过渡金属磷化物(TMPs)因可调电子结构和优异的析氧反应(OER)活性,成为贵金属催化剂的理想替代材料。金属-有机框架(MOFs)凭借大比表面积、有序孔结构和组分可设计性,为衍生高性能TMPs奠定了基础。从形貌设计、采用新型磷化工艺、优化结构设计及本征活性设计出发,介绍了提高了MOFs衍生TMPs催化剂OER性能的研究进展,并展望了其未来的发展趋势。
Transition metal phosphides (TMPs) have emerged as ideal alternatives to precious metal catalysts owing to their tunable electronic structures and excellent oxygen evolution reaction (OER) activity.Metal-organic frameworks (MOFs),with their large specific surface area,ordered pore structures,and designable compositions,provide a solid foundation for deriving high-performance TMPs.This review summarized recent research progress in enhancing the OER performance of MOF-derived TMPs catalysts from four key perspectives:morphology design,adoption of novel phosphidation processes,structural optimization,and intrinsic activity modulation.Future development trends in this field were also discussed.
[1] Wang T,Wang C,Jin Y,et al.Amorphous Co-Fe-P nanospheres for efficient water oxidation[J].Journal of Mater Chemistry A,2017,5(48):25378-25384.
[2] Witman M,Ling S,Anderson S,et al.In silico design and screening of hypothetical MOF-74 analogs and their experimental synthesis[J].Chemical Science,2016,7(9):6263-6272.
[3] Cao X K,Gao Y,Li Y T,et al.Research progress on MOFs and their derivatives as promising and efficient electrode materials for electrocatalytic hydrogen production from water[J].RSC Advances,2023,13(35):24393-24411.
[4] Zhang W,Han N,Luo J S,et al.Critical role of phosphorus in hollow structures cobalt-based phosphides as bifunctional ca-talysts for water splitting[J].Small,2021,18(4):2103561.
[5] Xu X W,Wang T Y,Zhao C,et al.MOFs derived NiFeP po-rous nanoflowers for boosted electrocatalytic water splitting[J].Microporous and Mesoporous Materials,2021,312:110760.
[6] Niu H J,Wang Q Y,Huang C X,et al.Noble metal-based he-terogeneous catalysts for electrochemical hydrogen evolution reaction[J].Applied Sciences,2023,13(4):2177.
[7] Gu L,Li Y,Chowdhury A D.Controllable synthesis of efficient and robust carbon-incorporated ruthenium-cobalt mixed metal phosphide-based bifunctional electrocatalyst for the water and urea oxidation[J].Materials Today Chemistry,2023,27:101290.
[8] Li X M,Xie Z K,Roy S,et al.Amorphous high-entropy phosphide nanosheets with multi-atom catalytic sites for efficient oxygen evolution[J].Advanced Materials,2025,37(10):2410295.
[9] Walid T,Xu Z,Rashid K,et al.Recent trends in transition metal phosphide (TMP)-based seawater electrolysis for hydrogen evolution[J].Sustainability,2023,15(19):14389.
[10] Xiao M J,Zhang C T,Wang P,et al.Polymetallic phosphides evolved from MOF and LDH dual-precursors for robust oxygen evolution reaction in alkaline and seawater media[J].Materials Today Physics,2022,24:100684.
[11] Han P,Hua S G,Ji J,et al.Hierarchical porous structured trimetallic non-oxides CoFeMo-A (A=P,Se) as electrocatalysts for oxygen evolution reaction[J].Journal of Alloys and Compounds,2023,932:167538.
[12] Anantharaj S,Subrata K,Noda.Progress in nickel chalcogenide electrocatalyzed hydrogen evolution reaction[J].Jouanal of Materials Chemistry A,2020,8(8):4174-4192.
[13] Shi Q,Liu Q,Zheng Y P,et al.Controllable construction of bifunctional CoxP@N,P-doped carbon electrocatalysts for rechargeable zinc-air batteries[J].Energy & Environmental Materials,2022,5(2):515-523.
[14] Xue H R,Zhang Z H,Lai Y,et al.Construction of Co2P nanoparticles anchored on hollow N-doped porous carbon nanoleaf for high-efficiency water splitting[J].Chemical Engineering Journal,2024,483:149057.
[15] Jiang H S,Shi J H,Liu X Y,et al.Highly dispersed copper phosphide nanoparticles accelerate the electrolytic water oxidation process[J].Green Chemistry,2024,26:3388-3396.
[16] Wang X,Chai L L,Ding J Y,et al.Chemical and morphological transformation of MOF-derived bimetallic phosphide for efficient oxygen evolution[J].Nano Energy,2019,62:745-753.
[17] Zhang T,Ren X H,Ma F,et al.MOF-derived Co(Ni)Ox species loading on two-dimensional cobalt phosphide:a Janus electrocatalyst toward efficient and stable overall water splitting[J].Applied Materials Today,2023,34:101912.
[18] Jiang H L,Zhao Z,Li G,et al.Hollow spherical heterostructured FeCo-P catalysts derived from MOF-74 for efficient overall water splitting[J].Advanced Science,2024,11(2):2306919.
[19] Xu Q C,Zhang L Y,Zhang J H,et al.Anion exchange membrane water electrolyzer:electrode design,lab-scaled testing system and performance evaluation[J].EnergyChem,2022,4(5):100087.
[20] Yang H Y,Driess M,Menezes P W.Self-supported electroca-talysts for practical water electrolysis[J].Advanced Energy Materials,2021,11(39):2102074.
[21] Lv Z P,Zhang H K,Liu C H,et al.Oxygen-bridged cobalt-chromium atomic pair in MOF-derived cobalt phosphide networks as efficient active sites enabling synergistic electrocatalytic water splitting in alkaline media[J].Advanced Science,2024,11(3):2306678.
[22] Chen N,Che S,Liu H C,et al.In situ growth of self-suppor-ting MOFs-derived Ni2P on hierarchical doped carbon for efficient overall water splitting[J].Catalysts,2022,12(11):1319.
[23] Zhao Y F,Zhang J Q,Xie Y H,et al.Constructing atomic he-terometallic sites in ultrathin nickel-incorporated cobalt phosphide nanosheets via a boron-assisted strategy for highly efficient water splitting[J].Nano Letters,2021,21(1):823-832.
[24] Wang X,Yang L L,Xing C C,et al.MOF-derived ultrathin cobalt molybdenum phosphide nanosheets for efficient electrochemical overall water splitting[J].Nanomaterials,2022,12(7):1098.
[25] Wang H H,Wu J H,Guo S W,et al.ZIF-67 derived superhydrophilic Fe-CoP/Ni2P@NC to construct self-supported electrode for boosting electrochemical water splitting[J].Journal of Alloys and Compounds,2025,1022:179796.
[26] Kou Z K,Li X,Zhang L,et al.Dynamic surface chemistry of catalysts in oxygen evolution reaction[J].Small Science,2021,1(7):2100011.
[27] Wang X Q,Zhou J H,Cui W G,et al.Electron manipulation and surface reconstruction of bimetallic iron-nickel phosphide nanotubes for enhanced alkaline water electrolysis[J].Advanced Science,2024,11(26):2401207.
[28] Guo X J,Lv C H,Wang Y,et al.Nickel phosphonate MOF derived N-doped carbon-coated phosphorus-vacancies-rich Ni2P particles as efficient bifunctional oxygen electrocatalyst[J].Chemistry-A Europe Jouranal,2023,29(66):202302182.
基金资助
山东省重点研发计划(公益类专项)项目(2019GGX103017)
PDF
