除湿材料研究进展:从传统无机材料到金属有机框架

刘玉桂1,2, 张典堂3, 马博谋3*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (7) : 26 -30.

PDF
化工新型材料 ›› 2026, Vol. 54 ›› Issue (7) : 26-30. DOI: 10.19817/j.cnki.issn1006-3536.2026.07.039
综述与专论

除湿材料研究进展:从传统无机材料到金属有机框架

    刘玉桂1,2, 张典堂3, 马博谋3*
作者信息 +

Research progress on dehumidification materials:from traditional inorganic materials to metal-organic frameworks

  • Liu Yugui1,2, Zhang Diantang3, Ma Bomou3
Author information +
文章历史 +
PDF

摘要

湿度控制对于日常生活、工业生产都具有重要意义,干燥剂作为湿度控制系统的关键材料一直都是除湿技术的研究重点。全面综述了传统无机多孔固体干燥剂(硅胶、分子筛、活性氧化铝)、吸湿盐(氯化物)液体干燥剂和基于金属有机框架(MOFs)的新型除湿干燥剂。阐述了三类干燥剂各自的除湿特点和性能缺陷,详细介绍了近年来三类干燥剂的研究进展,并对未来除湿干燥剂的发展趋势进行了展望。

Abstract

Humidity control is of great significance in our daily life and industrial production.Desiccants,the key materials of humidity control systems,have consistently been a major focus of research in dehumidification technology.This article provided a comprehensive review of traditional inorganic porous solid desiccants (silica gel,molecular sieves,activated alumina),hygroscopic salts (chlorides) liquid desiccants,as well as new types of desiccants based on metal-organic frameworks (MOFs).It elaborated the dehumidification characteristics and deficiencies of the three types of desiccants,provided a detailed research progress of these three types of desiccants in recent years,and looked forward the development trends of future desiccant technologies.

关键词

除湿材料 / 固体除湿 / 液体除湿 / 金属有机框架

Key words

dehumidification materials / solid desiccants / liquid desiccants / metal-organic frameworks

引用本文

引用格式 ▾
除湿材料研究进展:从传统无机材料到金属有机框架[J]. 化工新型材料, 2026, 54(7): 26-30 DOI:10.19817/j.cnki.issn1006-3536.2026.07.039

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 刘露露.常用固体吸附剂吸湿与再生性能研究[D].合肥:安徽建筑大学,2019.
[2] 牛永红,修诗博,张丽奇,等.空调用固体除湿材料研究进展[J].应用化工,2018,47(11):2464-2468.
[3] 郑金海.复合型除湿材料的设计制备与性能研究[D].石家庄:河北科技大学,2024.
[4] 杨发妹,陈柳.硅胶除湿转轮性能优化实验研究[J].低温与超导,2021,50(1):41-47.
[5] Sangteantong P,Chainarong K,Donphai W,et al.Green synthesis of surfactant-free mesoporous silica with strong hydrophilicity via metal salt modifications for moisture adsorption[J].Reaction Chemistry & Engineering,2024,9:816-824.
[6] 何晨晨.空调用新型固体除湿材料的制备及性能研究[D].西安:西安科技大学,2021.
[7] 陈康.多孔材料-聚合物复合干燥剂的开发及其在除湿换热器上的应用研究[D].杭州:浙江理工大学,2022.
[8] Zheng X,Chen K,Lin Z.Synthesis and characterization of slginate-silica gel composites for adsorption dehumidification[J].Industrial & Engineering Chemistry Research,2020,59(14):5760-5767.
[9] Li X,Ran M Y.Gypsum-based silica gel humidity-controlling composite materials:preparation,characterization,and performance[J].Journal of Wuhan University of Technology-Mater Sci Ed,2024,39(2):337-344.
[10] 刘侨.多级孔硅铝酸盐的制备及除湿性能[D].广州:华南理工大学,2016.
[11] Jeong Y,Ansari J R,Sadeghi K,et al.Applicability of polypropylene/polyethylene glycol/molecular sieve composites as desiccant pharmaceutical packaging materials[J].Food Packaging and Shelf Life,2024,42:101266.
[12] 刘林,何兆红,陈捷超,等.固体除湿复合干燥剂研究进展[J].新能源进展,2017,5(5):377-385.
[13] 智佳.铈改性分子筛的制备及对水蒸气吸脱附性能的研究[D].重庆:重庆大学,2015.
[14] Tan B Q,Luo Y S,Bi X Y,et al.Improved desorption performance of NaA zeolite by rare earth (Re=La,Nd) ion exchange[J].Heat and Mass Transfer,2019,55:3179-3187.
[15] Meshcheryakov E P,Reshetnikov S I,Sandu M P,et al.Efficient adsorbent-desiccant based on aluminium oxide[J].Applied Sciences-Basel,2021,11(6):2457.
[16] 许乃才,黄国勇,史丹丹,等.氧化铝基吸附材料制备及除氟研究进展[J].材料导报,2023,37(15):21080098.
[17] 廖艳,邱小伟,何春林,等.镧铈改性活性氧化铝及其对氟的吸附性能研究[J].离子交换与吸附,2025,41(4):279-291.
[18] 罗帅,张祥明.载锰活性氧化铝处理地下水中氟离子的效果研究[J].化工生产与技术,2024,30(5):21-24.
[19] 李爱征,黄宗华,杨英英,等.深度除湿技术在低湿行业中的应用及研究进展[J].暖通空调,2023,53(9):1-11.
[20] 何晨晨,陈柳.新型复合固体除湿材料的吸附和解吸性能研究[J].低温与超导,2020,48(4):58-65.
[21] 陆永吉.凹凸棒土改性PVDF共混除湿膜结构与性能研究[D].天津:天津工业大学,2022.
[22] 王雪.PVDF/PVA/CaCl2共混除湿膜结构设计与研究[D].天津:天津工业大学,2020.
[23] Zhu P H,Yu Z Y,Sun H,et al.3D printed cellulose nanofiber aerogel scaffold with hierarchical porous structures for fast solar-driven atmospheric water harvesting[J].Advanced Materials,2024,36(1):2306653.
[24] Guo H Y,Luo Q L,Liu D,et al.Super moisture-sorbent sponge for sustainable atmospheric water harvesting and power generation[J].Advanced Materials,2024,36(52):2414285.
[25] Yu Z H,Li S H,Zhang J C,et al.Phospholipid bilayer inspired sandwich structural nanofibrous membrane for atmospheric water harvesting and selective release[J].Nano Letters,2024,24(8):2629-2636.
[26] Fu C H,He Y X,Yu A H,et al.Vertical macroporous chitosan aerogel adsorbents for simple and efficient enhancement of atmospheric water harvesting and air dehumidification[J].Journal of Materials Chemistry A,2024,12(48):33926-33983.
[27] Li J X,Xu C J,Chen L F,et al.Tandem atmospheric water harvesting and passive cooling enabled by hygroscopic biopolymer-based aerogels[J].Advanced Functional Materials,2025,35(31):2423063.
[28] 王楷乔.环境友好型金属有机骨架材料合成及其室内空气除湿净化性能研究[D].北京:北京建筑大学,2024.
[29] 王子齐,魏一,汪士程,等.基于金属有机框架材料大气集水的研究进展[J].环境化学,2023,42(11):3678-3691.
[30] 王明辉.固体吸附材料的水蒸气吸脱附动态特性研究[D].北京:北京建筑大学,2022.
[31] 何晨晨,杨发妹,陈柳.金属有机框架材料型固体除湿器性能研究[J].低温与超导,2021,49(9):47-53.
[32] Ding D,Rasmussen O S,Qin M H.Sustainable metal-organic framework based paper sheet as wallpaper for passive indoor moisture control[J].Energy & Buildings,2024,313:114262.
[33] Qin M H,Rasmussen O S,Chen J,et al.Novel MOF-based autonomous humidity control materials for energy-efficient indoor moisture regulation[J].Building and Environment,2024,261:111757.
[34] Cheng M R,Bai H Y,Wang X S,et al.Engineering hygroscopic MOF-based silk via bioinspired interfacial assembly for fast moisture manipulation[J].Advanced Materials,2024,36(48):2411680.
[35] Luo Q,Chen M S,Yu D D,et al.An atmospheric water-harvester with ultrahigh uptake-release efficiency at low humidity[J].ACS Nano,2024,18(22):14650-14660.
[36] Ding D,Qin M H.Metal-organic frameworks (MOFs) based electrospun nanofiber membrane for passive indoor moisture control[J].Buildings,2023,13(5):1192.
[37] Zhang L Y,Li R Y,Zheng S,et al.Hydrogel-embedded vertically aligned metal-organic framework nanosheet membrane for efficient water harvesting[J].Nature Communications,2024,15(1):9738.
[38] Xu J X,Li T X,Chao J W,et al.Efficient solar-driven water harvesting from arid air with metal-organic frameworks modified by hygroscopic salt[J].Angewandte Chemie-International Edition,2020,59(13):5202-5210.
[39] Li M J,Shu L,Zhang X F,et al.Efficient atmospheric water harvesting enabled by hierarchically structured cellulose foam[J].Chemical Engineering Journal,2024,499:155932.
[40] An H,Chen Y,Wang Y,et al.High-performance solar-driven water harvesting from air with a cheap and scalable hygroscopic salt modified metal-organic framework[J].Chemical Engineering Journal,2023,461:141955.
[41] Zhao H Z,Lei M,Liu T,et al.Synthesis of composite material HKUST-1/LiCl with high water uptake for water extraction from atmospheric air[J].Inorganica Chimica Acta,2020,511:119842.
[42] Wu Q Y,Ma X,Zheng L B,et al.One-pot synthesis of composite metal-organic framework for enhanced water adsorption:feasibility and mechanism exploration[J].Desalination,2025,593:118251.

基金资助

无锡市“太湖之光”科技攻关(产业前瞻及关键技术研发)项目(G20242015)

AI Summary AI Mindmap
PDF

141

访问

0

被引

导航
相关文章

AI思维导图

/