泡沫金属因轻质、多孔、高导热的性能,常被用于强化复合相变材料传热,其低发射特性可以进一步促进在光热转换及热能存储一体化领域的应用。以泡沫铜、泡沫镍、泡沫铁和泡沫铁镍为光热转换和增强导热基体,制备泡沫金属基光热转换复合相变材料,对比研究了不同泡沫金属复合相变材料的综合性能。结果表明:在800W/m2的模拟太阳光下,泡沫铁复合相变材料的储热速率和光热转换效率显著优于其他3种泡沫金属。经1h光照后,其最高温度达74.4℃;在25～50℃的光热转换过程中光热转换效率为91.97%,可实现142.63J/g的潜热存储。因此,泡沫金属复合相变材料在能源存储领域具有较好的应用潜力。
Foam metals are widely used to enhance the heat transfer of composite phase change materials (CPCMs) due to their lightweight nature,porosity,and high thermal conductivity.Additionally,their low emissivity performance further promotes their application in integrated photothermal conversion and thermal energy storage.In this study,foam copper,foam nickel,foam iron,and foam iron-nickel were used as photothermal conversion and thermal conductivity enhancement matrices to fabricate foam metal-based photothermal conversion CPCMs.The comprehensive performance of different foam metal CPCMs was compared.The results indicated that under simulated sunlight at 800W/m2,the thermal storage rate and photothermal conversion efficiency of the iron foam-based composite phase change material were significantly higher than those of the other three foam metals.After one hour of illumination,its maximum temperature reached 74.4℃.During the photothermal conversion process from 25℃ to 50℃,the photothermal conversion efficiency was 91.97%,with a latent thermal storage of 142.63J/g.These findings demonstrate that foam metal-based CPCMs have strong potential for applications in energy storage.
[1] 刘佳佳,张凇铭,何秀芹,等.石蜡/SiO2/CuS纳米复合相变材料的制备用于太阳能的光热转换与存储[J].化工新型材料,2015,43(12):104-106.
[2] Gong J,Li C,Wasielewski M R.Advances in solar energy conversion[J].Chemical Society Reviews,2019,48(7):1862-1864.
[3] 王戎,陈祉叶,曾嘉伟,等.“双碳”目标下中国能源转型的战略思考[J].科技导报,2024,42(19):10-19.
[4] Ayachi S,He X,Yoon H J.Solar thermoelectricity for power generation[J].Advanced Energy Materials,2023,13(28):2300937.
[5] Zhang D,Zhang S,Liang Q,et al.One-step synthesis of multifunctional bacterial cellulose film-based phase change materials with cross-linked network structure for solar-thermal energy conversion,storage,and utilization[J].Small,2024,20(12):2307259.
[6] Nijsse F J M M,Mercure J F,Ameli N,et al.The momentum of the solar energy transition[J].Nature Communications,2023,14(1):6542.
[7] 蒋伟,吴淑英,何晓祥.石墨烯纳米片/石蜡定型相变材料的制备方法及热性能研究[J].化工新型材料,2022,50(6):86-90,95.
[8] Wang B,Liu Y,Wang D,et al.A review of the photothermal-photovoltaic energy supply system for building in solar energy enrichment zones[J].Renewable and Sustainable Energy Reviews,2024,191:114100.
[9] 张煜,侯予,陈良.等离激元Au纳米流体集热器性能研究[J].西安交通大学学报,2020,54(8):44-49.
[10] Chen C J,Kuang Y D,Hu L B.Challenges and opportunities for solar evaporation[J].Joule,2019,3(3):683-718.
[11] Yang J,Choi J,Bang D,et al.Convertible organic nanoparticles for near-infrared photothermal ablation of cancer cells[J].Hyperthermia,2011,50:441-444.
[12] Wen R,Zhu S,Wu M,et al.Design and preparation of Ag modified expanded graphite based composite phase change materials with enhanced thermal conductivity and light-to-thermal properties[J].Journal of Energy Storage,2021,41:102936.
[13] Xia Q,Zhang J,Zhang N,et al.Carbonized-wood based composite phase change materials loaded with alumina nanoparticles for photo-thermal conversion and energy storage[J].Journal of Energy Storage,2024,87:111377.
[14] Du M,Yu X,Zhang Z,et al.CuS nanoparticle-based microcapsules for solar-induced phase-change energy storage[J].ACS Applied Nano Materials,2022,5(9):13009-13017.
[15] Ye X,Ma Y,Tian Z,et al.Shape-stable MXene/sodium alginate/carbon nanotubes hybrid phase change material composites for efficient solar energy conversion and storage[J].Composites Science and Technology,2022,230:109794.
[16] 胡定华,许肖永,林肯,等.石蜡/膨胀石墨/石墨片复合相变材料导热性能研究[J].工程热物理学报,2021,42(9):2414-2418.
[17] Deng J,Li X,Li C,et al.Multifunctional flexible composite phase change material with high anti-leakage and thermal conductivity performances for battery thermal management[J].Journal of Energy Storage,2023,72:108313.
[18] Wong T L,Vallés C,Nasser A,et al.Effects of boron-nitride-based nanomaterials on the thermal properties of composite organic phase change materials:a state-of-the-art review[J].Renewable and Sustainable Energy Reviews,2023,187:113730.
[19] 代建龙,李果,曹一通,等.多孔金属泡沫强化石蜡相变蓄热性能[J].储能科学与技术,2024,13(11):3764-3771.
[20] Peng Z,Gao Q,Zhang Z,et al.Heat transfer performance of copper foam/paraffin composite phase change material under different centrifugal forces-a visual experimental study[J].International Journal of Heat and Mass Transfer,2024,226:125475.
[21] 柴伟杰,赵锡佳,曹世豪.金属蜂窝增强相变材料熔化储热试验与数值模拟[J].储能科学与技术,2024,13(12):4357-4367.
[22] Zhang H,Wang L,Xi S,et al.3D porous copper foam-based shape-stabilized composite phase change materials for high photothermal conversion,thermal conductivity and storage[J].Renewable Energy,2021,175:307-317.
[23] Kline S J,McClintock F A.Describing uncertainties in single-sample experiments[J].Journal of Mechanical Engineering,1953,75:3-8.
[24] Farnworth B.Mechanisms of heat flow through clothing insulation[J].Textile Research Journal,1983,53(12):717-725.
[25] 薛锦瑞,周国轩,邓朝辉,等.光热相变储能复合材料的制备及应用研究进展[J].复合材料学报,2025,DOI:10.13801/j.cnki.fhclxb.20241028.002.
[26] Yu J,Wang Y,Qi C,et al.Photothermal and thermoelectric performance of PCMs doped with nanoparticles and metal foam[J].International Communications in Heat and Mass Transfer,2023,143:106712.
[27] Yin Q,Zhang J,Tao Y,et al.The emerging development of solar evaporators in materials and structures[J].Chemosphere,2022,289:133210.
[28] Guo J,Wei P,Huang X,et al.Radially graded metal foams arrangement in heat storage device of photothermal utilization systems[J].Solar Energy Materials and Solar Cells,2023,256:112315.
[29] Farid M M,Khudhair A M,Razack S A K,et al.A review on phase change energy storage:materials and applications[J].Energy Conversion and Management,2004,45(9-10):1597-1615.
[30] Zalba B,Marín J M,Cabeza L F,et al.Free-cooling of buildings with phase change materials[J].International Journal of Refrigeration,2004,27(8):839-849.
[31] Pan X,Zhang N,Yuan Y,et al.Balsa-based porous carbon composite phase change material with photo-thermal conversion performance for thermal energy storage[J].Solar Energy,2021,230:269-277.
基金资助
重庆市自然科学基金项目(CSTB2022NSCQ-MSX0604)
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