氮化碳材料表面调控与光催化性能研究进展

陈辰, 刘建华, 王歌兰, 刘娜, 李培贺*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (2) : 95 -99.

PDF
化工新型材料 ›› 2026, Vol. 54 ›› Issue (2) : 95-99. DOI: 10.19817/j.cnki.issn1006-3536.2026.02.043
综述与专论

氮化碳材料表面调控与光催化性能研究进展

    陈辰, 刘建华, 王歌兰, 刘娜, 李培贺*
作者信息 +

Research progress on surface modulation and photocatalytic performance of carbon nitride materials

  • Chen Chen, Liu Jianhua, Wang Gelan, Liu Na, Li Peihe
Author information +
文章历史 +
PDF

摘要

石墨相氮化碳(g-C3N4)作为一种极具潜力的新型半导体光催化材料,凭借其独特的带隙结构,展现出优异的可见光吸收能力,在光催化水分解制氢以及分子转化等关键领域受到学者广泛关注。其独特的电子结构特性使其在光激发下能够有效产生光生载流子,为光催化反应提供充足的动力,成为解决能源与环境问题的重要候选材料。系统综述了g-C3N4的化学与物理制备方法,深入探讨了其在光催化分子转化及光催化降解领域的最新研究成果。为设计具备分子转化功能导向的新型氮化碳基材料提供了新思路,并对其未来发展趋势及潜在的应用领域进行了展望。

Abstract

Graphitic carbon nitride (g-C3N4),as a highly promising new semiconductor photocatalytic material,demonstrates excellent visible-light absorption capacity owing to its unique bandgap structure,and has garnered extensive attention from scholars in key fields such as photocatalytic water splitting for hydrogen production and molecular transformation.Its distinctive electronic structural characteristics enable it to effectively generate photogenerated carriers under photoexcitation,providing sufficient driving force for photocatalytic reactions and making it an important candidate material for addressing energy and environmental issues.This paper systematically reviewed the chemical and physical preparation methods of g-C3N4 and delved into the latest research achievements in the fields of photocatalytic molecular transformation and photocatalytic degradation.It offers new ideas for designing novel carbon nitride-based materials with molecular transformation functionality and provides an outlook on its future development trends and potential application areas.

关键词

氮化碳 / 表面调控 / 光催化 / 分子转化 / 水分解制氢

Key words

carbon nitride / surface modulation / photocatalysis / molecular transformation / water splitting for hydrogen production

引用本文

引用格式 ▾
氮化碳材料表面调控与光催化性能研究进展[J]. 化工新型材料, 2026, 54(2): 95-99 DOI:10.19817/j.cnki.issn1006-3536.2026.02.043

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Tan H,Zhou P,Liu M,et al.Photocatalysis of water into hydrogen peroxide over an atomic GaN5 site[J].Nature Synthesis,2023,2(6):557-563.
[2] Li W J,Wang J B,Liu Y H,et al.Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids[J].Chinese Chemical Letters,2025,36(3):110001.
[3] Zhou T,Han X,Shen W,et al.Construction of NiS/CTF heterojunction photocatalyst with an outstanding photocatalytic hydrogen evolution performance[J].Chinese Chemical Letters,2024,36(11):110415.
[4] Zhao X,Liu Q,Li X,et al.Two-dimensional g-C3N4 nanosheets-based photo-catalysts for typical sustainable processes[J].Chinese Chemical Letters,2023,34(11):108306.
[5] Liebig J.Analyse der harnsäure[J].Journal für Praktische Chemie,1834,2(1):342-344.
[6] Franklin E C.The ammono carbonic acids[J].Journal of the American Chemical Society,1922,44(3):486-509.
[7] Pauling L,Sturdivant J H.The structure of cyameluric acid,hydromelonic acid and related substances[J].Proceedings of the National Academy of Sciences,1937,23(12):615-620.
[8] He F,Wang Z,Li Y,et al.The nonmetal modulation of composition and morphology of g-C3N4-based photocatalysts[J].Applied Catalysis B:Environmental,2020,269:118828.
[9] Modwi A,Khezami L,Ghoniem M G,et al.Superior removal of dyes by mesoporous MgO/g-C3N4 fabricated through ultrasound method:adsorption mechanism and process modeling[J].Environmental Research,2022,205:112543.
[10] Zheng T,Li M,Zhou S,et al.Gas exfoliation mechanisms of graphitic carbon nitride into few-layered nanosheets[J].Journal of Porous Materials,2022,29:331-340.
[11] Groenewolt M,Antonietti M.Synthesis of g-C3N4 nanoparticles in mesoporous silica host matrices[J].Advanced Materials,2005,17(14):1789-1792.
[12] Molaei P,Rahimi-Moghadam F.Porous g-C3N4 nanosheets through facile thermal polymerization of melamine in the air for photocatalyst application[J].Journal of Materials Science:Materials in Electronics,2021,32:19655-19666.
[13] 姜鹏程,王周福,王玺堂,等.不同气氛下类石墨相氮化碳的合成及热稳定性能[J].材料导报,2021,35(6):6048-6053.
[14] Plubphon N,Thongtem S,Phuruangrat A,et al.Direct microwave heating synthesis and characterization of highly efficient g-C3N4 photocatalyst[J].Inorganic Chemistry Communications,2022,139:109386.
[15] 李超,曹传宝,朱鹤孙.电化学沉积法制备类石墨相氮化碳[J].科学通报,2003(9):905-908.
[16] Singh P P,Srivastava V.Recent advances in visible-light graphitic carbon nitride (g-C3N4) photocatalysts for chemical transformations[J].RSC Advances,2022,12(28):18245-18265.
[17] Pan Z,Ding W,Chen H,et al.A review on g-C3N4 decorated with silver for photocatalytic energy conversion[J].Chinese Chemical Letters,2024,35(2):108567.
[18] Wu J,Ding X,Zhu X.Preparation of organic compounds/g-C3N4 composites and their applications in photocatalysis[J].Materials Chemistry Frontiers,2024,8(23):3859-3876.
[19] Li B,Si Y,Fang Q,et al.Hierarchical self-assembly of well-defined Louver-like P-doped carbon nitride nanowire arrays with highly efficient hydrogen evolution[J].Nano-Micro Letters,2020,12:52.
[20] Wu T,Liu Z,Shao B,et al.Enhanced piezo-photocatalytic degradation of organic pollutants by cambered wall lamellar structure of porous tubular g-C3N4[J].Nano Energy,2024,120:109137.
[21] Liu X,Ma R,Zhuang L,et al.Recent developments of doped g-C3N4 photocatalysts for the degradation of organic pollutants[J].Critical Reviews in Environmental Science and Technology,2021,51(8):751-790.
[22] Wang M,Zeng Y,Dong G,et al.Br-doping of g-C3N4 towards enhanced photocatalytic performance in Cr(Ⅵ) reduction[J].Chinese Journal of Catalysis,2020,41(10):1498-1510.
[23] Ismail A,Zahid M,Ahmad B,et al.Tailoring g-C3N4 properties through P and K co-doping:advancing photocatalytic CO2 reduction to CH4[J].Chemical Engineering Journal,2025,513:163023.
[24] Liu G,Dong G,Zeng Y,et al.The photocatalytic performance and active sites of g-C3N4 effected by the coordination doping of Fe(Ⅲ)[J].Chinese Journal of Catalysis,2020,41(10):1564-1572.
[25] Chen J,Yan Z,Ding Y,et al.W single-atom mediated singlet oxygen formation on carbon nitride for powerful photocatalytic abatement of organic pollutants[J].Chemical Engineering Journal,2024,496:154238.
[26] Chen X,Wang J,Chai Y,et al.Efficient photocatalytic overall water splitting induced by the giant internal electric field of a g-C3N4/rGO/PDIP Z-scheme heterojunction[J].Advanced Materials,2021,33(7):2007479.
[27] Ahmad N,Kuo C F J,Mustaqeem M,et al.Synthesis of novel Type-Ⅱ MnNb2O6/g-C3N4 Mott-Schottky heterojunction photocatalyst:excellent photocatalytic performance and degradation mechanism of fluoroquinolone-based antibiotics[J].Chemosphere,2023,321:138027.
[28] Jiang J,Xiong Z,Wang H,et al.Sulfur-doped g-C3N4/g-C3N4 isotype step-scheme heterojunction for photocatalytic H2 evolution[J].Journal of Materials Science & Technology,2022,118:15-24.
[29] Sun D,Li P,Wang X,et al.Heterogeneous photocatalytic anaerobic oxidation of alcohols to ketones by Pt-mediated hole oxidation[J].Chemical Communications,2020,56(79):11847-11850.
[30] 刘建华,王歌兰,陈辰,等.W10/Cu/g-C3N4复合材料的制备及其光催化性能研究[J].化工新型材料,2025,53(8):258-262.
[31] He F,Xiao Q,Chen Y,et al.Synergistic reduction of U(Ⅵ) and selective oxidation of benzyl alcohol to prepare benzaldehyde via WOx/g-C3N4[J].Applied Catalysis B:Environmental,2024,343:123525.
[32] Bao X,Lv X,Wang Z,et al.Nitrogen vacancy enhanced photocatalytic selective oxidation of benzyl alcohol in g-C3N4[J].International Journal of Hydrogen Energy,2021,46(76):37782-37791.
[33] Quintana M A,Solís R R,Martín-Lara M Á,et al.Enhanced boron modified graphitic carbon nitride for the selective photocatalytic production of benzaldehyde[J].Separation and Purification Technology,2022,298:121613.
[34] Chandra M,Guharoy U,Pradhan D.Boosting the photocatalytic H2 evolution and benzylamine oxidation using 2D/1D g-C3N4/TiO2 nanoheterojunction[J].ACS Applied Materials & Interfaces,2022,14(19):22122-22137.
[35] Lopes J C,Moniz T,Sampaio M J,et al.Efficient synthesis of imines using carbon nitride as photocatalyst[J].Catalysis Today,2023,418:114045.
[36] Chauhan D K,Battula V R,Jain S,et al.Photocatalytic integrated production of hydrogen and imines from aromatic amines via Ni-mesoporous carbon nitride:an acceptorless dehydrogenative pathway[J].Journal of Cleaner Production,2021,307:127162.
[37] Wang Y,Li P,Wang J,et al.Visible-light photocatalytic selective oxidation of C(sp3)-H bonds by anion-cation dual-metal-site nanoscale localized carbon nitride[J].Catalysis Science & Technology,2021,11(13):4429-4438.
[38] Li P,Li Q,Wang G,et al.Metal-free polymeric and molecular disorder/order semiconductor heterojunctions for the visible-light photocatalytic Minisci reaction[J].Journal of Materials Chemistry A,2024,12:13760-13769.
[39] Singh J,Arora A,Basu S.Synthesis of coral like WO3/g-C3N4 nanocomposites for the removal of hazardous dyes under visible light[J].Journal of Alloys and Compounds,2019,808:151734.
[40] Oliveira W L,Ferreira M A,Mourão H A J L,et al.Heterogeneous Fenton-like surface properties of oxygenated graphitic carbon nitride[J].Journal of Colloid and Interface Science,2021,587:479-488.
[41] Chu Y C,Lin T J,Lin Y R,et al.Influence of P,S,O-doping on g-C3N4 for hydrogel formation and photocatalysis:an experimental and theoretical study[J].Carbon,2020,169:338-348.
[42] Meena P L,Poswal K,Surela A K,et al.Synthesis of graphitic carbon nitride/zinc oxide(g-C3N4/ZnO) hybrid nanostructures and investigation of the effect of ZnO on the photodegradation activity of g-C3N4 against the brilliant cresyl blue (BCB) dye under visible light irradiation[J].Advanced Composites and Hybrid Materials,2023,6(1):16.

基金资助

国家自然科学基金(22261042和U24A20544);内蒙古民族大学博士科研启动基金项目(BS445);2022年内蒙古自治区教育科学规划课题项目(NGJGH2022274);2023年内蒙古自治区教育科学规划课题项目(NGJGH2023107);内蒙古自治区直属高校基本科研业务费项目(GXKY22165和GXKY23Z078)

AI Summary AI Mindmap
PDF

315

访问

0

被引

导航
相关文章

AI思维导图

/