X,Zhang H,Ma Y,et al.Graphene-coated silica as a highly efficient sorbent for residual organophosphorus pesticides in water[J].Journal of Materials Chemistry A,2013,1(5):1875-1884.
[17] Pan N,Li L,Ding J,et al.Preparation of graphene oxide-manganese dioxide for highly efficient adsorption and separation of Th(Ⅳ)/U(Ⅵ)[J].Journal of Hazardous Materials,2016,309:107-115.
[18] Li X,Wang Z,Li Q,et al.Preparation,characterization,and application of mesoporous silica-grafted graphene oxide for highly selective lead adsorption[J].Chemical Engineering Journal,2015,273:630-637.
[19] Ge H,Ma Z.Microwave preparation of triethylenetetramine modified graphene oxide/chitosan composite for adsorption of Cr(Ⅵ)[J].Carbohydrate polymers,2015,131:280-287.
[20] Yan H,Yang H,Li A,et al.pH-tunable surface charge of chitosan/graphene oxide composite adsorbent for efficient removal of multiple pollutants from water[J].Chemical Engineering Journal,2016,284:1397-1405.
[21] Wang D,Liu L,Jiang X,et al.Adsorbent for p-phenylenediamine adsorption and removal based on graphene oxide functionalized with magnetic cyclodextrin[J].Applied Surface Science,2015,329(1):197-205.
[22] Hu X,Liu Y,Wang H,et al.Adsorption of copper by magnetic graphene oxide-supported β-cyclodextrin:Effects of pH,ionic strength,background electrolytes,and citric acid[J].Chemical Engineering Research and Design,2015,93:675-683.
[23] Li S,Lu X,Xue Y,et al.Fabrication of polypyrrole/graphene oxide composite nanosheets and their applications for Cr(Ⅵ) removal in aqueous solution[J].PLoS One,2012,7(8):43328.
[24] Zhang S,Shao Y,Liu J,et al.Graphene-polypyrrole nanocomposite as a highly efficient and low cost electrically switched ion exchanger for removing ClO4- from wastewater[J].ACS Applied Materials & Interfaces,2011,3(9):3633-3637.
[25] Qi H,Liu H,Gao Y.Removal of Sr(Ⅱ) from aqueous solutions using polyacrylamide modified graphene oxide composites[J].Journal of Molecular Liquids,2015,208:394-401.
[26] Dong S,Dou X,Mohan D,et al.Synthesis of graphene oxide/schwertmannite nanocomposites and their application in Sb(Ⅴ) adsorption from water[J].Chemical Engineering Journal,2015,270:205-214.
[27] Chen W,Yan L.In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures[J].Nanoscale,2011,3(8):3132-3137.
[28] Hu H,Zhao Z,Wan W,et al.Ultralight and highly compressible graphene aerogels[J].Advanced Materials,2013,25(15):2219-2223.
[29] Ma Y,Chen Y.Three-dimensional graphene networks:synthesis,properties and applications[J].National Science Review,2015,2(1):40-53.
[30] Jayanthi S,Eswar N K R,Singh S A,et al.Macroporous three-dimensional graphene oxide foams for dye adsorption and antibacterial applications[J].RSC Advances,2016,6(2):1231-1242.
[31] Lei Y,Chen F,Luo Y,et al.Synthesis of three-dimensional graphene oxide foam for the removal of heavy metal ions[J].Chemical Physics Letters,2014,593(6):122-127.
[32] Bi H,Xie X,Yin K,et al.Spongy graphene as a highly efficient and recyclable sorbent for oils and organic solvents[J].Advanced Functional Materials,2012,22(21):4421-4425.
[33] Zhao L,Yu B,Xue F,et al.Facile hydrothermal preparation of recyclable S-doped graphene sponge for Cu 2+ adsorption[J].Journal of Hazardous Materials,2015,286:449-456.
[34] Zhou G,Liu C,Tang Y,et al.Sponge-like polysiloxane-graphene oxide gel as a highly efficient and renewable adsorbent for lead and cadmium metals removal from wastewater[J].Chemical Engineering Journal,2015,280:275-282.
[35] Xu R,Zhou G,Tang Y,et al.New double network hydrogel adsorbent:Highly efficient removal of Cd(Ⅱ) and Mn(Ⅱ) ions in aqueous solution[J].Chemical Engineering Journal,2015,275:179-188.

基金资助

国家自然科学基金(21206199)

AI Summary AI Mindmap
PDF (1138KB)

1636

访问

0

被引

导航
相关文章

AI思维导图

/