双壁碳纳米管是一种由两层石墨烯卷曲而成的同心圆管结构,它结合了单壁碳纳米管的电学性能和多壁碳纳米管的力学稳定性,可应用于医学、电子学和能源储存等领域。综述了双壁碳纳米管常用的合成方法,包含电弧放电法、豌豆荚生长法和化学气相沉积法,分析碳源种类、催化剂体系及反应温度等参数对双壁碳纳米管纯度的影响,讨论了其在生物检测、药物输送、复合材料以及能源储存其他领域的应用进展。
Double-walled carbon nanotubes are a concentric tubular structure formed by two layers of rolled graphene.They combine the electrical properties of single-walled carbon nanotubes with the mechanical stability of multi-walled carbon nanotubes,making them applicable in fields such as medicine,electronics,and energy storage.This review summarized the commonly used synthesis methods for double-walled carbon nanotubes,including arc discharge method,pea-pod growth method,and chemical vapor deposition.It analyzed the effects of parameters such as carbon source type,catalyst system,and reaction temperature on the purity of double-walled carbon nanotubes,and discussed their application progress in bio-detection,drug delivery,composite materials,and other areas of energy storage.
[1] Ibrahim K S.Carbon nanotube-properties and applications:a review[J].Carbon Letters,2013,14(3):131-144.
[2] Shen C,Brozena A H,Wang Y.Double-walled carbon nanotube:challenges and opportunities[J].Nanoscale,2011,3(2):503-518.
[3] Moore K E,Tune D D,Flavel B S.Double-walled carbon nanotube processing[J].Advanced Materials,2015,27(20):3105-3137.
[4] Iijima S.Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56-58.
[5] Hutchison J L,Kiselev N A,Krinichnaya E P,et al.Double-walled carbon nanotube fabricated by a hydrogen arc discharge method[J].Carbon,2001,39(5):761-770.
[6] Saito Y,Nakahira T,Uemura S.Growth conditions of double-walled carbon nanotube in arc discharge[J].The Journal of Physical Chemistry B,2003,107(4):931-934.
[7] Zhao J,Su Y,Yang Z,et al.Arc synthesis of double-walled carbon nanotube in low pressure air and their superior field emission properties[J].Carbon,2013,58:92-98.
[8] Smith B W,Monthioux M,Luzzi D E.Encapsulated C60 in carbon nanotube[J].Nature,1998,396(6709):323-324.
[9] Smith B W,Monthioux M,Luzzi D E.Carbon nanotube encapsulated fullerenes:a unique class of hybrid materials[J].Chemical Physics Letters,1999,315(1-2):31-36.
[10] Suarez-Martinez I,Higginbottom P J,Marks N A.Molecular dynamics simulations of the transformation of carbon peapods into double-walled carbon nanotube[J].Carbon,2010,48(12):3592-3598.
[11] Shi L,Wei J,Yanagi K,et al.Templated direct growth of ultra-thin double-walled carbon nanotube[J].Nanoscale,2018,10(45):21254-21261.
[12] Berd M,Puech P,Righi A,et al.Resonant laser-induced formation of double-walled carbon nanotube from peapods under ambient conditions[J].Small,2012,8(13):2045-2052.
[13] Fujisawa K,Kim H,Go S,et al.A review of double-walled and triple-walled carbon nanotube synthesis and applications[J].Applied Sciences,2016,6(4):109.
[14] Khosravifard E,Mosavian M T H,Maghrebi M.Statistical investigation of factors affecting the growth of carbon nanotube in the chemical vapor deposition (CVD) processes[J].Journal of Cluster Science,2025,36(1):32.
[15] Barnard J S,Paukner C,Koziol K K.The role of carbon precursor on carbon nanotube chirality in floating catalyst chemical vapour deposition[J].Nanoscale,2016,8(39):17262-17270.
[16] Duong B,Seraphin S,Wang L,et al.Production of predominantly semiconducting double-walled carbon nanotube[J].Carbon,2011,49(11):3512-3521.
[17] Liu Y,Qian W Z,Zhang Q,et al.Synthesis of high-quality,double-walled carbon nanotube in a fluidized bed reactor[J].Chemical Engineering & Technology,2009,32(1):73-79.
[18] Cheung C L,Kurtz A,Park H,et al.Diameter-controlled synthesis of carbon nanotube[J].The Journal of Physical Chemistry B,2002,106(10):2429-2433.
[19] Lee S H,Kim H R,Lee T,et al.Synthesis of carbon nanotube fibers from carbon precursors with low decomposition temperatures using a direct spinning process[J].Carbon,2017,124:219-227.
[20] Lyu S C,Liu B C,Lee S H,et al.Large-scale synthesis of high-quality double-walled carbon nanotube by catalytic decomposition of n-hexane[J].The Journal of Physical Chemistry B,2004,108(7):2192-2194.
[21] Kondo D,Sato S,Kawabata A,et al.Selective growth of vertically aligned double-and single-walled carbon nanotube on a substrate at 590℃[J].Nanotechnology,2008,19(43):435601.
[22] Flahaut E,Peigney A,Laurent Ch,et al.Synthesis of single-walled carbon nanotube-Co-MgO composite powders and extraction of the nanotube[J].Journal of Materials Chemistry,2000,10(2):249-252.
[23] Flahaut E,Bacsa R,Peigney A,et al.Gram-scale CCVD synthesis of double-walled carbon nanotube[J].Chemical Communications,2003(12):1442.
[24] Yang H S,Zhang L,Dong X H,et al.Precise control of the number of walls formed during carbon nanotube growth using chemical vapor deposition[J].Nanotechnology,2012,23(6):065604.
[25] Xu L,Yang J,Yuan X,et al.Efficient synthesis of high quality double walled carbon nanotube and their cost-effective properties[J].New Journal of Chemistry,2022,46(39):18724-18731.
[26] Hafner J H,Bronikowski M J,Azamian B R,et al.Catalytic growth of single-wall carbon nanotube from metal particles[J].Chemical Physics Letters,1998,296(1-2):195-202.
[27] Song J L,Wang L,Feng S A,et al.Growth of carbon nanotube by the catalytic decomposition of methane over Fe-Mo/Al2O3 catalyst:effect of temperature on tube structure[J].New Carbon Materials,2009,24(4):307-313.
[28] Dekali S,Bachelet C,Maunoir-Regimbal S,et al.Biological effects of double-walled carbon nanotube on the innate immune system:an in vitro study on THP-1 human monocytes[J].Toxicology,2016,365:1-8.
[29] Patel A M,Joshi A Y.Detection of biological objects using dynamic characteristics of double-walled carbon nanotube[J].Applied Nanoscience,2015,5(6):681-695.[30] Neves V,Heister E,Costa S,et al.Design of double-walled carbon nanotube for biomedical applications[J].Nanotechnology,2012,23(36):365102.
[31] Guillet J F,Flahaut E,Golzio M.A hydrogel/carbon-nanotube needle-free device for electrostimulated skin drug delivery[J].Chemphyschem:A European Journal of Chemical Physics and Physical Chemistry,2017,18(19):2715-2723.
[32] He Y,Jin H,Qiu S,et al.A novel strategy for high-performance transparent conductive films based on double-walled carbon nanotube[J].Chemical Communications,2017,53(20):2934-2937.
[33] Yang X,Zhai X,Zhang F,et al.Efficient electrolytic hydrogen evolution from cobalt porphyrin covalently functionalized with chain-like phosphazene on double-walled carbon nanotube[J].Journal of Colloid and Interface Science,2025,689:137238.
[34] Muangrat W,Obata M,Htay M T,et al.Nitrogen-doped graphene nanosheet-double-walled carbon nanotube hybrid nanostructures for high-performance supercapacitors[J].Flatchem,2021,29:100292.
[35] Maeng J,Park G H,Ji J,et al.N-doped carbon nanotube-graphene nanoarchitecture electrodes with solid-state biopolymer electrolyte for high performance flexible supercapacitors[J].Carbon,2025,243:120545.
基金资助
国家自然科学基金(52576075、52336003和52206096);山东省泰山学者项目(tstp20250505)
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