Fe3O4-g-C3N4/泡沫炭光催化体系及其类芬顿光催化活性研究

丁梓宸, 张越, 张晟斐, 柴希娟*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (5) : 187 -192.

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化工新型材料 ›› 2026, Vol. 54 ›› Issue (5) : 187-192. DOI: 10.19817/j.cnki.issn1006-3536.2026.05.023
科学研究

Fe3O4-g-C3N4/泡沫炭光催化体系及其类芬顿光催化活性研究

    丁梓宸, 张越, 张晟斐, 柴希娟*
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Fe3O4-g-C3N4/foam carbon photocatalytic system and its Fenton-like photocatalytic activity study

  • Ding Zichen, Zhang Yue, Zhang Shengfei, Chai Xijuan
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摘要

研究了一种新型整体式磁性光催化复合材料。以聚氨酯泡沫为模板,生物质酚醛树脂为碳源,FeCl3为磁源,制备了生物质磁性泡沫炭(MCF);进一步以MCF为载体,制备了磁连接的Fe3O4-CN/MCF复合光催化材料。该复合材料具有高比表面积和光催化效率,同时具备磁回收的能力,有效解决了传统粉体光催化材料分离和回收难的问题。此外,还探究了Fe3O4-CN负载量对复合材料性能的影响,发现最佳负载量为0.04g。实验结果表明,所制备的磁连接Fe3O4-CN/MCF复合光催化材料具有良好的催化性能和稳定性,经过5次循环利用,催化性能仅下降了约30%,远远高于单一氮化碳的降解能力,并具有良好的可重复利用性能。可以应用于光催化降解重金属离子和有机污染物等环境治理领域,具有广阔的应用前景。

Abstract

This study presented a new type of monolithic magnetic photocatalytic composite material.Using polyurethane foam as a template,biomass phenolic resin as a carbon source,and FeCl3 as a magnetic source,biomass magnetic foam carbon (MCF) was synthesized.Further,magnetically integrated Fe3O4-CN/MCF composite photocatalytic material was prepared using MCF as the carrier.The composite material had a high specific surface area,high photocatalytic efficiency,and magnetic recovery ability,effectively solving the problem of difficult separation and recovery of traditional powder photocatalytic materials.Moreover,this study explored the effect of Fe3O4-CN loading on the properties of the composite material,and found that the optimum loading amount was 4%.Experimental results showed that the prepared magnetically integrated Fe3O4-CN/MCF composite photocatalytic material had good catalytic performance and stability.After 5 cycles of use,the catalytic performance of the composite system decreased by only about 30%,which was much higher than the degradation ability of single nitrogen-carbon,and exhibited good reusability.This material can be applied in environmental remediation fields such as photocatalytic degradation of organic pollutants,offering broad application prospects.

关键词

磁性泡沫炭 / 光催化材料 / 负载量 / Fe3O4-CN

Key words

magnetic foam carbon / photocatalytic materials / loading amount / Fe3O4-CN

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Fe3O4-g-C3N4/泡沫炭光催化体系及其类芬顿光催化活性研究[J]. 化工新型材料, 2026, 54(5): 187-192 DOI:10.19817/j.cnki.issn1006-3536.2026.05.023

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