双相炭黑是新型的填料,螺旋纳米碳纤维(HCNF)是具有特殊结构的炭材料。以气相生长HCNF为基础,通过原位生成法制备了双向炭黑——SiO2/螺旋纳米碳纤维(SiO2-HCNF),研究了SiO2-HCNF的制备与性质。最后与炭黑N330和HCNF进行结合胶性能对比。结果表明:SiO2-HCNF结合胶的抗拉强度较天然橡胶(NR)提高了0.2MPa,较HCNF结合胶提高了0.098MPa,并且结合胶量也提高了8.27%。
Dual phase carbon black is a new type of filler,and helical carbon nanofibers (HCNF) is a new carbon material with special structure.The manufacture and properties of dual phase carbon black (SiO2-HCNF) were discussed,which was prepared by in-situ synthesis method used HCNF by chemical vapor deposition.Finally the properties of bound rubber was investigated by comparing SiO2-HCNF with carbon black (N330) and HCNF.The tensile strength of bound rubber of SiO2-HCNF was increased up to 0.2MPa compared with the nature rubber (NR) and 0.098MPa with HCNF,the bound rubber of SiO2-HCNF content was increased to 8.27% compared with HCNF.
[1] 张士齐,贾红兵,刘卫东.填料-橡胶的化学和物理作用及其对补强的影响[J].橡胶工业,2003,50(4):201-204.
[2] 王梦蛟.聚合物-填料和填料-填料相互作用对填充硫化胶动态力学性能的影响(续3)[J].轮胎工业,2001,21(1):38-44.
[3] Zhong X O,Hanafi I,Azhar A B.Optimisation of oil palm ash as reinforcement in natural rubber vulcanisation:a comparison between silica and carbon black fillers[J].Polymer Testing,2013,32(4):625-630.
[4] Strauβ Michael,Pieper Thomas,Peng Weiguo,et al.Structure of filled rubbers and mechanism of reinforcement[J].Makromolekulare Chemie Macromolecular Symposia,1993,76(1):131-136.
[5] 王晓波.橡胶中炭黑的分散度的评价机理和方法研究[D].青岛:青岛科技大学,2013.
[6] 危银涛,杨挺青,马六成,等.炭黑填充橡胶复合材料动态力学性能和生热预报[J].橡胶工业,2000,47(2):67-73.
[7] 李跃,任文坛,张勇,等.橡胶/炭黑导电复合材料的压阻效应研究进展[J].化工新型材料,2012,40(9):123-131.[8] Surya I,Ismail H,Azura A R.The effect of alkanolamide loading on properties of carbon black-filled natural rubber (SMR-L),epoxidised natural rubber (ENR),and styrene-butadiene rubber (SBR) compounds[J].Polymer Testing,2015,42(10):208-214.
[9] 李永泉,刘军,骆英,等.炭黑填充BST/PVDF复合薄膜的制备与介电性研究[J].化工新型材料,2015,43(12):39-41.
[10] 曹智灵.炭黑对硫化胶基本性能定伸应力的影响[J].贵州化工,2007,32(2):42-44.
[11] 王兵兵.白炭黑表面接枝改性及其在橡胶中的应用[D].广州:华南理工大学,2012.
[12] 王梦蛟.炭黑-白炭黑双相填料的研究[J].轮胎工业,1999,19(5):280-289.
[13] 李爱法,吴来春,蒋云.双相炭黑在全钢载重子午线轮胎胎面胶中的应用[J].橡胶工业,2010,30(10):608-610.
[14] 李岩.白炭黑的表面改性及其高填充SSBR复合材料的制备和性能研究[D].北京:北京化工大学,2014.
[15] Nitze F,Abou-Hamad E,Wågberg T.Carbon nanotubes and helical carbon nanofibers grown by chemical vapour deposition on C60 fullerene supported Pd nanoparticles[J].Carbon,2011,49(4):1101-1107.
[16] Vera-Agullo J,Glória-Pereira A,Varela-Rizo H,et al.Comparative study of the dispersion and functional properties of multiwall carbon nanotubes and helical-ribbon carbon nanofibers in polyester nanocomposites[J].Composites Science & Technology,2009,69(10):1521-1532.
基金资助
国家自然科学基金面上项目(51572177);四川理工学院研究生创新基金(y2015007);自贡市科技创新苗子工程(2015CXM06)
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