金属有机框架(MOFs)材料又被称为配位聚合物,一般是由金属离子或者金属蔟与有机桥联配体通过自组装而形成具有三维立体结构的多孔晶体材料。随着对MOFs材料的研究不断深入,越来越多的金属离子、金属蔟、有机桥联配体被发现。但MOFs材料存在的一些缺点使其应用受到限制。纤维素是自然界三大生物素之一,拥有丰富的储量。研究发现,以纤维素作为MOFs材料的基体,使MOFs材料与纤维素之间通过化学键或者氢键的作用相互结合,可有效改善MOFs材料的一些缺陷。通过总结近年纤维素基MOFs材料在水体处理方面的进展,期望为纤维素基MOFs材料在水体处理中的应用提供参考。
Metal organic framework (MOFs) materials,also known as coordination polymers,are generally porous crystalline materials with three-dimensional structures formed by self-assembly of metal ions or metal clusters with organic bridging ligands.With the continuous deepening of research on MOFs materials,more and more metal ions,metal clusters,and organic bridging ligands have been discovered.However,the certain drawbacks of MOFs materials limit their application.Cellulose is one of the three major biological substances in nature,with abundant reserves in the natural world.A study has found that using cellulose materials as the matrix of MOFs materials allows for chemical or hydrogen bonding between MOFs materials and cellulose,effectively improving some of the defects of MOFs materials.This article summarized the progress of cellulose-based MOFs materials in water treatment in recent years,aiming to provide some reference for exploring the application potential of cellulose-based MOFs materials in water treatment.
[1] 黄馨月,陈志友,郭俊喆,等.水污染治理现状概览[J].东北水利水电,2025,43(3):41-43.
[2] 吕超,谭小兵.环境保护与污水处理技术研究[M].沈阳:辽宁电子出版社,2023:95-98.
[3] Jian Y H,Zou J F,Zheng J C,et al.Current status and prospect of MOF-74-based materials for biomedical applications[J].Journal of Drug Delivery Science and Technology,2024,94(21):105470-105490.
[4] Zhang J J,Qi Y P,Shen Y F,et al.Research progress on chemical modification and application of cellulose:a review[J].Materials Science-Medziagotyra,2022,28(1):60-67.
[5] Khalid W,Heng L Y,Arip M N M.Surface modification of cellulose nanomaterial for urea biosensor application[J].Sains Malaysiana,2018,47(5):941-949.
[6] Laureano-Anzaldo C M,Haro-Mares N B,Meza-Contreras J C,et al.Chemical modification of cellulose with zwitterion moieties used in the uptake of red Congo dye from aqueous media[J].Cellulose,2019,26(17):9207-9227.
[7] Zhang X F,Wang Z G,Ding M L,et al.Advances in cellulose-metal organic framework composites:preparation and applications[J].Journal of Materials Chemistry A,2021,9(41):23353-23363.
[8] Abdelhamid H N,Mathew A P.Cellulose-metal organic frameworks (CelloMOFs) hybrid materials and their multifaceted applications:a review[J].Coordination Chemistry Reviews,2022,451(36):214263-214303.
[9] Torres-Cortés S A,Velasquez M,Pérez L D,et al.Ex situ synthesis of MOF@PET/cotton textile fibers as potential antibacterial materials[J].Journal of Polymer Research,2022,29(10):427-442.
[10] Amalia A,Lestari W W,Pratama J H,et al.Modification of dry-gel synthesized MIL-100(Fe) with carboxymethyl cellulose for curcumin slow-release[J].Journal of Polymer Research,2022,29(11):487-499.
[11] Liang Z P,Liang Y H,Yu P J,et al.Ultrasonic-assisted in situ synthesis of MOF-199 on the surface of carboxylated cellulose fibers for efficient adsorption of methylene blue[J].RSC Advances,2024,14(21):15095-15105.
[12] Tian S L,Yi Z D,Chen J Q,et al.In situ growth of UiO-66-NH2 in wood-derived cellulose for iodine adsorption[J].Journal of Hazardous Materials,2023,443(2):130236-130249.
[13] Singh R,Gautam N,Mishra A,et al.Heavy metals and living systems:an overview[J].Indian Journal of Pharmacology,2011,43(3):246-253.
[14] Zhao J X,He J,Liu L,et al.Self-cross-linking of metal-organic framework (MOF-801) in nanocellulose aerogel for efficient adsorption of Cr(Ⅵ) in water[J].Separation and Purification Technology,2023,327(1):124942-14916.
[15] Jiang S,Yan Z F,Deng Y Q,et al.Fluorescent bacterial cellulose@Zr-MOF via in-situ synthesis for efficient enrichment and sensitive detection of Cr(Ⅵ)[J].International Journal of Biological Macromolecules,2024,262(1):129854-129861.
[16] Wang M,Shao L P,Jia M Y.Shape memory and underwater superelastic mof@cellulose aerogels for rapid and large-capacity adsorption of metal ions[J].Cellulose,2022,29(15):8243-8254.
[17] Indurkar P,Mondal M,Kulshrestha V.Highly efficient Cu-doped BTC aerogel for lead ions adsorption from aqueous solution:statistical modeling and optimization study using response surface methodology[J].Surfaces and Interfaces,2022,34(1):102277-102290.
[18] Cao Y Y,Du M S,Han F,et al.Carboxymethyl cellulose aerogel decorated MOF-808 with defects via mixed-metallic center and etching for enhanced Pb(Ⅱ) removal[J].Separation and Purification Technology,2024,344(1):127262-12772.
[19] Yang P P,Song Y C,Sun J,et al.Carboxymethyl cellulose and metal-organic frameworks immobilized into polyacrylamide hydrogel for ultrahigh efficient and selective adsorption U(Ⅵ) from seawater[J].International Journal of Biological Macromolecules,2024,266(2):130996-131003.
[20] Yang Y X,Guo Y F,Qiu Z,et al.In situ growth of Zr-based metal-organic frameworks on cellulose sponges for Hg2+ and methylene blue removal[J].Carbohydrate Polymers,2024,328(1):121750-121760.
[21] Shiri M,Hosseinzadeh M,Shiri S,et al.Adsorbent based on MOF-5/cellulose aerogel composite for adsorption of organic dyes from wastewater[J].Scientific Reports,2024,14(1):15623-15635.
[22] Song W Q,Zhu M,Zhu Y F,et al.Zeolitic imidazolate framework-67 functionalized cellulose hybrid aerogel:an environmentally friendly candidate for dye removal[J].Cellulose,2020,27(4):2161-2172.
[23] Wu Y H,Li Y W,Zheng Y C,et al.Fabrication of highly porous MOF/cellulose beads for sustained degradation of dye[J].Cellulose,2023,30(16):10427-10436.
[24] Li X,Wang L L,Li S Y,et al.In situ growth of HKUST-1 on electrospun polyacrylonitrile nanofibers/regenerated cellulose aerogel for efficient methylene blue adsorption[J].International Journal of Biological Macromolecules,2024,274(2):133381.
[25] Alanazi K D,Alshammari B H,Alkhatib F M,et al.Adsorbent beads based on Fe-BTC@Chitosan/microcrystalline cellulose for simultaneous removal of sulfa drugs[J].Cellulose,2024,31(18):11087-11100.
[26] Liu Q,Yu H H,Zeng F M,et al.Polyaniline as interface layers promoting the in-situ growth of zeolite imidazole skeleton on regenerated cellulose aerogel for efficient removal of tetracycline[J].Journal of Colloid and Interface Science,2020,579(1):119-127.
[27] Abd El-Monaem E M,Omer A M,Khalifa R E,et al.Floatable cellulose acetate beads embedded with flower-like zwitterionic binary MOF/PDA for efficient removal of tetracycline[J].Journal of Colloid and Interface Science,2022,620(7):333-345.
[28] Koriem O A,Showman M S,El-Shazly A H,et al.Cellulose acetate/polyvinylidene fluoride based mixed matrix membranes impregnated with UiO-66 nano-MOF for reverse osmosis desalination[J].Cellulose,2023,30(1):413-426.
[29] Zhang J Y,Soliman A,El-marghany Adel,et al.Utilization of MOF-enhanced hydrophilic nanocomposite reverse osmosis membrane for desalination with antifouling capabilities[J].Polymer Engineering and Science,2024,64(9):4430-4441.
[30] Koriem O A,Showman M S,El-Shazly A H,et al.Synthesis of high-performance biocompatible polymeric membranes incorporated with zirconium-based MOF for an enhanced brackish water RO desalination[J].Cellulose,2024,31(4):2309-2325.
[31] Obaid M,Alsadun N,Shekhah O,et al.Deployment of superhydrophilic and super-antifouling Cr-soc-MOF-1-based membrane for ultrafast separation of stabilized oil-in-water emulsions[J].ACS Applied Materials & Interfaces,2023,15(25):31067-31076.
[32] Chen Z X,Xue J J,Zhang J Q,et al.Co-doped Zr-UiO-66-NH2@carboxylated cellulose nanocrystals/PAN membrane for oil/water separation with photocatalysis-PMS synergistic self-cleaning and antibacterial activity[J].International Journal of Biological Macromolecules,2024,282(4):137158-137160.
[33] Hu H W,Li Y,Hong X S,et al.A superhydrophobic zirconium-based metal-organic framework/cellulose fiber composite material[J].Polymer Engineering and Science,2024,64(5):1981-1992.
[34] Dmitrenko M,Kuzminova A,Zolotarev A,et al.Nanofiltration mixed matrix membranes from cellulose modified with zn-based metal-organic frameworks for the enhanced water treatment from heavy metal ions[J].Polymers,2023,15(6):1341-1365.
[35] Yao D X,Li Q H,Chen B Q,et al.Long-lasting antibacterial cellulose acetoacetate membrane loaded with Ag@UiO-66-NH2 nanoparticals for efficient dye/salt fractionation[J].Journal of Environmental Chemical Engineering,2023,11(6):111265-111275.
[36] Zhu W K,Han M S,Kim D Y,et al.Facile preparation of nanocellulose/Zn-MOF-based catalytic filter for water purification by oxidation process[J].Environmental Research,2022,205(2):112417-112428.
[37] Shen C K,Mao Z P,Xu H,et al.Catalytic MOF-loaded cellulose sponge for rapid degradation of chemical warfare agents simulant[J].Carbohydrate Polymers,2019,213(16):184-191.
[38] Li J R,Yang Z,Hu G F,et al.Heteropolyacid supported MOF fibers for oxidative desulfurization of fuel[J].Chemical Engineering Journal,2020,388(30):124325-124324.
[39] Duan C,Che S S,Tian G D,et al.Mussel-inspired polydopamine and Zr-porphyrin MOF co-decoration of a cellulose paper-based composite membrane for efficient photoreduction of Cr(Ⅵ) and photothermal antibacterial in wastewater[J].Separation and Purification Technology,2025,353(1):128255-128264.
[40] Alves A L M M,dos Santos F V,Correa D S.3D-printed MOF/MoS2 aerogel for dye adsorption and photocatalytic degradation[J].Materials Today Chemistry,2024,40(9):102248-102260.
[41] Yu Y J,Wu D S,Liu D Y,et al.Self-assembled bacterial cellulose-based photo-enzyme coupled system enabled by visible light-driven for efficient dye degradation[J].Bioresource Technology,2024,411(11):131324-131332.
基金资助
新疆维吾尔自治区重点研发专项(20220264-3);新疆维吾尔自治区自然科学基金面上项目(2022D01A76);新疆“天山英才计划”项目(XJ2021268);新疆农业大学研究生科研创新计划项目(XJAUGRI2022049)项目;新疆农业大学大学生创新项目(2022453);新疆维吾尔自治区级农业工程重点学科支持项目(XJZD20220812)
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