菠萝叶纤维素基高吸水树脂的制备及性能研究

刘运浩1, 胡晓龙1,2, 王超1, 宋书会1, 何祖宇1, 周闯1, 杨子明1, 李普旺1*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (5) : 162 -167.

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化工新型材料 ›› 2026, Vol. 54 ›› Issue (5) : 162-167. DOI: 10.19817/j.cnki.issn1006-3536.2026.05.044
科学研究

菠萝叶纤维素基高吸水树脂的制备及性能研究

    刘运浩1, 胡晓龙1,2, 王超1, 宋书会1, 何祖宇1, 周闯1, 杨子明1, 李普旺1*
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Preparation and properties of pineapple leaf cellulose-based superabsorbent resin

  • Liu Yunhao1, Hu Xiaolong1,2, Wang Chao1, Song Shuhui1, He Zuyu1Zhou Chuang1, Yang Ziming1, Li Puwang1
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摘要

采用水溶液聚合法,以菠萝叶纤维素(PALF)为骨架材料,丙烯酸(AA)和丙烯酰胺(AM)为聚合单体,并在交联剂N,N-亚甲基双丙烯酰胺(MBA)与引发剂过硫酸铵(APS)的作用下,制备了接枝共聚物菠萝叶纤维素基高吸水树脂[PALF-g-P(AA-AM)]。通过单因素实验探讨了最佳实验制备条件。采用红外光谱仪、扫描电镜、热重分析仪对高吸水树脂的结构、微观形貌和热稳定性进行了表征分析,并研究了其吸水和保水性能。结果表明:采用最佳条件制备的高吸水树脂在蒸馏水中的最大吸水倍率为795.25g/g;单体与PALF发生了接枝共聚,制备的高吸水树脂具有稳定的交联结构、热稳定性及优异的吸水保水性能。

Abstract

Pineapple leaf fiber (PALF) cellulose was used as the skeleton,acrylic acid (AA) and acrylamide (AM) served as monomers,and N,N-methylenebisacrylamide (MBA) and ammonium persulfate (APS) acted as the crosslinking agent and initiator,respectively,to prepare a graft copolymer pineapple leaf cellulose-based superabsorbent resin [PALF-g-P(AA-AM)] via aqueous solution polymerization.The optimal preparation conditions were determined through single-factor experiments.The structure,morphology,and thermal stability of the superabsorbent resin were characterized using FT-IR,SEM,and TG.Its water absorption and water retention properties were also examined.The results showed that the maximum water absorption of the superabsorbent resin prepared under optimal preparation conditions reached 795.25g/g in distilled water.The monomers were successfully graft-copolymerized onto PALF,and the prepared superabsorbent resin exhibited a stable crosslinked structure,good thermal stability,and excellent water absorption and retention performance.

关键词

菠萝叶纤维素 / 高吸水树脂 / 吸水倍率 / 保水性

Key words

pineapple leaf cellulose / superabsorbent resin / water absorption / water retention

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菠萝叶纤维素基高吸水树脂的制备及性能研究[J]. 化工新型材料, 2026, 54(5): 162-167 DOI:10.19817/j.cnki.issn1006-3536.2026.05.044

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