纳米氧化铜(CuO NPs)是应用最广泛的纳米材料之一,在医药、环境修复、催化、储能等诸多领域具有潜在的应用价值。随着人们对能源危机的关注日益增加以及化学和物理方法制备金属纳米材料所面临的挑战,绿色合成方法受到广泛关注,尤其植物介导的绿色合成方法展现出更多的优势。系统综述了植物介导合成CuO NPs的制备方法、原理、影响因素及其在环境污染物处理中的应用,并展望了其未来发展趋势,以期为相关领域的研究者提供思路与借鉴。
Copper oxide nanoparticles (CuO NPs) are among the most widely applied nanomaterials and have potential applications in many fields such as medicine,environmental remediation,catalysis,and energy storage.With the increasing concern over the energy crisis and the challenges faced in preparing metal nanomaterials through chemical and physical methods,green synthesis methods have received widespread attention,especially plant-mediated green synthesis methods,which have demonstrated more advantages.This paper systematically reviewed the preparation methods,mechanisms,influencing factors of plant-mediated green synthesis of CuO NPs and their applications in the treatment of environmental pollutants,and looked forward to future development trends,providing ideas and references for researchers in related fields.
[1] Bamisaye A,Adekola M A,Abati S M,et al.Recent advances in metal/metal-oxide nanoparticle-polymer nanohybrid for biomedical applications[J].Materials Today Chemistry,2025,49:103086.
[2] Khezri R,Vahdat S M.Reactions and catalytic applications of metal and metal oxide nanoparticles in organic and inorganic chemistry[J].Inorganica Chimica Acta,2025,588:122842.
[3] Raizada P,Sudhaik A,Patial S,et al.Engineering nanostructures of CuO-based photocatalysts for water treatment:current progress and future challenges[J].Arabian Journal of Chemistry,2020,13(11):8424-8457.
[4] Mobarak M N,Sikder M F,Muntaha K S,et al.Plant extract-mediated green-synthesized CuO nanoparticles for environmental and microbial remediation:a review covering basic understandings to mechanistic study[J].Nanoscale Advances,2025,7:2418-2445.
[5] Kannan K,Radhika D,Vijayalakshmi S,et al.Facile fabrication of CuO nanoparticles via microwave-assisted method:photocatalytic,antimicrobial and anticancer enhancing performance[J].International Journal of Environmental Analytical Chemistry,2022,102(5):1095-1108.
[6] 杨娜,杜秋月,杨淇,等.CuO材料在锂电池及气敏材料以及催化中的晶面、结构、形貌效应[J].化工新型材料,2024,52(6):58-62.
[7] Rheima A M,Sager A G,Mohammed M A,et al.Fabrication of dye-sensitized solar cell using CuO nanoparticles as a photo anode[J].Baghdad Science Journal,2025,22(7):2133-2143.
[8] Shi G J,Liu J,Chen B B,et al.Phase-controlled growth of cubic phase CuO nanoparticles by chemical vapor deposition[J].Physica Status Solidi A:Applications and Materials Science,2017,214(10):1700041.
[9] Meng J L,Yang Z H,Chen L L,et al.Energy storage performance of CuO as a cathode material for aqueous zinc ion battery[J].Materials Today Energy,2020,15:100370.
[10] Zahra S,Abbas T,Sheikh A,et al.Synthesis and characterization of nanosize copper oxide by non-aqueous sol-gel process[J].Journal of the Iranian Chemical Society,2024,21(8):2211-2220.
[11] Mahmood A,Tezcan F,Kardas G.Photoelectrochemical characteristics of CuO films with different electrodeposition time[J].International Journal of Hydrogen Energy,2017,42(36):23268-23275.
[12] Jaison J P,Balasubramanian B,Gangwar J,et al.Green synthesis of bioinspired nanoparticles mediated from plant extracts of asteraceae family for potential biological applications[J].Antibiotics-Basel,2023,12(3):543.
[13] Shiraz M,Imtiaz H,Azam A,et al.Phytogenic nanoparticles:synthesis,characterization,and their roles in physiology and biochemistry of plants[J].Biometals,2024,37(1):23-70.
[14] Alqarni L S,Alghamdi M D,Alshahrani A A,et al.Green nanotechnology:recent research on bioresource-based nanoparticle synthesis and applications[J].Journal of Chemistry,2022,2022:1-31.
[15] Cuong H N,Pansambal S,Ghotekar S,et al.New frontiers in the plant extract mediated biosynthesis of copper oxide (CuO) nanoparticles and their potential applications:a review[J].Environmental Research,2022,203:111858.
[16] Moges G.Critical review of biosynthesized CuO nanoparticle-functionalized fabrics:antimicrobial,biocompatibility and cost effectiveness assessments for medical applications[J].Journal of Molecular Structure,2025,1348:143244.
[17] Paganotti A,de Freitas C C,Pereira R H,et al.Biogenic CuO nanoparticles from Camellia sinensis and Pimpinella anisum plant extracts and their role as antimicrobial agents[J].Plant Nano Biology,2025,11:100138.
[18] Mrabet A,Merino-Garcia I,Perfecto-Irigaray M,et al.Green copper oxide photocathodes using plant extracts for an efficient photoelectrochemical CO2 conversion to alcohols[J].Journal of CO2 Utilization,2025,101:103222.
[19] Nagore P,Ghotekar S,Mane K,et al.Structural properties and antimicrobial activities of polyalthia longifolia leaf extract-mediated CuO nanoparticles[J].BioNanoScience,2021,11:579-589.
[20] Alhalili Z.Green synthesis of copper oxide nanoparticles (CuO NPs) from Eucalyptus globulus leaf extract:adsorption and design of experiments[J].Arabian Journal of Chemistry,2022,15(5):103739.
[21] Sutradhar P,Saha M,Maiti D.Microwave synthesis of copper oxide nanoparticles using tea leaf and coffee powder extracts and its antibacterial activity[J].Journal of Nanostructure in Chemistry,2014,4:86.
[22] Veisi H,Karmakar B,Tamoradi T,et al.Biosynthesis of CuO nanoparticles using aqueous extract of herbal tea (Stachys lavandulifolia) flowers and evaluation of its catalytic activity[J].Scientific Reports,2021,11(1):1983.
[23] Siddiqui H,Qureshi M S,Haque F Z.Effect of copper precursor salts:facile and sustainable synthesis of controlled shaped copper oxide nanoparticles[J].Optik,2016,127(11):4726-4730.
[24] Padil V V T,Černík M.Green synthesis of copper oxide nanoparticles using gum karaya as a biotemplate and their antibacterial application[J].International Journal of Nanomedicine,2013,8:889-898.
[25] Letchumanan D,Sok S P M,Ibrahim S,et al.Plant-based biosynthesis of copper/copper oxide nanoparticles:an update on their applications in biomedicine,mechanisms,and toxicity[J].Biomolecules,2021,11(4):564.
[26] Mary A P A,Ansari A T,Subramanian R.Sugarcane juice mediated synthesis of copper oxide nanoparticles,characterization and their antibacterial activity[J].Journal of King Saud University-Science,2019,31(4):1103-1114.
[27] Achamo T,Zereffa E A,Murthy H C A,et al.Phyto-mediated synthesis of copper oxide nanoparticles using artemisia abyssinica leaf extract and its antioxidant,antimicrobial and DNA binding activities[J].Green Chemistry Letters and Reviews,2022,15(3):598-614.
[28] Ain Noor-Ul,Safdar Naila,Yasmin Azra.Additive-based stability assessment of biologically designed CuO and GSH-CuO nanospheres and their applicability as nano-biosensors[J].Colloids and Surfaces B:Biointerfaces,2019,178:66-73.
[29] Antonio-Pérez A,Durán-Armenta L F,Pérez-Loredo M G,et al.Biosynthesis of copper nanoparticles with medicinal plants extracts:from extraction methods to applications[J].Micromachines,2023,14(10):1882.
[30] Akintelu S A,Folorunso A S,Folorunso F A,et al.Green synthesis of copper oxide nanoparticles for biomedical application and environmental remediation[J].Heliyon,2020,6(7):e04508.
[31] Samari F,Baluchi L,Salehipoor H,et al.Controllable phyto-synthesis of cupric oxide nanoparticles by aqueous extract of capparis spinosa (caper) leaves and application in iron sensing[J].Microchemical Journal,2019,150:104158.
[32] Ali K,Saquib Q,Ahmed B,et al.Bio-functionalized CuO nanoparticles induced apoptotic activities in human breast carcinoma cells and toxicity against aspergillus flavus:an in vitro approach[J].Process Biochemistry,2020,91:387-397.
[33] Fardood S T,Ramazani A,Asiabi P A,et al.A novel green synthesis of copper oxide nanoparticles using a henna extract powder[J].Journal of Structural Chemistry,2018,59(7):1737-1743.
[34] Din M I,Arshad F,Rani A,et al.Single-step green synthesis of stable copper oxide nanoparticles as efficient photocatalyst material[J].Journal of Optoelectronic and Biomedical Materials,2017,9(1):41-48.
[35] Nagajyothi P C,Muthuraman P,Sreekanth T V M,et al.Green synthesis:in vitro anticancer activity of copper oxide nanoparticles against human cervical carcinoma cells[J].Arabian Journal of Chemistry,2017,10(2):215-225.
[36] Prakash S,Elavarasan N,Venkatesan A,etal.Green synthesis of copper oxide nanoparticles and its effective applications in Biginelli reaction,BTB photodegradation and antibacterial activity[J].Advanced Powder Technology,2018,29(12):3315-3326.
[37] Prakalathan D,Kavitha G,Kumar G D.Bioinspired copper oxide nanocomposites:harnessing plant extracts for enhanced photocatalytic performance[J].Environmental Science and Pollution Research International,2024,31(39):51415-51430.
[38] Hafeez M,Ghazal A,Khan J,Ahmad P,etal.Eucalyptus globulus extract-assisted fabrication of copper oxide/zinc oxide nanocomposite for photocatalytic applications[J].Crystals,2022,12(8):1153.
[39] 唐茂,薛娅,向丹丹,等.CuO/ZnO复合光催化材料研究进展[J].化工新型材料,2021,49(5):51-55.
[40] Nzilu D M,Madivoli E S,Makhanu D S,et al.Green synthesis of copper oxide nanoparticles and its efficiency in degradation of rifampicin antibiotic[J].Scientific Reports,2023,13(1):14030.
[41] Mahmoud A E,Al-Qahtani K M,Alflaij S O,et al.Green copper oxide nanoparticles for lead,nickel,and cadmium removal from contaminated water[J].Scientific Reports,2021,11(1):12547.
[42] Eid A M,Fouda A,Hassan S E,et al.Plant-based copper oxide nanoparticles;biosynthesis,characterization,antibacterial activity,tanning wastewater treatment,and heavy metals sorption[J].Catalysts,2023,13(2):348.
[43] Assefa H,Singh S,Shehata N,et al.Green synthesis and characterization of CuO/PANI nanocomposite for efficient Pb(Ⅱ) adsorption from contaminated water[J].Scientific Reports,2024,14(1):30972.
[44] Khairy T,Amin D H,Salama H M,et al.Antibacterial activity of green synthesized copper oxide nanoparticles against multidrug-resistant bacteria[J].Scientific Reports,2024,14(1):25020.
[45] Wang X H,Li J,Liu R,et al.Responses of bacterial communities to CuO nanoparticles in activated sludge system[J].Environmental Science & Technology,2017,51(10):5368-5376.