Carbon-based materials have particularly received increasing attention owing to their low cost,structural diversity and relatively inert electrochemistry.It was preferred basement materials to building three-dimensional self-supporting electrode.MnO2 with high theoretical specific capacity,low cost,abundant natural resources and friend environment,has been paid great attention as the supercapacitor electrode materials.The research progress of MnO2-AC,CNT,CF and GR as composites electrode in the supercapacitor were introduced.The development trend of composites electrode was also prospected.
[1] Burke A.Ultracapacitors:why,how,and where is the technology[J].Journal of Power Sources,2000,91(1):37-50.
[2] And M W,Brodd R J.What are batteries,fuel cells,and supercapacitors?[J].Chemical Reviews,2004,104(10):4245-4270.
[3] Zhang L L,Zhao X S.Carbon-based materials as supercapacitor electrodes[J].Chemical Society Reviews,2009,38(9):2520-2531.
[4] Wang G,Zhang L,Zhang J.A review of electrode materials for electrochemical supercapacitors[J].Chemical Society Reviews,2012,41(1):797-828.
[5] Wang F,Xiao S,Hou Y,et al.Electrode materials for aqueous asymmetric supercapacitors[J].RSC Advances,2013,3(3):13059-13084.
[6] Ji H,Zhao X,Qiao Z,et al.Capacitance of carbon-based electrical double-layer capacitors[J].Nature Communications,2014,5(2):3317-3323.
[7] Zhang L L,Gu Y,Zhao X S.Advanced porous carbon electrodes for electrochemical capacitors[J].Journal of Materials Chemistry A,2013(33):9395-9408.
[8] Béguin F,Presser V,Balducci A,et al.Carbons and electrolytes for advanced supercapacitors[J].Advanced Materials,2014,26(14):2219-2252.
[9] Zhi M,Xiang C,Li J,et al.Nanostructured carbon-metal oxide composite electrodes for supercapacitors:a review[J].Nanoscale,2013,5(1):72-88.
[10] Snook G A,Kao P,Best A S.Conducting-polymer-based supercapacitor devices and electrodes[J].Journal of Power Sources,2011,196(1):1-12.
[11] Xu C,Kang F,Li B,et al.Recent progress on manganese dioxide based supercapacitors[J].Journal of Materials Research,2011,25(8):1421-1432.
[12] Bao L H,Li X D.Towards textile energy storage from cotton T-shirts[J].Advanced Materials,2012,24(24):3246-3252.
[13] Cheng Z Y,Tan G P,Qiu Y F,et al.High performance electrochemical capacitors based on MnO2/activated-carbon-paper[J].Journal of Materials Chemistry C,2015(24):6166-6171.
[14] Kim M,Hwang Y,Min K,et al.Introduction of MnO2 nanoneedles to activated carbon to fabricate high-performance electrodes as electrochemical supercapacitors[J].Electrochimica Acta,2013,113(4):322-331.
[15] Li Q,Lu X F,Xu H,et al.Carbon/MnO2 double-walled nanotube arrays with fast ion and electron transmission for high-performance supercapacitors[J].ACS Appl Mater Interfaces,2014,6(4):2726-2733.
[16] Zhang H,Cao G,Wang Z,et al.Growth of manganese oxide nanoflowers on vertically-aligned carbon nanotube arrays for high-rate electrochemical capacitive energy storage[J].Nano Letters,2008,8(9):2664-2668.
[17] Wu M S,Guo Z S,Jow J J.Highly regulated electrodeposition of needle-like manganese oxide nanofibers on carbon fiber fabric for electrochemical capacitors[J].The Journal of Physical Chemistry C,2012,114(49):21861-21867.
[18] Luo Y,Jiang J,Zhou W,et al.Self-assembly of well-ordered whisker-like manganese oxide arrays on carbon fiber paper and its application as electrode material for supercapacitors[J].Journal of Materials Chemistry,2012,22(17):8634-8640.
[19] Bordjiba T,Bélanger D.Direct redox deposition of manganese oxide on multiscaled carbon nanotube/microfiber carbon electrode for electrochemical capacitor[J].Journal of The Electrochemical Society,2009,156(5):A378-A384.
[20] Ye K H,Liu Z Q,Xu C W,et al.MnO2/reduced graphene oxide composite as high-performance electrode for flexible supercapacitors[J].Inorganic Chemistry Communications,2013,30(1):1-4.
[21] Li Z,Mi Y,Liu X,et al.Flexible graphene/MnO2 composite papers for supercapacitor electrodes[J].Journal of Materials Chemistry,2011,21(38):14706-14711.
[22] Dong X,Wang X,Wang J,et al.Synthesis of a MnO2-graphene foam hybrid with controlled MnO2 particle shape and its use as a supercapacitor electrode[J].Carbon,2012,50(13):4865-4870.
[23] He Y,Chen W,Li X,et al.Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes[J].ACS Nano,2013,7(1):174-182.
[24] Kim M,Hwang Y,Kim J.Fabrication of graphene-carbon nanotube papers decorated with manganese oxide nanoneedles on the graphene sheets for supercapacitors[J].Physical Chemistry Chemical Physics,2014,16(1):351-361.
[25] Cheng Y,Lu S,Zhang H,et al.Synergistic effects from graphene and carbon nanotubes enable flexible and robust electrodes for high-performance supercapacitors[J].Nano Letters,2012,12(8):4206-4211.
基金资助
教育部留学回国人员科技活动择优资助项目(2015192);黑龙江省自然基金(LC2015020);黑龙江省教育厅科学技术研究项目(12541120);哈尔滨理工大学青年拔尖人才培养计划(201306)