化工新型材料

化工新型材料 ›› 2026, Vol. 54 ›› Issue (2) : 60-65. DOI: 10.19817/j.cnki.issn1006-3536.2026.02.025

综述与专论

SrTiO₃的合成及应用研究进展

周杰, 石祥辉, 王璐, 朱蓓蓓

作者信息 +

Research progress on synthesis and application of SrTiO₃

Zhou Jie, Shi Xianghui, Wang Lu, Zhu Beibei

Author information +

文章历史 +

Received		Published
2025-02-17		2026-02-20
Issue Date	Revised Date
2026-02-12	2025-02-17

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摘要

作为一种新型钙钛矿材料,SrTiO₃具有稳定性好、光电性能优异等显著优点,日益受到科学界的追捧。重点综述了SrTiO₃的主要合成方法,包括水热法、溶剂热法、固相法、熔盐法、声化学法和溶胶-凝胶法等,并探讨了SrTiO₃在光催化、储能、传感和燃料电池等领域的应用,指出目前研究中存在的主要问题,并对未来的发展方向进行了展望。

Abstract

As a new type of perovskite material,SrTiO₃ is gradually sought after by the scientific community because of its remarkable advantages such as good stability and excellent photovoltaic properties.The main synthesis methods of SrTiO₃,including hydrothermal,solvothermal,solid-phase,molten-salt,acoustic-chemical and sol-gel methods,were highlighted and reviewed.We also discussed the applications of SrTiO₃ in the fields of photocatalysis,energy storage,sensing,and fuel cell,pointed out the main problems in the current research,and outlined the future development directions.

关键词

钛酸锶 / 钙钛矿 / 合成 / 应用 / 进展

Key words

SrTiO₃ / perovskite / synthesis / application / progress

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SrTiO₃的合成及应用研究进展[J]. 化工新型材料, 2026, 54(2): 60-65 DOI:10.19817/j.cnki.issn1006-3536.2026.02.025

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] Zhang Y,Zhong L,Duan D.Single-step hydrothermal synthesis of strontium titanate nanoparticles from crystalline anatase titanium dioxide[J].Ceramics International,2015,41(10):13516-13524.
[2] Huang S T,Lee W W,Chang J L,et al.Hydrothermal synthesis of SrTiO₃ nanocubes:characterization,photocatalytic activities,and degradation pathway[J].Journal of the Taiwan Institute of Chemical Engineers,2014,45(4):1927-1936.
[3] Shen H,Lu Y,Wang Y,et al.Low temperature hydrothermal synthesis of SrTiO₃ nanoparticles without alkali and their effective photocatalytic activity[J].Journal of Advanced Ceramics,2016,5(4):298-307.
[4] Mourão H A J L,Lopes O F,Ribeiro C,et al.Rapid hydrothermal synthesis and pH-dependent photocatalysis of strontium titanate microspheres[J].Materials Science in Semiconductor Processing,2015,30:651-657.
[5] Souza A E,Santos G T A,Barra B C,et al.Photoluminescence of SrTiO₃:influence of particle size and morphology[J].Crystal Growth & Design,2012,12(11):5671-5679.
[6] Nakashima K,Kera M,Fujii I,et al.A new approach for the preparation of SrTiO₃ nanocubes[J].Ceramics International,2013,39(3):3231-3234.
[7] Kimijima T,Kanie K,Nakaya M,et al.Solvothermal synthesis of shape-controlled perovskite MTiO₃ (M=Ba,Sr,and Ca) particles in H₂O/polyols mixed solutions[J].Materials Transactions,2014,55(1):147-153.
[8] Berbenni V,Marini A,Bruni G.Effect of mechanical activation on the preparation of SrTiO₃ and Sr₂TiO₄ ceramics from the solid state system SrCO₃-TiO₂[J].Journal of Alloys and Compounds,2001,329(1-2):230-238.
[9] Liu Y,Xie L,Li Y,et al.Synthesis and high photocatalytic hydrogen production of SrTiO₃ nanoparticles from water splitting under UV irradiation[J].Journal of Power Sources,2008,183(2):701-707.
[10] Wang T X,Liu S Z,Chen J.Molten salt synthesis of SrTiO₃ nanocrystals using nanocrystalline TiO₂ as a precursor[J].Powder Technology,2011,205(1-3):289-291.
[11] Zhang J,Huang M,Yanagisawa K,et al.NaCl-H₂O-assisted preparation of SrTiO₃ nanoparticles by solid state reaction at low temperature[J].Ceramics International,2015,41(4):5439-5444.
[12] Ham Y,Hisatomi T,Goto Y,et al.Flux-mediated doping of SrTiO₃ photocatalysts for efficient overall water splitting[J].Journal of Materials Chemistry A,2016,4(8):3027-3033.
[13] Yu J C,Zhang L,Li Q,et al.Sonochemical preparation of nanoporous composites of titanium oxide and size-tunable strontium titanate crystals[J].Langmuir,2003,19(18):7673-7675.
[14] Xu M,Lu Y N,Liu Y F,et al.Synthesis of monosized strontium titanate particles with tailored morphologies[J].Journal of the American Ceramic Society,2006,89(12):3631-3634.
[15] Ashiri R,Ajami R,Moghtada A.Sonochemical synthesis of SrTiO₃ nanocrystals at low temperature[J].International Journal of Applied Ceramic Technology,2014,12(S2):E202-E206.
[16] Bao D,Yao X,Wakiya N,et al.Band-gap energies of sol-gel-derived SrTiO₃ thin films[J].Applied Physics Letters,2001,79(23):3767-3769.
[17] Pechini M P.Method of preparing lead and alkaline earth titanates and niobates and coating method using the same to form a capacitor:US3330697[P].1967-07-11.
[18] Iwashina K,Kudo A.Rh-doped SrTiO₃ photocatalyst electrode showing cathodic photocurrent for water splitting under visible-light irradiation[J].Journal of the American Chemical Society,2011,133(34):13272-13275.
[19] Su E C,Huang B S,Wey M Y.Enhanced optical and electronic properties of a solar light-responsive photocatalyst for efficient hydrogen evolution by SrTiO₃/TiO₂ nanotube combination[J].Solar Energy,2016,134:52-63.
[20] Wang B,Shen S,Guo L.Surface reconstruction of facet-functionalized SrTiO₃ nanocrystals for photocatalytic hydrogen evolution[J].ChemCatChem,2016,8(4):798-804.
[21] Moss B,Wang Q,Butler K T,et al.Linking in situ charge accumulation to electronic structure in doped SrTiO₃ reveals design principles for hydrogen-evolving photocatalysts[J].Nature Materials,2021,20(4):511-517.
[22] Trang T N Q,Tran Van M,Phan T B,et al.Spatially controlled photogenerated charge carriers induced by SrTiO₃-architectured heterojunction nanocubes for a photocatalytic hydrogen evolution reaction[J].ACS Applied Energy Materials,2021,4(9):8910-8921.
[23] Zeng B,Wang S,Feng Z,et al.Atomically unraveling the dependence of surface microstructure on plasmon-induced hydrogen evolution on Au/SrTiO₃[J].Nano Energy,2022,91:106638.
[24] Yang J,Chen H,Bai P,et al.Modulating the electronic structure of macroporous SrTiO₃ through cobalt doping for enhance photocatalytic hydrogen evolution[J].International Journal of Hydrogen Energy,2024,80:104-114.
[25] Namade L D,Band S S,Pawar P K,et al.Ultraviolet light-driven degradation of organic dyes using SrTiO₃ photocatalytic nanoparticles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2025,708:135976.
[26] Paul P C,Shah A,Singh L R,et al.Mn-doped SrTiO₃ and SrTiO₃-Fe₂O₃ composite perovskites:photocatalytic dye degradation and energy storage application[J].Journal of Materials Science:Materials in Electronics,2023,34(16):1305.
[27] Mehra S,Saroha J,Rani E,et al.Development of visible light-driven SrTiO₃ photocatalysts for the degradation of organic pollutants for waste-water treatment:contrasting behavior of MB & MO dyes[J].Optical Materials,2023,136:113344.
[28] Wu X,Chen J,Yang X,et al.Synergistic activation of peroxymonosulfate for tetracycline hydrochloride degradation with SrTiO₃/Ti₃C₂T_x photocatalyst[J].Applied Surface Science,2025,680:161317.
[29] Ding B,Liu S,Wang Y,et al.Construction of ZnIn₂S₄/SrTiO₃/In(OH)₃ heterojunction for antibiotic removal,H₂ evolution and CO₂ reduction[J].Journal of Alloys and Compounds,2025,1010:177574.
[30] Pan L,Mei H,Zhu G,et al.Bi selectively doped SrTiO_3-x nanosheets enhance photocatalytic CO₂ reduction under visible light[J].Journal of Colloid and Interface Science,2022,611:137-148.
[31] Tang Y,Li Y,Bao W,et al.Enhanced dry reforming of CO₂ and CH₄ on photothermal catalyst Ru/SrTiO₃[J].Applied Catalysis B:Environmental,2023,338(123054):123054.
[32] Yahya M S,Ismail M.Catalytic effect of SrTiO₃ on the hydrogen storage behaviour of MgH₂[J].Journal of Energy Chemistry,2019,28:46-53.
[33] Zhu J,Wang H,Huang L,et al.Nanosized SrTiO₃ catalyzes hydrogen sorption of MgH₂[J].ACS Applied Energy Materials,2024,7(18):7677-7686.
[34] Liu L,Chu B,Li P,et al.Achieving high energy storage performance and ultrafast discharge speed in SrTiO₃-based ceramics via a synergistic effect of chemical modification and defect chemistry[J].Chemical Engineering Journal,2022,429:132548.
[35] Pourmohamadian H,Rahimi-Nasrabadi M,Sheikhzadeh G A,et al.Preparation of SrTiO₃-microencapsulated palmitic acid by means of a sol-gel approach as thermal energy storage materials[J].Journal of Materials Science:Materials in Electronics,2017,29(1):794-800.
[36] Chan N Y,Zhao M,Huang J,et al.Highly sensitive gas sensor by the LaAlO₃/SrTiO₃ heterostructure with Pd nanoparticle surface modulation[J].Advanced Materials,2014,26(34):5962-5968.
[37] Ahmad K,Mohammad A,Mathur P,et al.Preparation of SrTiO₃ perovskite decorated rGO and electrochemical detection of nitroaromatics[J].Electrochimica Acta,2016,215:435-446.
[38] Bhardwaj R,Hazra A.Pd functionalized SrTiO₃ hollow spheres for humidity-tolerant ethanol sensing[J].Sensors and Actuators B:Chemical,2022,372:132615.
[39] Kacem K,Casanova-Chafer J,Ameur S,et al.Gas sensing properties of graphene oxide loaded with SrTiO₃ nanoparticles[J].Journal of Alloys and Compounds,2023,941:169011.
[40] Bhardwaj R,Hazra A.SrTiO₃-TiO₂ heterostructured nanotube arrays for ultrafast ethanol Sensing[J].ACS Applied Nano Materials,2022,5(10):15507-15517.
[41] Wu L,Ji Y,Ouyang B,et al.Self-powered light-temperature dual-parameter sensor using Nb-doped SrTiO₃ materials via thermo-phototronic effect[J].Advanced Functional Materials,2021,31(17):2010439.
[42] Gao X,Zhou F,Li M,et al.Flexible stannum-doped SrTiO₃ nanofiber membranes for highly sensitive and reliable piezoresistive pressure sensors[J].ACS Applied Materials & Interfaces,2021,13(44):52811-52821.
[43] Kumar G S,Prasanna S B,Marenahalli B L,et al.Flake-like structure of SrTiO₃ nanoparticles dispersed on graphene oxide:a selective and sensitive electrochemical sensor for determination of chloramphenicol in milk and honey samples[J].Food Chemistry,2024,444:138637.
[44] Shen X,Kawabata T,Sasaki K.Redox-stable S_r0.9La_0.1TiO₃-supported SOFC single cells[J].International Journal of Hydrogen Energy,2017,42(10):6941-6949.
[45] Shah M A K Y,Rauf S,Zhu B,et al.Semiconductor Nb-Doped SrTiO_3-δ Perovskite Electrolyte for a Ceramic Fuel Cell[J].ACS Applied Energy Materials,2021,4(1):365-375.
[46] Lv X,Lam F L Y,Hu X.Developing SrTiO₃/TiO₂ heterostructure nanotube array for photocatalytic fuel cells with improved efficiency and elucidating the effects of organic substrates[J].Chemical Engineering Journal,2022,427:131602.